[(4-trifluoromethyl-2,6-bis(2′-pyridyl)benzene(-1H))Pt(2,6-dimethylphenyl isocyanide)]PF₆ | 1416239-75-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(4-trifluoromethyl-2,6-bis(2′-pyridyl)benzene(-1H))Pt(2,6-dimethylphenyl isocyanide)]PF₆
• CAS: 1416239-75-2
• 化学式: C₂₆H₁₉F₃N₃Pt*F₆P
• 分子量: 770.496
• InChiKey: AEHIIMSJXNTMOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 [(4-trifluoromethyl-2,6-bis(2′-pyridyl)benzene(-1H))PtCl] 、 2,6-二甲基苯基异腈 以 二氯甲烷 、 水 为溶剂， 反应 0.5h， 生成 [(4-trifluoromethyl-2,6-bis(2′-pyridyl)benzene(-1H))Pt(2,6-dimethylphenyl isocyanide)]PF₆
  参考文献：
  名称：

  Luminescent Pincer-Type Cyclometalated Platinum(II) Complexes with Auxiliary Isocyanide Ligands: Phase-Transfer Preparation, Solvatomorphism, and Self-Aggregation

  摘要：

  A series of luminescent pincer-type cyclometalated platinum(II) complexes, namely [4-R-((NCN)-C-boolean AND-N-boolean AND)-PtC N(C6H3-2,6-Me-2)] PF6 (2-4; 4-R-((NCHN)-C-boolean AND-N-boolean AND) represents substituted 1,3-bis(2'-pyridyl)benzene ligands), were prepared under phase-transfer conditions. Complex 2 shows two solvatomorphic crystal structures and exhibits vapoluminescent response toward acetonitrile vapor. The photophysical properties of and supramolecular nanowires formed from these complexes were also investigated.

  DOI：

  10.1021/om300965b