α-benzyloxyacrylamide | 118770-49-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: α-benzyloxyacrylamide
• 英文别名: 2-Phenylmethoxyprop-2-enamide
• CAS: 118770-49-3
• 化学式: C₁₀H₁₁NO₂
• 分子量: 177.203
• InChiKey: PMZVSHSZVKFXMZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  52.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-benzyloxy-3-bromopropanamide 在 敌草腈 、 potassium carbonate 作用下， 生成 α-benzyloxyacrylamide
  参考文献：
  名称：

  CONTROL OF MOLECULAR WEIGHT AND END GROUP FUNCTIONALITY OF POLYMERS

  摘要：

  公开号：

  EP0333758B1

文献信息

• Non-peptidyl vasopressin V1a antagonists
  申请人：——

  公开号：US20020049187A1

  公开（公告）日：2002-04-25

  This invention provides methods and 2-(azetidin-2-on-1-yl) acetic acid derivatives of Formula I 1 for the antagonism of the vasopressin V 1a receptor.

  本发明提供一种用于拮抗血管加压素V1A受体的方法和公式I1的2-(氮杂环丙酮-2-酮-1-基)乙酸衍生物。
• METHOD OF PRODUCING A LAMINATE COMPRISING A CURED ADHESIVE SHEET
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20160068718A1

  公开（公告）日：2016-03-10

  Problem: To provide a method for producing a laminate comprising a thick, highly transparent cured adhesive sheet exhibiting flow characteristics accompanied by satisfactory fluidity and satisfactory initial adhesion to an adherend before irradiation, and satisfactory hardness (in particular, a high storage modulus) after irradiation. Solution: A method for producing a laminate comprising a first substrate, a second substrate, and a cured adhesive sheet disposed therebetween, the method comprising steps of: forming into a sheet a radiation-curable adhesive sheet precursor comprising a polymer/monomer mixture comprising a partially polymerized (meth) acrylic monomer, a monomer having radiation reactive sites activated by short-wavelength radiation of a first wavelength or less, and a photoinitiator for initiating polymerization of the polymer/monomer mixture and the radiation reactive site-possessing monomer via radiation of a wavelength greater than the first wavelength; irradiating the precursor with radiation of a wavelength greater than the specific wavelength to polymerize the radiation-curable adhesive sheet precursor, forming a radiation-curable adhesive sheet; disposing the radiation-curable adhesive sheet adjacent to at least one surface of the first substrate; disposing the second substrate adjacent to a radiation-curable adhesive sheet; applying heat and/or pressure to the radiation-curable adhesive sheet; and irradiating the radiation-curable adhesive sheet with radiation comprising short-wavelength radiation of a first wavelength or less to obtain a cured adhesive sheet.

  问题：提供一种制备层压板的方法，该层压板包括一种厚的、高透明度的固化粘合片，该粘合片表现出流动性和流动性良好的流动特性，并在照射前对粘附物具有良好的初始粘附性，并在照射后表现出良好的硬度（特别是高储存模量）。 解决方案：一种制备层压板的方法，包括以下步骤：形成一种辐射固化粘合片前体，该前体包括聚合物/单体混合物，其中包括部分聚合的（甲基）丙烯酸单体、一种具有辐射反应位点的单体，该反应位点通过波长小于等于第一波长的短波辐射激活，并且包括光引发剂，用于通过波长大于第一波长的辐射引发聚合物/单体混合物和具有辐射反应位点的单体的聚合反应；用波长大于特定波长的辐射照射前体，以聚合辐射固化粘合片前体，形成一种辐射固化粘合片；将辐射固化粘合片置于第一基底的至少一个表面旁；将第二基底置于辐射固化粘合片旁；对辐射固化粘合片施加热和/或压力；并用包括波长小于等于第一波长的短波辐射的辐射照射辐射固化粘合片，以获得固化的粘合片。
• METHOD OF PRODUCING POLYMERIC LATEX
  申请人：SUMITOMO DOW LIMITED

