1,3-bis(2-methyloxiran-2-yl)benzene | 17096-86-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-bis(2-methyloxiran-2-yl)benzene
• 英文别名: 2-Methyl-2-[3-(2-methyloxiran-2-yl)phenyl]oxirane
• CAS: 17096-86-5
• 化学式: C₁₂H₁₄O₂
• 分子量: 190.242
• InChiKey: UREMWELOADXCRJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  25.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,3-bis(2-methyloxiran-2-yl)benzene 在 silica-alumina grade 25 作用下， 以 甲苯 为溶剂， 反应 1.0h， 生成 2,2'-(1,3-phenylene)dipropanal
  参考文献：
  名称：

  Method of making a dialdeyhde

  摘要：

  我们发现，使用无定形硅铝催化剂可以将二环氧化物转化为二醛。该方法包括将混合有有机溶剂的二环氧化物与硅铝催化剂接触，形成一个溶剂和二醛反应产物混合物，并从反应混合物中分离出二醛。这些二醛在化学中间体中有用，特别在制造烯醇醚化合物的过程中有用，这些化合物可以用作增塑剂、稀释剂、润湿剂、凝聚助剂以及化学过程中的中间体。

  公开号：

  US10544076B1

文献信息

• Aromatic enol ethers
  申请人：Eastman Chemical Company

  公开号：US10865172B1

  公开（公告）日：2020-12-15

  Disclosed are aromatic enol ethers that have utility as film-hardening additives for coating formulations. The aromatic enol ethers have particular utility as film-hardening additives for water-based coating formulations. The aromatic enol ethers provide improvements in hardness and hardness related properties such as block resistance without contributing to the volatile organic content of the composition.

  本发明涉及芳香烯醇醚，其作为涂料配方的膜硬化添加剂具有实用性。该芳香烯醇醚特别适用于水性涂料配方的膜硬化添加剂。该芳香烯醇醚提供了硬度和硬度相关性质的改进，例如阻塞抵抗力，而不会对组成物的挥发性有机物含量产生贡献。
• Process to make aromatic enol ethers and olefin isomers of aromatic enol ethers
  申请人：Eastman Chemical Company

  公开号：US10865171B1

  公开（公告）日：2020-12-15

  Disclosed is a method for making aromatic enol ethers that have utility as film-hardening additives for coating formulations. The aromatic enol ethers have particular utility as film-hardening additives for water-based coating formulations. The aromatic enol ethers provide improvements in hardness and hardness related properties such as block resistance without contributing to the volatile organic content of the composition.

  本发明公开了一种制备芳香烯醇醚的方法，该方法具有作为涂料配方的膜硬化添加剂的实用性。这种芳香烯醇醚在水性涂料配方中具有特殊的膜硬化添加剂实用性。芳香烯醇醚提供了硬度和硬度相关性能的改善，如阻塞抗性，而不会为组合物贡献挥发性有机物含量。
• Aromatic dicarbinols
  申请人：Eastman Chemical Company

  公开号：US10815179B1

  公开（公告）日：2020-10-27

  Disclosed are aromatic dicarbinol compounds that may have utility in a variety of chemical applications such as plasticizers, diluents, wetting agents and paint additives and as intermediates in chemical processes. The aromatic dicarbinols have particular utility as reactants in processes for the synthesis of aromatic enol ether compounds.

  本发明涉及芳香族二元醇化合物，其在各种化学应用中可能具有用途，例如增塑剂、稀释剂、润湿剂和涂料添加剂以及作为化学过程中间体。这些芳香族二元醇在合成芳香族烯醇醚化合物的过程中作为反应物具有特殊的实用性。
• Process for producing organic compound epoxy resin composition, cured article obtained from the epoxy resin, and semiconductor device obtained with epoxy resin
  申请人：——

  公开号：US20040260039A1

  公开（公告）日：2004-12-23

  There are disclosed a process for producing an organic compound in the presence of a particular substituted triarylphosphine compound, particularly, a process for producing an oxyalkylene derivative at a high yield using the above compound which is very active and easy to handle, by reacting an organic epoxy compound with a carboxylic acid ester, a carboxylic acid anhydride, a sulfonic acid ester or a carbonic acid ester, and an epoxy resin composition using a particular substituted triarylphosphine compound as a curing accelerator, a cured material of the composition and a semiconductor device using the composition.

  本文披露了一种在特定取代三芳基膦化合物存在下生产有机化合物的工艺，特别是一种使用上述化合物作为催化剂，通过将有机环氧化合物与羧酸酯、羧酸酐、磺酸酯或碳酸酯反应，以及使用特定取代三芳基膦化合物作为固化促进剂的环氧树脂组合物的工艺，从而高产地生产氧代烷基衍生物，还包括该组合物的固化材料和使用该组合物的半导体器件。
• RADIATION- OR THERMALLY-CURABLE BARRIER SEALANTS
  申请人：Kong Shengqian

  公开号：US20100164368A1

  公开（公告）日：2010-07-01

  This invention relates to curable sealants that provide low moisture permeability and good adhesive strength after cure. The composition comprises an aromatic compound having meta-substituted reactive groups and a cationic or radical initiator.

  本发明涉及可固化密封剂，其在固化后提供低水分透过率和良好的粘接强度。该组分包括具有间位取代反应基团的芳香化合物和阳离子或自由基引发剂。