1-(Diphenylphosphoryl)-2,2-dimethylpropan-1-one | 70393-73-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(Diphenylphosphoryl)-2,2-dimethylpropan-1-one
• 英文别名: 1-diphenylphosphoryl-2,2-dimethylpropan-1-one
• CAS: 70393-73-6
• 化学式: C₁₇H₁₉O₂P
• 分子量: 286.3
• InChiKey: DXBAPQHGNIUNMX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-(Diphenylphosphoryl)-2,2-dimethylpropan-1-one 、 水 以72%的产率得到
  参考文献：
  名称：

  LINDNER E.; VORDERMAIER G., CHEM. BER. 1979, 112, NO 4, 1456-1463

  摘要：

  DOI：
• 作为产物：
  描述：

  pivaloyl diphenylphosphine 、 氧气 生成 1-(Diphenylphosphoryl)-2,2-dimethylpropan-1-one
  参考文献：
  名称：

  LINDNER E.; VORDERMAIER G., CHEM. BER. 1979, 112, NO 4, 1456-1463

  摘要：

  DOI：

文献信息

• IMAGE FORMATION METHOD, DECORATIVE SHEET, DECORATIVE SHEET MOLDING, PROCESS FOR PRODUCING IN-MOLD MOLDED PRODUCT, IN-MOLD MOLDED PRODUCT, AND INK SET
  申请人：FUJIFILM Corporation

  公开号：US20150064398A1

  公开（公告）日：2015-03-05

  The object of the present invention is to provide an image formation method that can give an image that is excellent in terms of adhesion to a substrate, blocking resistance of a resulting printed material, and molding suitability, in particular vacuum forming properties, and that can suppress post-molding cracking of a molding. Disclosed is an image formation method comprising, in order, Step a: a step of applying Liquid A to a substrate, Step b: a step of irradiating the applied Liquid A with actinic radiation so as to carry out complete curing or semi-curing up to a degree of cure of at least 90%, Step c: a step of applying Liquid B to a cured layer of the completely cured or semi-cured Liquid A, and Step d: a step of completely curing Liquid A and Liquid B.

  本发明的目的是提供一种图像形成方法，该方法能够给出在粘附于基板、印刷材料的阻塞抵抗性和成型适应性方面表现优异的图像，特别是真空成型性能，并且能够抑制成型后的开裂。揭示了一种图像形成方法，包括以下步骤：步骤a：将液体A涂在基板上；步骤b：用光致辐射照射已涂覆的液体A，以进行完全固化或半固化，直至至少90％的固化度；步骤c：在完全固化或半固化的液体A的固化层上涂覆液体B；步骤d：完全固化液体A和液体B。
• Ink composition, inkjet recording method, printed material, and process for producing lithographic printing plate
  申请人：FUJIFILM Corporation

  公开号：EP1829680A1

  公开（公告）日：2007-09-05

  An ink composition is provided that includes (A) an N-vinyllactam, (B) a radically polymerizable compound, and (C) a polymerization initiator, the content of the N-vinyllactam (A) being at least 10 wt % of the ink total weight, and the content ratio by weight of (A):(B) being 1:8.5 to 1:1. There is also provided an inkjet recording method that includes (a1) a step of discharging the ink composition onto a recording medium and (b1) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation. A printed material recorded by the inkjet recording method is also provided. Furthermore, a process for producing a lithographic printing plate is provided that includes (a2) a step of discharging the ink composition onto a hydrophilic support and (b2) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation so as to form a hydrophobic image on the hydrophilic support by curing the ink composition.

  提供了一种墨水组合物，其中包括 (A)一种 N-乙烯内酰胺、(B)一种可辐射聚合的化合物和 (C)一种聚合引发剂，N-乙烯内酰胺 (A) 的含量至少为墨水总重量的 10 wt %，(A):(B) 的重量含量比为 1:8.5 至 1:1。还提供了一种喷墨记录方法，该方法包括 (a1) 将墨水组合物排放到记录介质上的步骤和 (b1) 通过用阳极辐射照射排放的墨水组合物来固化墨水组合物的步骤。还提供了用喷墨记录方法记录的印刷材料。此外，还提供了一种生产平版印刷板的工艺，该工艺包括 (a2) 将墨水组合物排放到亲水性支撑物上的步骤，以及 (b2) 通过用阳极辐射照射排放的墨水组合物来固化墨水组合物的步骤，以便通过固化墨水组合物在亲水性支撑物上形成疏水性图像。
• Ink set for inkjet recording and inkjet recording method
  申请人：FUJIFILM Corporation

