methyl 2,2-dimethyl-3-(3-phenyl-1-propenyl)cyclopropanecarboxylate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methyl 2,2-dimethyl-3-(3-phenyl-1-propenyl)cyclopropanecarboxylate
• 英文别名: methyl 2,2-dimethyl-3-[(Z)-3-phenylprop-1-enyl]cyclopropane-1-carboxylate
• 化学式: C₁₆H₂₀O₂
• 分子量: 244.334
• InChiKey: NFAAJGVVRYFFAC-XFFZJAGNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  methyl 2,2-dimethyl-3-[(1E)-3-phenyl-2-formyl-1-propenyl]cyclopropanecarboxylate 在 5%-palladium/activated carbon 作用下， 以 xylene 为溶剂， 反应 7.0h， 以65%的产率得到methyl 2,2-dimethyl-3-(3-phenyl-1-propenyl)cyclopropanecarboxylate
  参考文献：
  名称：

  EP1728781

  摘要：

  公开号：

文献信息

• METHOD FOR PRODUCING OLEFIN COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1970368B1

  公开（公告）日：2012-08-29
• Method for producing (1-alkenyl) cyclopropane compound
  申请人：YOSHIKAWA Koji

  公开号：US20070197818A1

  公开（公告）日：2007-08-23

  A method for producing a (1-alkenyl)cyclopropane compound represented by the formula (2): wherein R 1 and R 2 are the same or different, and independently represent a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group, an optionally substituted aryl group or an optionally substituted aralkyl group, which comprises bringing a (2-formyl-1-alkenyl)cyclopropane compound represented by the formula (1): wherein R 1 and R 2 are the same as defined above, into contact with a palladium catalyst.
• METHOD FOR PRODUCING (2-FORMYL-1-ALKENYL) CYCLOPROPANE COMPOUND
  申请人：YOSHIKAWA Kouji

  公开号：US20090137839A1

  公开（公告）日：2009-05-28

  A method for producing a (2-formyl-1-alkenyl)cyclopropane compound represented by the formula (1): wherein R 1 and R 2 are the same or different, and independently represent a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group, an optionally substituted aryl group or an optionally substituted aralkyl group, which comprises reacting a formylcyclopropane compound represented by the formula (3): wherein R 1 is the same as defined above, with an aldehyde compound represented by the formula (4): wherein R 2 is the same as defined above, in the presence of a base.
• US7498459B2
  申请人：——

  公开号：US7498459B2

  公开（公告）日：2009-03-03
• US7700799B2
  申请人：——

  公开号：US7700799B2

  公开（公告）日：2010-04-20