1,4,8,11,15,18,22,25-octa(dodecylthio)phthalocyanine | 344453-63-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 1,4,8,11,15,18,22,25-octa(dodecylthio)phthalocyanine
• 英文别名: 5,8,14,17,23,26,32,35-Octakis(dodecylsulfanyl)-2,11,20,29,37,38,39,40-octazanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28(38),30(37),31,33,35-nonadecaene
• CAS: 344453-63-0
• 化学式: C₁₂₈H₂₁₀N₈S₈
• 分子量: 2117.66
• InChiKey: ZJZGFILLDLJGTR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  55.1
• 重原子数：
  144
• 可旋转键数：
  96
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  311
• 氢给体数：
  2
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  tin(ll) chloride 、 1,4,8,11,15,18,22,25-octa(dodecylthio)phthalocyanine 以 戊醇 为溶剂， 以80%的产率得到dichloro(1,4,8,11,15,18,22,25-octa(dodecylthio)phthalocyaninato)tin(IV)
  参考文献：
  名称：

  Synthesis, electrochemical characterization of tetra- and octa-substituted dodecyl-mercapto tin phthalocyanines in solution and as self-assembled monolayers

  摘要：

  Non-peripherally (alpha) tetra- (9) and octa-(7) substituted dodecyl-mercapto tin(IV) phthalocyanines were synthesized and their electrochemical behavior studied. Cyclic voltammetry and spectroelectrochemistry show ring-based reductions for 7 and 9, the former shows two ring oxidations, while the latter shows only one ring-based oxidation. The adsorption kinetics of (7) and (9) on gold electrode were investigated by electrochemical impedance spectroscopy (EIS). The equilibrium constant (K) for the adsorption and the Gibbs free energy (Delta G(ads)) of the SAMs were evaluated based on the Frumkin isotherm. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2008.08.018

文献信息

• SUBSTITUTED PHTHALOCYANINES AND THEIR PRECURSORS
  申请人：Gentian AS

  公开号：EP1238016A1

  公开（公告）日：2002-09-11
• [EN] SUBSTITUTED PHTHALOCYANINES AND THEIR PRECURSORS<br/>[FR] PHTALOCYANINES SUBSTITUEES ET LEURS PRECURSEURS
  申请人：GENTIAN AS

  公开号：WO2001042368A1

  公开（公告）日：2001-06-14

  This invention relates to a process for the preparation of phthalonitrile sulfonate esters, a process for the preparation of substituted phthalonitriles using said phthalonitrile sulfonate esters, a process for the preparation of substituted phthalocyanines using said substituted phthalonitriles, a process for the preparation of phthalonitrile halides, a process for the preparation of substituted phthalocyanines using said phthalonitrile halides, novel phthalonitrile sulfonate esters, novel substituted phthalonitriles, novel substituted phthalocyanines and certain uses of said novel substituted phthalocyanines.
• [EN] SUBSTITUTED DI(HYDROXY/ALKOXY)SILICON PHTHALOCYANINES AND THEIR USES<br/>[FR] PHTALOCYANINES DE DI(HYDROXY/ALCOXY)SILICIUM SUBSTITUEES ET UTILISATIONS DE CES DERNIERES
  申请人：GENTIAN AS

  公开号：WO2002096913A1

  公开（公告）日：2002-12-05

  This invention relates to certain substituted di(hydroxy/alkoxy)silicon phthalocyanines and certain uses thereof, in particular their uses in photodynamic therapy and in photodiagnostics.