N,N'-bismethyl-3,6-bis(4-trifuloromethylphenyl-2-thienyl)-1,4-diketopyrrolo[3,4-c]pyrrole | 1371538-19-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bismethyl-3,6-bis(4-trifuloromethylphenyl-2-thienyl)-1,4-diketopyrrolo[3,4-c]pyrrole
• 英文别名: 2,5-Dimethyl-3,6-di(5-(4-trifluoromethylphenyl)-2-thienyl)pyrrolo[3,4-c]pyrrole-1,4-dione；2,5-dimethyl-1,4-bis[5-[4-(trifluoromethyl)phenyl]thiophen-2-yl]pyrrolo[3,4-c]pyrrole-3,6-dione
• CAS: 1371538-19-0
• 化学式: C₃₀H₁₈F₆N₂O₂S₂
• 分子量: 616.608
• InChiKey: AWGKSMMODWUUKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  42
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  97.1
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  2,5-dihydro-3,6-bis(4-trifluoromethylphenyl-2-thienyl)pyrrolo[3,4-c]pyrrole-1,4-dione 、 碘甲烷 在 potassium tert-butylate 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 7.0h， 以10%的产率得到N,N'-bismethyl-3,6-bis(4-trifuloromethylphenyl-2-thienyl)-1,4-diketopyrrolo[3,4-c]pyrrole
  参考文献：
  名称：

  Synthesis and n-Type Field-effect Transistor Characteristics of Dioxopyrrolopyrrole Derivatives

  摘要：

  研究人员合成了带有抽电子基团的二氧代吡咯衍生物，并将其作为 n 沟道半导体应用于有机场效应晶体管。一种具有分子间氢键网络的衍生物显示出良好的电子迁移率，高达 2.9 × 10-2 cm2 V-1 s-1。

  DOI：

  10.1246/cl.2011.822

文献信息

• N-Type Materials And Organic Electronic Devices
  申请人：Sonar Prashant

  公开号：US20120298976A1

  公开（公告）日：2012-11-29

  There is presently provided organic compounds of formula I, n-type acceptor materials derived from such compounds and devices comprising such n-type acceptor materials. (A n -D p  r A n I

  目前提供了公式I的有机化合物，从这些化合物衍生的n型受体材料以及包含这种n型受体材料的器件。(An-DprAnI)
• SEMICONDUCTORS BASED ON DIKETOPYRROLOPYRROLES
  申请人：WÜRTHNER Frank

  公开号：US20120074393A1

  公开（公告）日：2012-03-29

  The present invention relates to 1,4-diketopyrrolo[3,4-c]pyrrole (DPP) derivatives of the below formula to their manufacture; to their use as organic semiconductors, e.g. in semiconductor devices, especially a sensor, a diode, a photodiode, an organic field effect transistor, a transistor for flexible displays, and/or a solar cell (photovoltaic cell); to such semiconductor devices comprising diketopyrrolopyrrol derivatives of the formula I as a semiconducting effective means, and to devices containing said semiconductor devices. The compounds of the formula I have excellent solubility in organic solvents. High efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when said compounds are used in semiconductor devices or organic photovoltaic (PV) devices.

  本发明涉及以下式的1,4-二酮吡咯并[3,4-c]吡咯（DPP）衍生物的制造方法；将其用作有机半导体，例如在半导体器件中，特别是传感器、二极管、光电二极管、有机场效应晶体管、用于柔性显示器的晶体管和/或太阳能电池（光伏电池）中的半导体器件；以及包含该类半导体器件的设备。式I的化合物在有机溶剂中具有良好的溶解性。当这些化合物用于半导体器件或有机光伏（PV）器件时，可以观察到高效的能量转换、优异的场效应迁移率、良好的开关电流比和/或优异的稳定性。
• INTERFACIAL NANOFIBRIL COMPOSITE FOR SELECTIVE ALKANE VAPOR DETECTION
  申请人：University of Utah Research Foundation

  公开号：US20170122893A1

  公开（公告）日：2017-05-04

  A nanofiber composite sensor for detecting alkanes can include a network of contacting nanofibers having multiple contact points. Each contact point can form an interfiber interface of interdigitated alkyl chains. Alkanes can be adsorbed at the interfiber interface which results in an increased interfiber distance between first and second nanofibers and a decreased charge transfer efficiency. The detected alkanes can be in a vapor or liquid phase.
• Synthesis and n-Type Field-effect Transistor Characteristics of Dioxopyrrolopyrrole Derivatives
  作者：Yuki Suna、Jun-ichi Nishida、Yoshihide Fujisaki、Yoshiro Yamashita

  DOI：10.1246/cl.2011.822

  日期：2011.8.5

  Dioxopyrrolopyrrole derivatives with electron-withdrawing groups have been synthesized and applied to organic field-effect transistors as n-channel semiconductors. A derivative with an intermolecular hydrogen-bonding network showed a good electron mobility up to 2.9 × 10−2 cm2 V−1 s−1.

  研究人员合成了带有抽电子基团的二氧代吡咯衍生物，并将其作为 n 沟道半导体应用于有机场效应晶体管。一种具有分子间氢键网络的衍生物显示出良好的电子迁移率，高达 2.9 × 10-2 cm2 V-1 s-1。