N-hexadecyl-4-azido-1,8-naphthalimide | 1087053-36-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: N-hexadecyl-4-azido-1,8-naphthalimide
• 英文别名: 6-Azido-2-hexadecylbenzo[de]isoquinoline-1,3-dione；6-azido-2-hexadecylbenzo[de]isoquinoline-1,3-dione
• CAS: 1087053-36-8
• 化学式: C₂₈H₃₈N₄O₂
• 分子量: 462.635
• InChiKey: IKCHZHIHBNDIHO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.86
• 重原子数：
  34.0
• 可旋转键数：
  16.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  86.14
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  N-hexadecyl-4-azido-1,8-naphthalimide 、 足球烯 以 邻二氯苯 为溶剂， 反应 0.05h， 以72%的产率得到
  参考文献：
  名称：

  Synthesis of 4-aziridino[C60]fullerene-1,8-naphthalimide (C60-NI dyads) and their photophysical properties

  摘要：

  A series of 4-aziridino[C-60]fullerene-1,8-naphthalimide (C-60-NI) dyads 4 ([6,6]-closed ring) were synthesized as the only addition product from the reaction of C-60 with the corresponding azide compounds 3 under microwave irradiation in good yield. A quenching of fluorescence was shown in dyads 4, and this decay was evidenced to be an intramolecular process. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.05.019
• 作为产物：
  描述：

  6-bromo-2-cetyl-1H-benzo[de]isoquinoline-1,3-(2H)-dione 在 sodium azide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 6.0h， 以83%的产率得到N-hexadecyl-4-azido-1,8-naphthalimide
  参考文献：
  名称：

  Synthesis of 4-aziridino[C60]fullerene-1,8-naphthalimide (C60-NI dyads) and their photophysical properties

  摘要：

  A series of 4-aziridino[C-60]fullerene-1,8-naphthalimide (C-60-NI) dyads 4 ([6,6]-closed ring) were synthesized as the only addition product from the reaction of C-60 with the corresponding azide compounds 3 under microwave irradiation in good yield. A quenching of fluorescence was shown in dyads 4, and this decay was evidenced to be an intramolecular process. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.05.019

文献信息

• Synthesis of 4-aziridino[C60]fullerene-1,8-naphthalimide (C60-NI dyads) and their photophysical properties
  作者：Fengrui Liu、Weiqiong Du、Qin Liang、Yuqin Wang、Jianmin Zhang、Jingwei Zhao、Shizheng Zhu

  DOI：10.1016/j.tet.2010.05.019

  日期：2010.7

  A series of 4-aziridino[C-60]fullerene-1,8-naphthalimide (C-60-NI) dyads 4 ([6,6]-closed ring) were synthesized as the only addition product from the reaction of C-60 with the corresponding azide compounds 3 under microwave irradiation in good yield. A quenching of fluorescence was shown in dyads 4, and this decay was evidenced to be an intramolecular process. (C) 2010 Elsevier Ltd. All rights reserved.