N-[(4-N,N-bis(2'-cyanoethyl)aminobenzylidene)-amino]benzene | 56133-54-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-[(4-N,N-bis(2'-cyanoethyl)aminobenzylidene)-amino]benzene
• 英文别名: N,N-Bis(2-cyanoethyl)-alpha-phenylimino-P-toluidine；3-[N-(2-cyanoethyl)-4-(phenyliminomethyl)anilino]propanenitrile
• CAS: 56133-54-1
• 化学式: C₁₉H₁₈N₄
• 分子量: 302.379
• InChiKey: GEWVPFPUUZSDFJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  23
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  63.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N-[(4-N,N-bis(2'-cyanoethyl)aminobenzylidene)-amino]benzene 、 uranyl acetate 以 异丙醇 为溶剂， 以90%的产率得到bis(N-[(4-N,N-bis(2'-cyanoethyl)aminobenzylidene)-amino]benzene)dioxouranium(VI) acetate
  参考文献：
  名称：

  STUDIES ON HIGH-COORDINATION COMPLEXES OF DIOXOURANIUM(VI) WITH A SCHIFF BASE

  摘要：

  A new series of six complexes of dioxouranium(VI) with the Schiff base N-[(4-N,N-bis-(2'-cyanoethyl)aminobenzylidene)amino]benzene (L) derived from 4-N,N-bis-(2'-cyanoethyl)aminobenzaldehyde and aniline and having the general compositions UO2X2L2 (X = Br, I, NCS, CH3COO or NO3) and UO2X2L4 (X = ClO4) were prepared: The complexes were characterized on the basis of elemental analyses, molecular weight measurements, conductivity measurements and infrared spectroscopy. X-ray powder diffraction data of two representative complexes are also presented. In all of these complexes the Schiff base ligand behaves as a monodentate neutral ligand which coordinates to the metal via the azomethine nitrogen atom. On the basis of the analyses the probable coordination number either 6 or 8 for U(VI) is suggested depending upon the nature of the anion present.

  DOI：

  10.1081/sim-120005611

文献信息

• STUDIES ON HIGH-COORDINATION COMPLEXES OF DIOXOURANIUM(VI) WITH A SCHIFF BASE
  作者：Kishor Arora、Sharma K.P.

  DOI：10.1081/sim-120005611

  日期：2002.11.7

  A new series of six complexes of dioxouranium(VI) with the Schiff base N-[(4-N,N-bis-(2'-cyanoethyl)aminobenzylidene)amino]benzene (L) derived from 4-N,N-bis-(2'-cyanoethyl)aminobenzaldehyde and aniline and having the general compositions UO2X2L2 (X = Br, I, NCS, CH3COO or NO3) and UO2X2L4 (X = ClO4) were prepared: The complexes were characterized on the basis of elemental analyses, molecular weight measurements, conductivity measurements and infrared spectroscopy. X-ray powder diffraction data of two representative complexes are also presented. In all of these complexes the Schiff base ligand behaves as a monodentate neutral ligand which coordinates to the metal via the azomethine nitrogen atom. On the basis of the analyses the probable coordination number either 6 or 8 for U(VI) is suggested depending upon the nature of the anion present.