(2-(2,4,6-Me3C6H2NCH)C4H3N)3Eu(THF) | 1312458-78-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-(2,4,6-Me3C6H2NCH)C4H3N)3Eu(THF)
• CAS: 1312458-78-8
• 化学式: C₄₆H₅₃EuN₆O
• 分子量: 857.926
• InChiKey: YZOXZMVPCCJXAJ-QPJRWADESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (2,4,6-trimethylphenyl)(1H-pyrrole-2-ylmethylene)amine 、 [)Me3Si)2N]3Eu(μ-Cl)Li(THF) 以 甲苯 为溶剂， 生成 (2-(2,4,6-Me3C6H2NCH)C4H3N)3Eu(THF)
  参考文献：
  名称：

  Synthesis, characterization, and catalytic activities of rare-earth metal complexes with iminopyrrolyl ligands

  摘要：

  A series of rare-earth metal complexes with substituted iminopyrrolyl ligands were prepared and characterized. Reactions of [(Me3Si)(2)N](3)Ln(mu-Cl)Li(THF)(3) with 3 equiv. of 2-(2.6-Et2C6H3N CH)C4H3NH (la) in toluene generated tris-iminopyrrolyl rare-earth metal complexes with formula [2-(2,6-Et2C6H3N CH)C4H3N](3)Ln(THF)(n) [n = 0, Ln = Y (2a), Eu (2b); n =1,Ln= Nd (2c), Sm (2d)] in moderate yields. Treatments of [(Me3Si)(2)N](3)Ln(mu Cl) Li(THF)(3) with 3 equiv. of 2-(2,4.6-Me3C6H2N CH)C4H3NH (1b) in toluene afforded tris-iminopyrrolyl rare-earth metal complexes with formula 12-(2,4,6-Me3C6H2N CH)C(4)H(3)NI(3)Ln(THF) [Ln = Y (3a), Sm (3b), Eu (3c)]. The catalytic properties of all rare-earth metal complexes on the ring-opening polymerization of E-caprolactone have been studied. The results represent rare example of the pyrrolyl ligands as initiators for E-caprolactone polymerization. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.04.015