α,ω-bis(5'-bromo-3'-octyl-2,2'-bithien-5-yl)ethane | 325141-88-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: α,ω-bis(5'-bromo-3'-octyl-2,2'-bithien-5-yl)ethane
• 英文别名: 5-bromo-2-[5-[2-[5-(5-bromo-3-octylthiophen-2-yl)thiophen-2-yl]ethyl]thiophen-2-yl]-3-octylthiophene
• CAS: 325141-88-6
• 化学式: C₃₄H₄₄Br₂S₄
• 分子量: 740.795
• InChiKey: SHOPVXDCWRVKQT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.5
• 重原子数：
  40
• 可旋转键数：
  19
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  113
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  α,ω-bis(5'-bromo-3'-octyl-2,2'-bithien-5-yl)ethane 在 四(三苯基膦)钯 copper(l) iodide 、 copper diacetate 、 三乙胺 作用下， 以 吡啶 、 甲醇 、 苯 为溶剂， 反应 36.0h， 生成 13,22,35,44-Tetraoctyl-45,46,47,48,49,50,51,52-octathianonacyclo[40.2.1.12,5.18,11.112,15.120,23.124,27.130,33.134,37]dopentaconta-1(44),2,4,8,10,12,14,20,22,24,26,30,32,34,36,42-hexadecaen-16,18,38,40-tetrayne
  参考文献：
  名称：

  Synthesis and Spectroscopic Properties of [2.2]Quinquethiophenophane as an Ideal π-Dimer Model

  摘要：

  [GRAPGICS]The title compound has been synthesized as the first oligothiophenophane that has the typical stacking structure of a layered cyclophane and can behave as an ideal pi -dimer model.

  DOI：

  10.1021/ol006745r
• 作为产物：
  描述：

  1,2-bis(5-bromo-2-thienyl)ethane 在 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) N-溴代丁二酰亚胺(NBS) 作用下， 以 乙醚 、 氯仿 、 溶剂黄146 为溶剂， 生成 α,ω-bis(5'-bromo-3'-octyl-2,2'-bithien-5-yl)ethane
  参考文献：
  名称：

  Synthesis and Spectroscopic Properties of [2.2]Quinquethiophenophane as an Ideal π-Dimer Model

  摘要：

  [GRAPGICS]The title compound has been synthesized as the first oligothiophenophane that has the typical stacking structure of a layered cyclophane and can behave as an ideal pi -dimer model.

  DOI：

  10.1021/ol006745r

文献信息

• α,ω-Bis(quinquethienyl)alkanes as a π-Dimer Model of Polythiophene
  作者：Teizi Satou、Toyofumi Sakai、Takeshi Kaikawa、Kazuo Takimiya、Tetsuo Otsubo、Yoshio Aso

  DOI：10.1021/ol0499396

  日期：2004.3.1

  [GRAPHICS]A series of the title dimeric quinquethiophenes linked with a di- to hexamethylene spacer was synthesized and examined as a pi-dimer model of polythiophene. Upon two-electron oxidation with iron(III) chloride in dichloromethane, they readily form intramolecular pi-dimer species, except for the dimethylene-linked dimer that cannot be bent into a pi-stacked structure.
• Syntheses, Structures, Spectroscopic Properties, and π-Dimeric Interactions of [<i>n</i>.<i>n</i>]Quinquethiophenophanes
  作者：Toyofumi Sakai、Teizi Satou、Takeshi Kaikawa、Kazuo Takimiya、Tetsuo Otsubo、Yoshio Aso

  DOI：10.1021/ja050783u

  日期：2005.6.1

  A cyclophane-type of dimeric quinquethiophenes (4a-e) with the bridge chains consecutively varying from two to six methylenes has been synthesized and studied as ideal pi-dimer models. The double-decker structures of these compounds are verified by upfield shifts for the proton NMR signals of the inside thiophenes, as compared to those of monomeric dimethylquinquethiophene (3). The electronic absorption and emission spectra of 4a-e are perturbed by through-space g-electronic interactions involving exciton-exciton coupling between the two overlapped quinquethiophenes, which become marked with shortening of the bridged alkylene chains. One-electron oxidation of 4a-e with FeCl3 in dichloromethane results in the appearance of specific polaronic bands in the near-infrared region of the electronic absorption spectra, due to the generation of a radical cation species (polaron) on one of the quinquethiophenes, which electronically interacts with the remaining neutral species. Two-electron oxidation of 4a-e introduces spectral changes, revealing that the resulting two quinquethiophene radical cations readily form an intramolecular,pi-dimer, thanks to their close stacking, in contrast to the difficult formation of an intermolecular pi-dimer from 3. The pi-dimeric spectra of 4b-e are comprised of two strong absorption bands, similar to that of 3, the low-energy band of which is considerably red-shifted by an effective pi-dimeric interaction depending on the lengths of the bridged alkylene chains. Quite different is the spectrum of 4a with three absorption bands inherent in pi-dimer, presumably because the two short bridging chains of 4a force the pi-dimer to take a constrained, strongly interactive structure.