  公开号：EP1958994A1

  公开（公告）日：2008-08-20

  An ink set for inkjet recording is provided that includes at least a colored liquid composition comprising at least a radically polymerizable compound, a photopolymerization initiator, and a colorant, and an undercoat liquid composition comprising at least a radically polymerizable compound and a photopolymerization initiator, the colored liquid composition comprising as the photopolymerization initiator at least one type of α-aminoacetophenone compound, and the undercoat liquid composition comprising as the photopolymerization initiator at least one type of compound selected from the group consisting of an acylphosphine oxide compound, an α-hydroxyacetophenone compound, and an oxime ester compound. There is also provided an inkjet recording method employing the ink set for inkjet recording, the method including a step of applying the undercoat liquid composition on top of a recording medium, a step of semi-curing the undercoat liquid composition, and a step of carrying out image formation by discharging the colored liquid composition on top of the semi-cured undercoat liquid composition.

  本发明提供了一种用于喷墨记录的墨水组，该墨水组至少包括一种彩色液体组合物，该彩色液体组合物至少包含一种可径向聚合的化合物、一种光聚合引发剂和一种着色剂，以及一种底涂液体组合物，该底涂液体组合物至少包含一种可径向聚合的化合物和一种光聚合引发剂、着色液体组合物包含至少一种α-氨基苯乙酮化合物作为光聚合引发剂，底涂层液体组合物包含至少一种选自由酰基氧化膦化合物、α-羟基苯乙酮化合物和肟酯化合物组成的组的化合物作为光聚合引发剂。还提供了一种喷墨记录方法，该方法采用了用于喷墨记录的墨水组，该方法包括在记录介质上涂敷底层液体组合物的步骤、半固化底层液体组合物的步骤，以及通过在半固化底层液体组合物上排放有色液体组合物来形成图像的步骤。
• Ink composition, inkjetrecording method, printed material, method for producing planographic printing plate, and planographic printing plate
  申请人：FUJIFILM Corporation

  公开号：EP1964894A2

  公开（公告）日：2008-09-03

  There are provided an ink composition including at least an initiator, a polymerizable monomer and a polymer comprising a fluorine containing group and a polymerizable group; an inkjet recording method using the ink composition; a printed material recorded by the inkjet recording method; a method of producing a planographic printing plate using the ink composition; and a planographic printing plate obtained by the method of producing a planographic printing plate.

  提供了一种墨水组合物，其中至少包括一种引发剂、一种可聚合单体和一种包含含氟基团和可聚合基团的聚合物；一种使用该墨水组合物的喷墨记录方法；一种通过该喷墨记录方法记录的印刷材料；一种使用该墨水组合物制作平版印刷板的方法；以及一种通过该制作平版印刷板的方法获得的平版印刷板。
• Ink composition, inkjet recording method, printed material, and process for producing molded printed material
  申请人：FUJIFILM Corporation

  公开号：EP2042572A1

  公开（公告）日：2009-04-01

  An ink composition is provided that includes a perfluoroalkyl group-containing polymer, a polymerizable monomer, and a radical polymerization initiator, in which at least 80 wt % of the polymerizable monomer is a monofunctional polymerizable monomer selected from the group consisting of a monofunctional acrylate, a monofunctional methacrylate, a monofunctional vinyloxy compound, a monofunctional N-vinyl compound, a monofunctional acrylamide, and a monofunctional methacrylamide. There are also provided an inkjet recording method that includes a step of discharging the ink composition onto a recording medium and a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation, a printed material obtained by the inkjet recording method, and a process for producing a molded printed material that includes a step of forming an image by discharging the ink composition onto a support by an inkjet method, a step of irradiating the image thus obtained with actinic radiation so as to cure the ink composition and obtain a printed material having the image cured on the support, and a step of molding the printed material.

  提供了一种墨水组合物，它包括含全氟化烷基的聚合物、可聚合单体和自由基聚合引发剂，其中至少80重量％的可聚合单体是从单官能丙烯酸酯、单官能甲基丙烯酸酯、单官能乙烯氧基化合物、单官能N-乙烯基化合物、单官能丙烯酰胺和单官能甲基丙烯酰胺组成的组中选出的单官能可聚合单体。还提供了一种喷墨记录方法，该方法包括将墨水组合物排放到记录介质上的步骤，以及通过用阳极辐射照射排放的墨水组合物来固化墨水组合物的步骤，通过该喷墨记录方法获得的印刷材料、以及一种用于生产模塑印刷材料的工艺，该工艺包括通过喷墨方法将墨水成分排放到支撑物上以形成图像的步骤，用放电辐射照射由此获得的图像以固化墨水成分并获得在支撑物上固化了图像的印刷材料的步骤，以及模塑印刷材料的步骤。