10-(2-Chlorophenyl)-5,5-difluoro-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2 inverted exclamation mark,1 inverted exclamation mark-f][1,3,2]diazaborinin-4-ium-5-uide | 1357004-00-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 10-(2-Chlorophenyl)-5,5-difluoro-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2 inverted exclamation mark,1 inverted exclamation mark-f][1,3,2]diazaborinin-4-ium-5-uide
• 英文别名: 8-(2-chlorophenyl)-2,2-difluoro-4,6,10,12-tetramethyl-3-aza-1-azonia-2-boranuidatricyclo[7.3.0.03,7]dodeca-1(12),4,6,8,10-pentaene
• CAS: 1357004-00-2
• 化学式: C₁₉H₁₈BClF₂N₂
• 分子量: 358.626
• InChiKey: WMEUFFJXVURTKV-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  10-(2-Chlorophenyl)-5,5-difluoro-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2 inverted exclamation mark,1 inverted exclamation mark-f][1,3,2]diazaborinin-4-ium-5-uide 在 碘苯二乙酸 、 碘 作用下， 以 乙腈 为溶剂， 反应 10.0h， 以90%的产率得到4,4-difluoro-2,6-diiodo-1,3,5,7-tetramethyl-8-(2-chlorophenyl)-4-bora-3a,4a-diaza-s-indacene
  参考文献：
  名称：

  A new practical and highly efficient iodination of BODIPY derivatives with hypervalent iodine reagent

  摘要：

  A practical, convenient, and highly efficient mono- and diiodination of 1,3,5,7-tetramethyl BODIPY derivatives was achieved by using IOAc as the iodination reagent which was generated in situ from the mixture of phenyliodine(III) diactate with iodine. The iodinated reactions were performed smoothly to give the mono- or diiodination products in good to excellent yields. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.10.040

文献信息

• An Efficient and Convenient Bromination of BODIPY Derivatives with Copper(II) Bromide
  作者：Jia-Hai Ye、Yan Zhang、Guangpu Wang、Chengmei Huang、Zhengjuan Hu、Whenchao Zhang

  DOI：10.1055/s-0031-1289637

  日期：2012.1

  mono- and dibromination of 1,3,5,7-tetramethyl-substituted BODIPYs were developed by using copper(II) bromide as the bromination reagent under mild reactions, in good to excellent yields. The selectivity of mono- or dibromination depends strongly on the additives of the reactions. copper - bromination - selectivity - fluorescent dyes - 4,4-difluoro-4-bora-3a,4a-diaza-s-indacenes

  以溴化铜（II）为溴化试剂，在温和的反应下，开发了一种高效，简便的单，二溴化1,3,5,7-四甲基取代的BODIPY的方法，收率良好。单溴或二溴的选择性很大程度上取决于反应的添加剂。 铜-溴化-选择性-荧光染料- 4,4-二氟-4-硼-3a，4a-二氮杂-小号-indacenes