1,3-diisocyano-cyclohexane | 935-26-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 金属杂环化合物
• 英文名称: 1,3-diisocyano-cyclohexane
• 英文别名: cyclohexane-1,3-diyl diisocyanide；1,3-Diisocyanocyclohexane
• CAS: 935-26-2
• 化学式: C₈H₁₀N₂
• 分子量: 134.181
• InChiKey: KIPCQSDBDJLNEO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  8.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,3-diisocyano-cyclohexane 、 苯甲酰异氰酸脂 以 乙醚 、 苯 为溶剂， 生成 1,3-Bis(5-imino-2-phenyloxazolidin-4-yl)cyclohexan
  参考文献：
  名称：

  Neidlein,R., Archiv der Pharmazie und Berichte der Deutschen Pharmazeutischen Gesellschaft, 1965, vol. 298, p. 124 - 130

  摘要：

  DOI：

文献信息

• HYDROSILYLATION REACTION CATALYST
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US20170233417A1

  公开（公告）日：2017-08-17

  A hydrosilylation reaction catalyst prepared from: a catalyst precursor comprising a transition metal compound, excluding platinum, belonging to group 8-10 of the periodic table, e.g., iron acetate, cobalt acetate, nickel acetate, etc.; and a ligand comprising an isocyanide compound such as t-butyl isocyanide. The hydrosilylation reaction catalyst has excellent handling and storage properties. As a result of using this catalyst, a hydrosilylation reaction can be promoted under gentle conditions.

  一种水硅烷基化反应催化剂的制备方法：包括过渡金属化合物的催化剂前体，不包括铂，属于周期表8-10族的过渡金属，例如，醋酸铁、醋酸钴、醋酸镍等；以及包括异氰化合物的配体，例如叔丁基异氰化物。该水硅烷基化反应催化剂具有优异的搅拌和储存性能。使用该催化剂可以在温和条件下促进水硅烷基化反应。
• METHOD FOR PRODUCING TRANSITION METAL-ISOCYANIDE COMPLEX
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US20200071347A1

  公开（公告）日：2020-03-05

  This method is for producing a transition metal complex represented by formula (2), the method comprising reacting a compound containing a transition metal selected from V, Cr, Mo, W, Fe, Ru, Co, Rh, Ni, Pd, and Pt with an isocyanide compound represented by formula (1) in the presence of an alkali metal supported by a solid substance which is insoluble in an organic solvent. This production method can be used to easily and efficiently produce a transition metal complex that includes a predetermined transition metal having an oxidation number of 0 and that has the same or different isocyanide compounds, without using a compound harmful to the human body. (1): (CN) x —R 1 R 1 represents a mono- to tri-valent organic group having 1-30 carbon atoms, and x represents an integer of 1-3}. (2): M 1 a (L) b M 1 represents V, Cr, Mo, W, Fe, Ru, Co, Rh, Ni, Pd, or Pt, and is a zero-valent transition metal, L represents an isocyanide compound represented by formula (1), M 1 and L may be the same or different from each other, “a” represents an integer of 1-8, and b represents an integer of 2-12}.

  这种方法是用于生产由公式（2）表示的过渡金属配合物，该方法包括在不溶于有机溶剂的固体物质的支持下，将含有选自V、Cr、Mo、W、Fe、Ru、Co、Rh、Ni、Pd和Pt的过渡金属的化合物与由公式（1）表示的异腈化合物反应。该生产方法可用于轻松高效地生产包括预定过渡金属的氧化数为0且具有相同或不同异腈化合物的过渡金属配合物，而无需使用对人体有害的化合物。(1)：(CN)x—R1 R1表示具有1-30个碳原子的单价至三价有机基团，x表示1-3的整数}。(2)：M1a(L)bM1表示V、Cr、Mo、W、Fe、Ru、Co、Rh、Ni、Pd或Pt，是零价过渡金属，L表示由公式（1）表示的异腈化合物，M1和L可以相同或不同，“a”表示1-8的整数，而“b”表示2-12的整数}。
• Hydrosilylation reaction catalyst
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US10005797B2

  公开（公告）日：2018-06-26

  A hydrosilylation reaction catalyst prepared from: a catalyst precursor comprising a transition metal compound, excluding platinum, belonging to group 8-10 of the periodic table, e.g., iron acetate, cobalt acetate, nickel acetate, etc.; and a ligand comprising an isocyanide compound such as t-butyl isocyanide. The hydrosilylation reaction catalyst has excellent handling and storage properties. As a result of using this catalyst, a hydrosilylation reaction can be promoted under gentle conditions.

  一种加氢硅烷化反应催化剂，由以下物质制备而成：催化剂前体，包括属于元素周期表第 8-10 族的过渡金属化合物（铂除外），如醋酸铁、醋酸钴、醋酸镍等；以及配体，包括异氰酸酯化合物，如 t-丁基异氰酸酯。加氢硅烷化反应催化剂具有极佳的处理和储存性能。使用这种催化剂，可以在温和的条件下促进加氢硅烷化反应。
• Method for producing transition metal-isocyanide complex
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US11034712B2

  公开（公告）日：2021-06-15

  This method is for producing a transition metal complex represented by formula (2), the method comprising reacting a compound containing a transition metal selected from V, Cr, Mo, W, Fe, Ru, Co, Rh, Ni, Pd, and Pt with an isocyanide compound represented by formula (1) in the presence of an alkali metal supported by a solid substance which is insoluble in an organic solvent. This production method can be used to easily and efficiently produce a transition metal complex that includes a predetermined transition metal having an oxidation number of 0 and that has the same or different isocyanide compounds, without using a compound harmful to the human body. (1): (CN)x—R1 R1 represents a mono- to tri-valent organic group having 1-30 carbon atoms, and x represents an integer of 1-3}. (2): M1a(L)b M1 represents V, Cr, Mo, W, Fe, Ru, Co, Rh, Ni, Pd, or Pt, and is a zero-valent transition metal, L represents an isocyanide compound represented by formula (1), M1 and L may be the same or different from each other, “a” represents an integer of 1-8, and b represents an integer of 2-12}.

  该方法用于生产由式(2)表示的过渡金属络合物，该方法包括使含有选自V、Cr、Mo、W、Fe、Ru、Co、Rh、Ni、Pd和Pt的过渡金属的化合物与由式(1)表示的异氰化合物在碱金属存在下反应，碱金属由不溶于有机溶剂的固体物质支撑。这种生产方法可用于方便、高效地生产过渡金属配合物，其中包括氧化数为 0 的预定过渡金属和具有相同或不同异氰酸化合物的过渡金属配合物，而无需使用对人体有害的化合物。(1):(CN)x-R1 R1代表具有1-30个碳原子的一价至三价有机基团，x代表1-3的整数}。(2):M1a(L)b M1代表V、Cr、Mo、W、Fe、Ru、Co、Rh、Ni、Pd或Pt，是零价过渡金属，L代表式（1）所代表的异氰化物，M1和L可以相同或不同，"a "代表1-8的整数，b代表2-12的整数}。
• Radiation curable acrylated polyurethane oligomer compositions
  申请人：INTEREZ, Inc.(a Delaware corporation)

  公开号：EP0168173B1

  公开（公告）日：1989-01-18