1,2-bis-(o-salicylaldiminophenylthiomethyl)benzene | 152367-74-3

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 1,2-bis-(o-salicylaldiminophenylthiomethyl)benzene
• 英文别名: 1,2-di(o-salicylaldiminophenylthio)xylene；1,2-bis(o-salicylaldiminophenylthio)xylene；2-[[2-[[2-[[2-[(2-Hydroxyphenyl)methylideneamino]phenyl]sulfanylmethyl]phenyl]methylsulfanyl]phenyl]iminomethyl]phenol
• CAS: 152367-74-3
• 化学式: C₃₄H₂₈N₂O₂S₂
• 分子量: 560.741
• InChiKey: RLNFEXIDNWSDKO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  40
• 可旋转键数：
  10
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  116
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  copper(II) perchlorate hexahydrate 、 1,2-bis-(o-salicylaldiminophenylthiomethyl)benzene 以 甲醇 、 氯仿 为溶剂， 生成
  参考文献：
  名称：

  六齿NSO供体配体的配合物-II。1,3-二（邻-水杨基铝基二氨基苯硫基）丙烷和1,2-二（邻-水杨基铝基二氨基苯硫基）二甲苯的铜（II）配合物

  摘要：

  所述六齿二元席夫碱配体1,3-二（ø -salicylaldiminophenylthio）丙烷（H 2 DSALPTP）和1,2-二（ø -salicylaldiminophenylthio）二甲苯（H 2 DSALPTX），用N 2小号2 ö 2供体原子，与铜（II）盐，CuX 2 '· n H 2 O（X'= Cl，NO 3，ClO 4和n（分别为2、3和6），得到的络合物中配体的柔韧性质在其作为一元三齿螯合剂的作用中得以体现，而使一半的配体游离。在所有这些络合物中，铜（II）受体中心都存在于正方形平面环境中，第四个配位位点被氯离子或水分子占据。EPR参数（最低g <2.03）指示其菱形对称性。发现所有络合物在室温下于二氯甲烷溶液中的循环伏安图中均表现出准可逆的Cu III / Cu II对。

  DOI：

  10.1016/0277-5387(95)00110-e

文献信息

• Iron(III) complexes of hexadentate NSO-donor ligands, 1,3-di(o-salicylaldiminophenylthio)propane and 1,2-di(o-salicylaldiminophenylthio)xylene
  作者：Shefali Pal、Sailendra Nath Poddar、Gurucharan Mukherjee

  DOI：10.1016/s0277-5387(00)83071-5

  日期：1993.10

  Iron(III) complexes of hexadentate Schiff base N2S2O2 donor ligands, 1,3-di-(o-salicylaldiminophenylthio)propane (H2DSALPTP) and 1,2-di(o-salicylaldiminophenylthio)xylene (H2DSALPTX) have been synthesized and characterized. The ligands gave dark green iron(III) complexes [Fe(DSALPTP)]FeCl4 and [Fe(DSALPTX)]FeCl4 when reacted with anhydrous FeCl3. The Mossbauer data of these two complexes suggest the presence of two iron sites, one of which is octahedral and the other tetrahedral. The octahedral site is the complex cationic species and the tetrahedral site is the anion FeCl4-. On the other hand, Fe(ClO4)3.6H2O reacted with the ligands to give the complexes [Fe(DSALPTP)]ClO4 and [Fe(DSALPTX)]ClO4. The iron(III) centre in the complex cationic species of the first two complexes are low-spin and for the latter two complexes high-spin. Though a colour change from yellow to green occurred when the ligands reacted with Fe(NO3)3-9H2O, no compound could be isolated in the solid state from the solution.
• Complexes of hexadentate nso donor ligands-III. Nickel(II) complexes of 1,3-di(o-salicylaldiminophenylthio)propane and 1,2-di(o-salicylaldiminophenylthio)xylene
  作者：Shefali Pal、Saktiprosad Ghosh、Gurucharan Mukherjee、Asok Kumar Nandi

  DOI：10.1016/s0277-5387(98)00127-2

  日期：1998.9

  Nickel(II) complexes of the hexadentate N2S2O2 donor ligands, 1,3-di(o-salicylaldiminophenylthio)propane (H(2)DSALPTP) and 1,2-di(o-salicylaldiminophenylthio)xylene (H(2)DSALPTX) have been synthesised and characterised. H(2)DSALPTP reacted with NiCl2.6H(2)O or Ni(ClO4)(2).6H(2)O in presence of ammonia to give the complex [Ni(DSALPTP)] (1). H(2)DSALPTX reacted smoothly with N(ClO4)(2) to yield the corresponding complex [Ni(DSALPTX)] (2). The ligand did not react with NiCl2 in the absence of ammonia but in its presence produced the complex (2). The molecular and crystal structure;of [Ni(DSAL PTX)] exhibits a very unusual deployment of the six donor sites of the ligand. It crystallises in the orthorhombic system with space group P2(1)2(1)2(1). In dichloromethane solution both the complexes are found to exhibit Ni(II)/Ni(III) redox couples in their cyclic voltammograms at room temperature with E-1/2 values 0.87 and 0.78 V (vs. Ag/AgCl). (C) 1998 Elsevier Science Ltd. All rights reserved.