diphenyl(9-fluorenyl)phosphine sulfide | 54458-21-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: diphenyl(9-fluorenyl)phosphine sulfide
• 英文别名: Diphenylfluorenylphosphinsulfid；9H-fluoren-9-yl-diphenyl-sulfanylidene-lambda5-phosphane；9H-fluoren-9-yl-diphenyl-sulfanylidene-λ5-phosphane
• CAS: 54458-21-8
• 化学式: C₂₅H₁₉PS
• 分子量: 382.466
• InChiKey: CTHFCVMTCIKZPT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  27
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  32.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  diphenyl(9-fluorenyl)phosphine 在 sulfur 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以72%的产率得到diphenyl(9-fluorenyl)phosphine sulfide
  参考文献：
  名称：

  New Halo Compounds of Si, P, As, AND Sb Bearing a Bulky Substituted Fluorenyl Group

  摘要：

  New halo compounds of Si, P, As, and Sb potential precursors of doubly-bonded derivatives of these elements, have been synthesized: dichloro-and difluorosilanes 2-6 bearing a methylfluorenyl group and a second substituent of various size (Me, Ph, Mes, R2CMe); dichlorophosphines 13 and 14, fluoro- and difluoroarsines 15 and 16 and fluorostibine 17, substituted by the diphenyl (or dimesityl) phosphinofluorenyl group. Phosphine oxide and sulfide 9 and 10 also have been prepared.

  DOI：

  10.1080/10426500390228639

文献信息

• New Halo Compounds of Si, P, As, AND Sb Bearing a Bulky Substituted Fluorenyl Group
  作者：L. Baiget、M. Bouslikhane、J. Escudie、G. Cretiu Nemes、I. Silaghi-Dumitrescu、L. Silaghi-Dumitrescu

  DOI：10.1080/10426500390228639

  日期：2003.9.1

  New halo compounds of Si, P, As, and Sb potential precursors of doubly-bonded derivatives of these elements, have been synthesized: dichloro-and difluorosilanes 2-6 bearing a methylfluorenyl group and a second substituent of various size (Me, Ph, Mes, R2CMe); dichlorophosphines 13 and 14, fluoro- and difluoroarsines 15 and 16 and fluorostibine 17, substituted by the diphenyl (or dimesityl) phosphinofluorenyl group. Phosphine oxide and sulfide 9 and 10 also have been prepared.