[(hexafluoromethylacetylacetonate)3(cerium(III))(μ-(3,5-bis(2-pyridyl)pyrazolate)(chromium(III))(acetylacetonate)2] | 640726-44-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(hexafluoromethylacetylacetonate)3(cerium(III))(μ-(3,5-bis(2-pyridyl)pyrazolate)(chromium(III))(acetylacetonate)2]
• CAS: 640726-44-9
• 化学式: C₃₈H₂₆CeCrF₁₈N₄O₁₀
• 分子量: 1232.73
• InChiKey: KDCBFAQTOJHIFF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Ce(hexafluoroacetylacetone)3(H2O)2 、 [Cr(III)(acetylacetonate)2(3,5-bis(2-pyridyl)pyrazolate)]/ethanol(1/1) 以 氯仿 为溶剂， 生成 [(hexafluoromethylacetylacetonate)3(cerium(III))(μ-(3,5-bis(2-pyridyl)pyrazolate)(chromium(III))(acetylacetonate)2]
  参考文献：
  名称：

  Structural comparison in a series of 3,5-bis(2-pyridyl)pyrazolato bridged Ln(III)–Cr(III) dinuclear complexes

  摘要：

  The novel Ln(III) ion size dependent structural transformation round Ln(III) in a series of discrete [(hfac)(3)Ln(mu-bpypz)Cr(acac)(2)] dinuclear complexes is examined in comparison with the structural parameters in relation to the lanthanide(III) ion radius. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2004.12.146

文献信息

• Novel Structural Transformation around Ln(III) and Unusual Bending of Acetylacetonato Chelate in A Series of New 3d–4f Dinuclear Complexes [(hfac)₃Ln(μ-bpypz)Cr(acac)₂]
  作者：Ryouji Kawahata、Toshiaki Tsukuda、Takashi Yagi、Md. Abdus Subhan、Hiroyasu Nakata、Akira Fuyuhiro、Sumio Kaizaki

  DOI：10.1246/cl.2003.1084

  日期：2003.11

  A new series of discrete [(hfac)3Ln(μ-bpypz)Cr(acac)2] dinuclear complexes has demonstrated the novel LnIII ion size depedent structural transformation around LnIII as well as diastereospecifically assembled chiral configuration along with the unusual bending of the acetylacetonate chelate ring in CrIII.

  一系列新的离散[(hfac)3Ln(μ-bpypz)Cr(acac)2]二核配合物展示了围绕 LnIII 离子的新型 LnIII 离子尺寸依赖性结构转变，以及非对映组装手性构型和 CrIII 中乙酰丙酮螯合环的不寻常弯曲。