benzenesulfonic acid hexadecyl ester | 131060-12-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzenesulfonic acid hexadecyl ester
• 英文别名: Benzolsulfonsaeure-hexadecylester；hexadecyl benzenesulfonate；hexadecylbenzenesulphonate
• CAS: 131060-12-3
• 化学式: C₂₂H₃₈O₃S
• 分子量: 382.608
• InChiKey: WZXYXXWJPMLRGG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  26
• 可旋转键数：
  17
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  吡啶 、 benzenesulfonic acid hexadecyl ester 生成 1-hexadecyl-pyridinium; benzolsulfate
  参考文献：
  名称：

  Some Alkyl Benzenesulfonates^1,2

  摘要：

  DOI：

  10.1021/ja01138a503

文献信息

• [EN] MULTIVINYLAMINOSILANES AS BRANCHING AGENTS FOR FUNCTIONALIZED ELASTOMERIC POLYMERS<br/>[FR] MULTIVINYLAMINOSILANES UTILISÉS COMME AGENTS DE RAMIFICATION POUR DES POLYMÈRES ÉLASTOMÈRES FONCTIONNALISÉS
  申请人：TRINSEO EUROPE GMBH

  公开号：WO2016131590A1

  公开（公告）日：2016-08-25

  The present invention relates to novel polymerizable multivinylaminosilanes which are useful as branching agents for synthetic and natural rubber. The compounds of the invention can be used as such in the polymerization of conjugated diene monomers, optionally together with aromatic vinyl monomers, thus producing polymers, specifically elastomeric polymers, which can favorably be used in rubber articles such as tires.

  本发明涉及一种新型可聚合的多乙烯胺硅烷，可用作合成和天然橡胶的分支剂。该发明的化合物可直接用于共轭二烯单体的聚合反应中，可选地与芳香族乙烯单体一起使用，从而产生聚合物，特别是弹性聚合物，可有利地用于橡胶制品，如轮胎。
• [EN] AMINOSILANE-FUNCTIONALIZED DIENES FOR USE IN FUNCTIONALIZATION OF ELASTOMERIC POLYMERS<br/>[FR] DIÈNES À FONCTIONNALITÉ AMINOSILANE DESTINÉS À ÊTRE UTILISÉS DANS LA FONCTIONNALISATION DE POLYMÈRES ÉLASTOMÈRES
  申请人：TRINSEO EUROPE GMBH

  公开号：WO2017067877A1

  公开（公告）日：2017-04-27

  The present invention relates to novel aminosiIane-functionalized diene compounds of the following Formula 1; wherein each R' is independently selected from C1-C12 alkyl, C6-C18 aryl, C7-C18 alkylaryl, tri(C1-C6, alkyl, C6-C12 aryl or C7-C18 alkylaryl)silyl and allyl, wherein two R' groups may be connected to form a ring and the ring may contain, further to the Si-bonded nitrogen atom, one or more of an oxygen atom, a nitrogen atom, an >N(C1-C6 alkyl or C7-C18 alkylaryl) group and a sulfur atom: each R" is independently selected from C1-C6 hydrocarbyl; Ra, Rb Rc, Rd and Re are independently selected from hydrogen, methyl and ethyl; x is an integer selected from 0, 1 and 2, y is an integer selected from 1, 2 and 3 and x + y = 3. The diene compounds are useful as modifying monomers in the polymerization of conjugated diene monomers, optionally together with aromatic vinyl monomers, thus producing polymers, specifically elastomeric polymers, which can favorably be used in rubber articles such as tires. The present invention further relates to a process for preparing said diene compounds, a process for preparing an elastomeric polymer, involving the use of said diene compounds, the thus-obtainable elastomeric polymer, a non-cured or cured (vulcanized ) polymer composition including said elastomeric polymer, a method of making the vulcanized polymer composition, and an article comprising a component formed from the vulcanized polymer composition.