  公开号：EP0591556A1

  公开（公告）日：1994-04-13

  A method of producing a polymeric latex by emulsifying and polymerizing a polymeric monomer, being characterized in that polymerization is performed by using a polymerizing tank, the polymerizing tank being in turn characterized in that: a stirring shaft (1) adapted to be rotated from the outside of the polymerizing tank is disposed in the central portion of the tank; that a bottom paddle (2) is mounted on the shaft (1), the bottom paddle having a sweep-back angle α of 30 to 60° at the leading end thereof arranged at a tank bottom portion with the lower end portion thereof close to the bottom wall surface of a stirring tank, that a flat paddle (3) is mounted on the stirring shaft (1) at a portion above the bottom paddle (2), the flat paddle having a crossed axes angle β of 40 to 100° relative to the bottom paddle (2) and having a plate-like fin (4) extending downwardly at the leading end thereof, and that a plurality of baffle plates (5) each extending in the axial direction along the sidewall surface of the stirring tank from the lower to upper portion thereof are disposed at certain intervals. This method makes it possible to remarkably reduce the amount of fine solidified substances.

  一种通过乳化和聚合聚合单体生产聚合胶乳的方法，其特征在于聚合是通过使用聚合罐进行的，聚合罐的特征又在于：搅拌轴 (1) 安装在聚合罐的中央部分，可从聚合罐外部旋转；底部桨叶 (2) 安装在搅拌轴 (1) 上，底部桨叶的前端有一个 30 至 60° 的后掠角 α，底部桨叶的下端靠近搅拌槽的底壁表面，平桨叶 (3) 安装在搅拌轴 (1) 上，位于底部桨叶 (2) 的上方、平桨相对于底桨(2)的交叉轴角β为 40 至 100°，其前端有一个向下延伸的板状鳍(4)，在搅拌轴(1)上沿搅拌槽侧壁表面的轴向从下部到上部以一定间距布置多个挡板(5)。这种方法可以显著减少细小凝固物质的数量。
• AQUEOUS EMULSION AND PROCESS FOR PRODUCING THE SAME
  申请人：Nippon Zeon Co., Ltd.

  公开号：EP1090931A1

  公开（公告）日：2001-04-11

  A highly stable aqueous emulsion of a polymer predominantly comprised of units of at least one monomer selected from acrylate esters, methacrylate esters, styrenic monomers and diene monomers, which is dispersion-stabilized with a water-soluble compound having a molecular weight of at least 300 and an alcoholic hydroxyl group; characterized by having an average particle diameter of 0.05 - 5 µm, a calcium chloride chemical stability index of at least 20 and a surface tension of at least 45 mN/m as measured at a solid content of 30 wt.%. The aqueous emulsion is produced by polymerizing a monomer or monomers in the presence of an alcohol and a polymerization initiator generating a peroxide free-radical in an aqueous medium, while the monomer or monomers and the alcoholic hydroxyl group-containing water-soluble compound are incorporated continuously or intermittently into a polymerization system.

  一种高度稳定的聚合物水乳液，主要由至少一种选自丙烯酸酯、甲基丙烯酸酯、苯乙烯单体和二烯单体的单体单元组成，用分子量至少为 300 的水溶性化合物和醇羟基进行分散稳定；其特征是平均颗粒直径为 0.05 - 5 µm，氯化钙化学稳定指数至少为 20，在固体含量为 30 wt.% 时测得的表面张力至少为 45 mN/m。水性乳液是通过在醇和聚合引发剂的存在下，在水性介质中产生过氧化物自由基而使单体聚合，同时将单体和含羟基的醇类水溶性化合物连续或间歇地加入聚合体系中而制成的。
• COATING MATERIAL AND MOLDED ARTICLE
  申请人：Zeon Corporation

  公开号：EP1247851A1

  公开（公告）日：2002-10-09

  By coating a dip-formed article with a coating agent comprising a polymer latex dispersion-stabilized with a water-soluble high-molecular-weight compound containing an alcoholic hydroxyl group, a coated article having excellent donning and putting off properties and anti-blocking property, and exhibiting greatly reduced fine particles-releasability is obtained.

  通过在浸渍成型的物品上涂覆由聚合物乳胶分散体组成的涂层剂，再用含有醇羟基的水溶性高分子量化合物进行稳定，可以获得一种具有优异的穿脱性能和抗阻塞性能的涂层物品，并大大降低了细小颗粒的释放性。