2,6-bis(α-aminoisopropyl)pyridine | 935658-60-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2,6-bis(α-aminoisopropyl)pyridine
• 英文别名: 2,6-C5H3N(CMe2NH2)2；2-[6-(2-Aminopropan-2-yl)pyridin-2-yl]propan-2-amine
• CAS: 935658-60-9
• 化学式: C₁₁H₁₉N₃
• 分子量: 193.292
• InChiKey: PXFOCZRTENWLFG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  64.9
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  氯化铑(三水) 、 2,6-bis(α-aminoisopropyl)pyridine 以 乙醇 为溶剂， 以96%的产率得到mer-[RhCl3(2,6-C5H3N(CMe2NH2)2)]
  参考文献：
  名称：

  Synthesis and exploratory coordination chemistry of the new ditertiary carbinamine ligand 2,6-bis(α-aminoisopropyl)pyridine

  摘要：

  The new pyridine-based N boolean AND N boolean AND N tridentate ligand 2,6-C5H3N(CMe2NH2)(2) (1) was synthesized by the treatment of 2,6-pyridinedicarbonitrile with an excess of the organocerium reagent in situ generated from CeCl3 and methyllithium in THF. The reaction of 1 with [RuCl2(PPh3)(3)] in THF at ambient conditions afforded (OC-6-23)-[RuCl{2,6-C5H3N(CMeNH2)(2)}(PPh3)(2)]Cl (2). The corresponding dimethyl sulfoxide complex [RuCl{2,6-C5H3N(CMe2NH2)(2)} {S(O)Me-2}(2)]Cl (3) was isolated as a mixture of the (OC-6-23) and (OC-632) stercoisonters 3a and 3b from the reaction between 1 and (OC-6-22)-[RuCl2 {S(O)Me-2}(3)(OSMe2)] in toluene at 80 degrees C. A prolonged interaction in toluene at reflux temperature gave isomerically pure 3a. The metal trichloride hydrates MCl3 - xH(2)O (M = Ru, Rh, Ir; x congruent to 2-4) produced mer-[RuCl3{2,6-C5H3N(CMe2NH2)(2)}] (M = Ru: 4; Rh: 5; Ir: 6), when combined with I in refluxing ethanol. The crystal structures of the following compounds were determined: ligand 1 and complexes 2 5 as addition compounds 2 - CH2Cl2, 3a (.) C7H8, ;4 (.) EtOH and 5 (.) 2(1)/2DMF. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.08.025

文献信息

• Ruthenium or Osmium Complexes and Their Uses as Catalysts for Water Oxidation
  申请人：Corbea Javier Jesus Concepcion

  公开号：US20110042227A1

  公开（公告）日：2011-02-24

  The present invention provides ruthenium or osmium complexes and their uses as a catalyst for catalytic water oxidation. Another aspect of the invention provides an electrode and photo-electrochemical cells for electrolysis of water molecules.

  本发明提供了铑或锇配合物及其用作催化水氧化的催化剂。发明的另一个方面提供了用于电解水分子的电极和光电化学电池。
• US8524903B2
  申请人：——

  公开号：US8524903B2

  公开（公告）日：2013-09-03
• US8871078B2
  申请人：——

  公开号：US8871078B2

  公开（公告）日：2014-10-28
• US9359680B2
  申请人：——

  公开号：US9359680B2

  公开（公告）日：2016-06-07
• Synthesis and exploratory coordination chemistry of the new ditertiary carbinamine ligand 2,6-bis(α-aminoisopropyl)pyridine
  作者：Lutz Dahlenburg、Harald Treffert、Jörg Dannhäuser、Frank W. Heinemann

  DOI：10.1016/j.ica.2006.08.025

  日期：2007.4

  The new pyridine-based N boolean AND N boolean AND N tridentate ligand 2,6-C5H3N(CMe2NH2)(2) (1) was synthesized by the treatment of 2,6-pyridinedicarbonitrile with an excess of the organocerium reagent in situ generated from CeCl3 and methyllithium in THF. The reaction of 1 with [RuCl2(PPh3)(3)] in THF at ambient conditions afforded (OC-6-23)-[RuCl2,6-C5H3N(CMeNH2)(2)}(PPh3)(2)]Cl (2). The corresponding dimethyl sulfoxide complex [RuCl2,6-C5H3N(CMe2NH2)(2)} S(O)Me-2}(2)]Cl (3) was isolated as a mixture of the (OC-6-23) and (OC-632) stercoisonters 3a and 3b from the reaction between 1 and (OC-6-22)-[RuCl2 S(O)Me-2}(3)(OSMe2)] in toluene at 80 degrees C. A prolonged interaction in toluene at reflux temperature gave isomerically pure 3a. The metal trichloride hydrates MCl3 - xH(2)O (M = Ru, Rh, Ir; x congruent to 2-4) produced mer-[RuCl32,6-C5H3N(CMe2NH2)(2)}] (M = Ru: 4; Rh: 5; Ir: 6), when combined with I in refluxing ethanol. The crystal structures of the following compounds were determined: ligand 1 and complexes 2 5 as addition compounds 2 - CH2Cl2, 3a (.) C7H8, ;4 (.) EtOH and 5 (.) 2(1)/2DMF. (c) 2006 Elsevier B.V. All rights reserved.