  本发明涉及以下式子1的新型氨基硅烷官能化二烯化合物；其中每个R'独立选择自C1-C12烷基，C6-C18芳基，C7-C18烷基芳基，三(C1-C6烷基，C6-C12芳基或C7-C18烷基芳基)硅基和烯丙基，其中两个R'基团可以连接形成环，并且该环可能包含除了硅键合氮原子外的一个或多个氧原子，氮原子，>N(C1-C6烷基或C7-C18烷基芳基)基团和硫原子：每个R"独立选择自C1-C6烃基；Ra，Rb，Rc，Rd和Re独立选择自氢，甲基和乙基；x是选择自0、1和2的整数，y是选择自1、2和3的整数，并且x+y=3。该二烯化合物在共轭二烯单体的聚合中作为改性单体有用，可选与芳香族乙烯单体一起使用，从而产生聚合物，特别是弹性聚合物，可有利地用于橡胶制品，如轮胎。本发明还涉及制备所述二烯化合物的方法，涉及使用所述二烯化合物的弹性聚合物的制备方法，涉及得到的弹性聚合物，包括所述弹性聚合物的未固化或固化（硫化）聚合物组合物，制备硫化聚合物组合物的方法，以及包括从硫化聚合物组合物形成的组件的物品。
• Vinylsilanes for Use in Functionalized Elastomeric Polymers
  申请人：TRINSEO EUROPE GMBH

  公开号：US20160264601A1

  公开（公告）日：2016-09-15

  The present invention relates to novel vinylsilane compounds which are useful as modifying monomers in the polymerization of conjugated diene monomers, optionally together with aromatic vinyl monomers, thus producing polymers, specifically elastomeric polymers, which can favorably be used in rubber articles such as tires.

  本发明涉及一种新型的乙烯基硅烷化合物，其可用作共轭二烯单体的改性单体，在与芳香族乙烯单体一起聚合的过程中，生成聚合物，特别是弹性聚合物，可优选用于橡胶制品，如轮胎。
• Peroxygen bleaching and compositions therefor
  申请人：FMC Corporation

  公开号：EP0001495A1

  公开（公告）日：1979-04-18

  A process of removing soil and/or stains from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator a phenyl sulfonate ester of the formula: wherein R is selected from the class consisting of a hydrocarbon radical of 1 to 16 carbon atoms and a heterocyclic radical having 1 ring or 2 fused rings, said ring or rings containing 5 to 6 members of which 1 to 2 are heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur; X is hydrogen or at least one electron withdrawing substituent and n is an integer of from 1 to 5. Also described are dry blend compositions containing the bleach bath components.

  一种去除织物上的污垢和/或污渍的工艺，方法是将织物浸入过氧漂白浴中，过氧漂白浴中的过氧活化剂是式中的苯磺酸酯： 其中 R 选自 1 至 16 个碳原子的烃基和具有 1 个环或 2 个融合环的杂环基，所述环或环含有 5 至 6 个成员，其中 1 至 2 个为杂原子，选自氮、氧和硫组成的组；X 为氢或至少一个取电子取代基，n 为 1 至 5 的整数。还描述了含有漂白浴成分的干混组合物。
• Peroxygen containing compositions and bleaching process
  申请人：FMC Corporation

  公开号：EP0009998A1

  公开（公告）日：1980-04-16

  Soil and/or stains are/is removed from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator an N-sulfonyl-azole of the formula: where Z represents the number of carbon and nitrogen atoms necessary to complete a pyrazole, pyrrole, triazole, or benzotriazole ring, in which the ring can be substituted with phenyl, C1-10 alkyl, halogen, amino, cyano, nitro or C1-10 alkoxy and R is a C1-10 alkyl radical. Peroxygen-containing compositions contain a peroxygen compound and an N-sulfonylazole compound as defined above and may also optionally contain one or more of a detergent, water, a buffering agent and a detergency builder.

  将织物浸泡在含有过氧活化剂 N-磺酰基唑的过氧漂白浴中，可去除织物上的污垢和/或污渍： 式中 Z 代表完成吡唑、吡咯、三唑或苯并三唑环所需的碳原子和氮原子数，其中环可被苯基、C1-10 烷基、卤素、氨基、氰基、硝基或 C1-10 烷氧基取代，R 为 C1-10 烷基。 含过氧化合物包含过氧化合物和如上定义的 N-磺酰基唑化合物，还可选择包含一种或多种洗涤剂、水、缓冲剂和去污剂。