1-diphenylphosphino-3-ethaneylthiopropane | 29138-51-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-diphenylphosphino-3-ethaneylthiopropane
• 英文别名: 3-Ethylsulfanylpropyl(diphenyl)phosphane
• CAS: 29138-51-0
• 化学式: C₁₇H₂₁PS
• 分子量: 288.394
• InChiKey: ZHXLLVTYKNOSGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  19
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  acethylacetonato(1,5-cyclooctadiene)rhodium(I) 、 1-diphenylphosphino-3-ethaneylthiopropane 在 trityl tetrafluoroborate 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  铑（I）的阳离子配合物，用于末端烯烃均相O 2-氧化为甲基酮的催化剂

  摘要：

  [Rh（LL）2 ] +，[Rh（LL）（二烯）] +和[Rh（LL）S 2 ] +络合物有效地用作末端烯烃的双氧氧化为甲基酮的催化剂。络合物起单加氧酶的作用，第二个氧原子被转移到醇溶剂中。

  DOI：

  10.1016/0022-328x(85)87071-6

文献信息

• Process for the preparation of copolymers of carbon monoxide and ethylenically unsaturated compounds
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0614928A2

  公开（公告）日：1994-09-14

  A process for the preparation of co-polymers by reacting carbon monoxide and one or more ethylenically unsaturated compounds under polymerizable conditions in the substantial absence of a liquid non-polymerizable diluent and in the presence of a catalyst system based on (a) a source of cations of one or more noble metals of Group VIII of the Periodic Table; (b) a source of anions of acids having a pKa of less than 4; (c) a source of cations of one of more metals selected from the group consisting of nickel, cobalt, manganese, lead, zinc, magnesium, iron (II), copper (II), lanthanum and neodymium and (d) a source of bidentate ligands.

  一种用于制备共聚物的工艺，该工艺是在基本不存在液态不可聚合稀释剂的情况下，在可聚合的条件下，使一氧化碳和一种或多种乙烯基不饱和化合物发生反应，该催化剂体系的基础是 (a) 元素周期表第八族的一种或多种贵金属阳离子源； (b) pKa 小于 4 的酸阴离子源； (c) 从镍、钴、锰、铅、锌、镁、铁(II)、铜(II)、镧和钕组成的组中选出的一种或 多种金属的阳离子源；以及 (d) 双齿配体源。
• Gas phase process for the copolymerization of carbon monoxide and ethylenically unsaturated compounds
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0702045A2

  公开（公告）日：1996-03-20

  A gas phase process for the preparation of co-polymers comprising reacting carbon monoxide and an ethylenically unsaturated compound in the presence of a catalyst system based on (a) a source of cations of a metal of Group VIII of the Periodic Table; (b) a source of anions which comprise a plurality of boron atoms or a source of organic boron containing anions or an aluminoxane; and (c) a source of ligands.

  一种制备共聚物的气相工艺，包括一氧化碳和乙烯基不饱和化合物在催化剂系统存在下发生反应，催化剂系统的基础是 (a) 元素周期表第八族金属的阳离子源； (b) 由多个硼原子组成的阴离子源或有机含硼阴离子源或铝氧烷；以及 (c) 配体源。
• Process for the copolymerization of carbon monoxide with an olefinically unsaturated compound
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0733660A1

  公开（公告）日：1996-09-25

  A process for the copolymerization of carbon monoxide with an olefinically unsaturated compound comprising suspending a solid particulate material in a liquid diluent in which the polymer to be produced forms a suspension, and contacting the monomers in the liquid diluent containing the suspended solid particulate material with a catalyst composition which is based on a source of a Group VIII metal and a boron hydrocarbyl compound.

  一种一氧化碳与烯烃不饱和化合物共聚的工艺，包括将固体颗粒材料悬浮在液体稀释剂中，待生产的聚合物在液体稀释剂中形成悬浮液，并将含有悬浮固体颗粒材料的液体稀释剂中的单体与催化剂组合物接触，催化剂组合物基于第八族金属和硼烃基化合物。
• A process for the preparation of a copolymer of carbon monoxide
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0794210A1

  公开（公告）日：1997-09-10

  A process for the copolymerization of carbon monoxide with ethene and optionally another olefinically unsaturated compound in which process the monomers are copolymerized in the presence of a liquid diluent and a catalyst composition which is based on (a) a Group VIII metal compound, (b) an anion of an acid which is obtainable by combining a Brønsted acid with a Lewis acid, and (c) an organic oxidant in a quantity of less than 30 moles per mole of Group VIII metal.

  一种一氧化碳与乙烯和另一种烯烃不饱和化合物共聚的工艺，在该工艺中，单体在一种液体稀释剂和一种催化剂组合物的存在下共聚，该催化剂组合物的基础是 (a) 第 VIII 族金属化合物、 (b) 一种酸的阴离子，该酸可通过将一种布氏酸与一种路易斯酸结合而获得，以及 (c) 一种有机氧化剂，每摩尔 VIII 族金属的含量小于 30 摩尔。
• Process for the preparation of phosphorus-containing compounds and their intermediates
  申请人：SRI International

  公开号：EP1671976A1

  公开（公告）日：2006-06-21

  This invention relates to processes for making phosphorus compounds R2P-X-PR2, R2P-M, R2P-L and R3P, and the novel cation R2P+(L)-X-P+(L)R2, where R represents an optionally substituted hydrocarbyl group, X represents a bridging group, L represents a leaving group and M represents an alkali metal atom. The invention relates further to a process for making a compound R2P-L from a compound R-H via a new process for making the compound R-Li followed by its reaction with a compound Hal2P-L. The compound R2P-X-PR2 is a ligand suitable for making catalysts for copolymerizing carbon monoxide and an olefinically unsaturated compound.

  本发明涉及磷化合物 R2P-X-PR2、R2P-M、R2P-L 和 R3P 的制造工艺，以及新型阳离子 R2P+(L)-X-P+(L)R2，其中 R 代表任选取代的烃基，X 代表桥基，L 代表离去基团，M 代表碱金属原子。本发明还涉及一种由化合物 R-H 通过新工艺制得化合物 R-Li，然后与化合物 Hal2P-L 反应制得化合物 R2P-L 的工艺。化合物 R2P-X-PR2 是一种配体，适用于制造一氧化碳和烯烃不饱和化合物共聚的催化剂。