1-methylphosphonane | 80461-84-3

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: 1-methylphosphonane
• CAS: 80461-84-3
• 化学式: C₉H₁₉P
• 分子量: 158.224
• InChiKey: FZRKPTGFFMZXBB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-methyl-3,8-phosphonanedione 1-oxide 在 三氟化硼乙醚 、 苯硅烷 、 镍 作用下， 以 乙醇 为溶剂， 反应 80.0h， 生成 1-methylphosphonane
  参考文献：
  名称：

  Synthesis of phosphonane and dibenzo[d,f]phosphonin derivatives

  摘要：

  DOI：

  10.1021/jo00345a001

文献信息

• PROCESS FOR PRODUCING CARBONYL COMPOUNDS BY DEHYDROGENATION OF ALCOHOLS
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP1160245A1

  公开（公告）日：2001-12-05

  The present invention provides a method for producing a carbonyl compound by dehydrogenating an alcohol. Namely, it relates to a method for producing a carbonyl compound, which comprises dehydrogenating an alcohol in the presence of a complex compound catalyst comprising ruthenium and an organic phosphine wherein aliphatic carbons are bonded to two or more of the three bonding hands of the phosphorus atom.

  本发明提供了一种通过脱氢醇生产羰基化合物的方法。也就是说，本发明涉及一种生产羰基化合物的方法，该方法包括在由钌和有机膦组成的复合催化剂存在下对醇进行脱氢，其中脂肪族碳与磷原子三个键手中的两个或两个以上键手成键。
• GAMMA-BUTYLOLACTONE COMPOSITION AND PRODUCTION METHOD THEREFOR
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3109243A1

  公开（公告）日：2016-12-28

  An object of the present invention is to provide high-purity gamma-butyrolactone (GBL) capable of preventing occurrence of reaction other than the object at the time of use, which reaction is caused due to a high acidity of GBL. The present invention relates to a gamma-butyrolactone composition containing gamma-butyrolactone and a nitrogen-containing compound, wherein a content of the gamma-butyrolactone is 99.0% by mass or more, and a total content of the nitrogen-containing compound is 0.1 ppm by mass to 1,000 ppm by mass as converted to a nitrogen atom.

  本发明的目的是提供高纯度的γ-丁内酯（GBL），能够防止在使用时发生目的之外的反应，这种反应是由于γ-丁内酯的高酸度引起的。本发明涉及一种含有γ-丁内酯和含氮化合物的γ-丁内酯组合物，其中γ-丁内酯的含量为 99.0%（质量分数）或以上，含氮化合物的总含量为 0.1 ppm（质量分数）至 1 000 ppm（质量分数）（转换为氮原子）。
• GAMMA-BUTYROLACTONE COMPOSITION AND METHOD FOR PRODUCING SAME
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP3527559A1

  公开（公告）日：2019-08-21

  An object of the present invention is to provide high-purity gamma-butyrolactone (GBL) capable of preventing occurrence of reaction other than the object at the time of use, which reaction is caused due to a high acidity of GBL. The present invention relates to a gamma-butyrolactone composition containing gamma-butyrolactone and a nitrogen-containing compound, wherein the content of the gamma-butyrolactone is 99.0% by mass or more, and the total content of the nitrogen-containing compound is 0.1 ppm by mass to 1,000 ppm by mass as converted to a nitrogen atom.

  本发明的目的是提供高纯度的γ-丁内酯（GBL），能够防止在使用时发生目的之外的反应，这种反应是由于γ-丁内酯的高酸度引起的。本发明涉及一种含有γ-丁内酯和含氮化合物的γ-丁内酯组合物，其中γ-丁内酯的含量为 99.0%（质量分数）或以上，含氮化合物的总含量为 0.1 ppm（质量分数）至 1 000 ppm（质量分数）（转换为氮原子）。
• Method for producing carbonyl compound by dehydrogenating alcohol
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20020002289A1

  公开（公告）日：2002-01-03

  The present invention provides a method for producing a carbonyl compound by dehydrogenating an alcohol. Namely, it relates to a method for producing a carbonyl compound, which comprises dehydrogenating an alcohol in the presence of a complex compound catalyst comprising ruthenium and an organic phosphine wherein aliphatic carbons are bonded to two or more of the three bonding hands of the phosphorus atom.

  本发明提供了一种通过脱氢醇生产羰基化合物的方法。也就是说，本发明涉及一种生产羰基化合物的方法，该方法包括在由钌和有机膦组成的复合催化剂存在下对醇进行脱氢，其中脂肪族碳与磷原子三个键手中的两个或两个以上键手成键。
• QUIN, L. D.;MIDDLEMAS, E. D.;RAO, N. S., J. ORG. CHEM., 1982, 47, N 6, 905-912
  作者：QUIN, L. D.、MIDDLEMAS, E. D.、RAO, N. S.

  DOI：——

  日期：——