2-Hydroxy-2'-(2-hydroxyethoxy)-1,1'-binaphtyl | 55515-89-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-Hydroxy-2'-(2-hydroxyethoxy)-1,1'-binaphtyl
• 英文别名: 1-[2-(2-Hydroxyethoxy)naphthalen-1-yl]naphthalen-2-ol
• CAS: 55515-89-4
• 化学式: C₂₂H₁₈O₃
• 分子量: 330.383
• InChiKey: DNTPEPKVQJLJHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,4-双(溴甲基)萘 、 2-Hydroxy-2'-(2-hydroxyethoxy)-1,1'-binaphtyl 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 以67 %的产率得到2,2'-[naphthalene-1,4-diylbis(methyleneoxy[1,1'-binaphthalene]-2',2-diyloxy)]-di(ethan-1-ol)
  参考文献：
  名称：

  [EN] OLIGOMERIC BINAPHTHYL COMPOUNDS AND THERMOPLASTIC RESINS
  [FR] COMPOSÉS BINAPHTYLE OLIGOMÈRES ET RÉSINES THERMOPLASTIQUES

  摘要：

  The present invention relates to oligomeric binaphtyl compounds of the formula (I) that are suitable as monomers for preparing thermoplastic resins, such as polycarbonate resins, which have beneficial optical and mechanical properties and can be used for producing optical devices. where X1and X2are independently selected from hydrogen, -Alk1-OH, -CH2-A2-CH2-OH, -Alk2-C(O)ORx, -CH2-A2-C(O)ORxand -C(O)-A2-C(O)ORx, where Rxis selected from the group consisting of hydrogen, phenyl, benzyl and C1-C4-alkyl; Y1and Y2are independently selected from -CH2-, -CHArY- and -CH(CH2ArY)-; A1is e. g. a single bond, -CH2-, -CHArA-, -CH(CH2ArA)-, -C(CH2ArA)2-, a moiety of the formula (A), mono- or polycyclic arylene having from 6 to 26 carbon atoms as ring members or mono- or polycyclic hetarylene having a total of 5 to 26 atoms, which are ring members, alternatively, the moiety -Y1-A1-Y2- in formula (I) may be -CH2- or -CHArY-, n is 1, 2 or 3; m, p, q and r are independently 0,1 or 2; R1, R2, R3and R4are independently selected from the group consisting of halogen, C2- C3-alkynyl, CN, R, OR, CH8R'3-8, NR2, C(O)R and CH=CHR", it being possible that R1, R2, R3or R4is identical or different if more than 1 of R1, R2, R3or R4is present, where s on each occurrence is 0,1 or 2.

  公开号：

  WO2023208837A1
• 作为产物：
  描述：

  2-溴乙醇 、 S-1,1'-联-2-萘酚 在 potassium carbonate 作用下， 以 丁酮 为溶剂， 生成 2-Hydroxy-2'-(2-hydroxyethoxy)-1,1'-binaphtyl
  参考文献：
  名称：

  [EN] OLIGOMERIC BINAPHTHYL COMPOUNDS AND THERMOPLASTIC RESINS
  [FR] COMPOSÉS BINAPHTYLE OLIGOMÈRES ET RÉSINES THERMOPLASTIQUES

  摘要：

  The present invention relates to oligomeric binaphtyl compounds of the formula (I) that are suitable as monomers for preparing thermoplastic resins, such as polycarbonate resins, which have beneficial optical and mechanical properties and can be used for producing optical devices. where X1and X2are independently selected from hydrogen, -Alk1-OH, -CH2-A2-CH2-OH, -Alk2-C(O)ORx, -CH2-A2-C(O)ORxand -C(O)-A2-C(O)ORx, where Rxis selected from the group consisting of hydrogen, phenyl, benzyl and C1-C4-alkyl; Y1and Y2are independently selected from -CH2-, -CHArY- and -CH(CH2ArY)-; A1is e. g. a single bond, -CH2-, -CHArA-, -CH(CH2ArA)-, -C(CH2ArA)2-, a moiety of the formula (A), mono- or polycyclic arylene having from 6 to 26 carbon atoms as ring members or mono- or polycyclic hetarylene having a total of 5 to 26 atoms, which are ring members, alternatively, the moiety -Y1-A1-Y2- in formula (I) may be -CH2- or -CHArY-, n is 1, 2 or 3; m, p, q and r are independently 0,1 or 2; R1, R2, R3and R4are independently selected from the group consisting of halogen, C2- C3-alkynyl, CN, R, OR, CH8R'3-8, NR2, C(O)R and CH=CHR", it being possible that R1, R2, R3or R4is identical or different if more than 1 of R1, R2, R3or R4is present, where s on each occurrence is 0,1 or 2.

  公开号：

  WO2023208837A1

文献信息

• Method for producing thermoplastic resin
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US10654972B2

  公开（公告）日：2020-05-19

  The present invention provides a method for producing a thermoplastic resin by reacting reactants comprising a dihydroxy compound. In this production method, the dihydroxy compound comprises a dihydroxy compound represented by the following formula (1), wherein the total weight of a compound represented by the following formula (A), a compound represented by the following formula (B), and a compound represented by the following formula (C) in the dihydroxy compound is 1,500 ppm or less, based on 100 parts by weight of the dihydroxy compound represented by the formula (1):

  本发明提供了一种通过对包含二羟基化合物的反应物进行反应生产热塑性树脂的方法。在该生产方法中，二羟基化合物包括由下式（1）表示的二羟基化合物，其中二羟基化合物中由下式（A）表示的化合物、由下式（B）表示的化合物和由下式（C）表示的化合物的总重量为 1,500 ppm 或更少，基于由式（1）表示的二羟基化合物的 100 重量份：
• Dihydroxy compound
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US10711100B2

  公开（公告）日：2020-07-14

  The present invention provides a method for producing a thermoplastic resin by reacting reactants comprising a dihydroxy compound. In this production method, the dihydroxy compound comprises a dihydroxy compound represented by the following formula (1), wherein the total weight of a compound represented by the following formula (A), a compound represented by the following formula (B), and a compound represented by the following formula (C) in the dihydroxy compound is 1,500 ppm or less, based on 100 parts by weight of the dihydroxy compound represented by the formula (1):

  本发明提供了一种通过对包含二羟基化合物的反应物进行反应生产热塑性树脂的方法。在该生产方法中，二羟基化合物包括由下式（1）表示的二羟基化合物，其中二羟基化合物中由下式（A）表示的化合物、由下式（B）表示的化合物和由下式（C）表示的化合物的总重量为 1,500 ppm 或更少，基于由式（1）表示的二羟基化合物的 100 重量份：
• METHOD FOR PRODUCING THERMOPLASTIC RESIN
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20190233585A1

  公开（公告）日：2019-08-01

  The present invention provides a method for producing a thermoplastic resin by reacting reactants comprising a dihydroxy compound. In this production method, the dihydroxy compound comprises a dihydroxy compound represented by the following formula (1), wherein the total weight of a compound represented by the following formula (A), a compound represented by the following formula (B), and a compound represented by the following formula (C) in the dihydroxy compound is 1,500 ppm or less, based on 100 parts by weight of the dihydroxy compound represented by the formula (1):