N-(3''-(dimethylamino)propyl)-4-[2'-morpholinoethylamino]naphthalene-1,8-dicarboximide | 1363332-93-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: N-(3''-(dimethylamino)propyl)-4-[2'-morpholinoethylamino]naphthalene-1,8-dicarboximide
• CAS: 1363332-93-7
• 化学式: C₂₃H₃₀N₄O₃
• 分子量: 410.516
• InChiKey: WGCBTGVSZNDHDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.13
• 重原子数：
  30.0
• 可旋转键数：
  8.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  65.12
• 氢给体数：
  1.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  N-(2-氨基乙基)吗啉 、 N-(3-dimethylaminopropyl)-4-chloro-1,8-naphthalimide 反应 4.0h， 生成 N-(3''-(dimethylamino)propyl)-4-[2'-morpholinoethylamino]naphthalene-1,8-dicarboximide
  参考文献：
  名称：

  Path-selective photoinduced electron transfer (PET) in a membrane-associated system studied by pH-dependent fluorescence

  摘要：

  The pH-dependent fluorescence behavior of two regioisomeric 'receptor(1)-spacer(1)-fluorophore-spacer(2)-receptor(2)' systems 1 and 2 in micellar solutions of sodium dodecyl sulfate show that photoinduced electron transfer (PET) only occurs from the amine group connected to the 4-amino position of the aminonaphthalimide fluorophore in both cases. This demonstrates the directing influence of the photogenerated electric field within the aminonaphthalimide excited state on the electron transfer process. Since path-selectivity of PET is also known within the membrane-bound photosynthetic reaction center in bacteria, its origins may be illuminated by the simple experiments described here. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.09.059