异十三胺 | 35723-81-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 异十三胺
• 中文别名: 异三癸胺
• 英文名称: isotridecyl amine
• 英文别名: i-tridecylamine；Isotridecanamine；11-methyldodecan-1-amine
• CAS: 35723-81-0
• 化学式: C₁₃H₂₉N
• mdl: MFCD00044079
• 分子量: 199.38
• InChiKey: NGKIIKNJVVBNNE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  14
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  异十三胺 、 3-氯丙烯 反应 5.0h， 生成 isotridecyl allyl amine
  参考文献：
  名称：

  ANIONIC-CATIONIC-NONIONIC SURFACTANT,PRODUCTION AND USE THEREOF

  摘要：

  这项发明涉及一种阴离子-阳离子-非离子表面活性剂，其大致由式(I)所代表，以及该表面活性剂在三次采油中的生产和使用。该发明的阴离子-阳离子-非离子表面活性剂与现有技术相比具有明显改善的界面活性和稳定性。采用这种阴离子-阳离子-非离子表面活性剂，可以制备出用于三次采油的注水液组成物，其具有比现有技术更高的油位移效率和油洗能力。在式(I)中，每个基团如规范中所定义。

  公开号：

  US20170313928A1

文献信息

• Carbamates from Glycerine Carbonate for Pearlization
  申请人：Evonik Industries AG

  公开号：US20150044264A1

  公开（公告）日：2015-02-12

  Alkyl and/or alkenyl glycerol carbamate prepared by reacting a carbonate selected from the group consisting of glycerol carbonate, diglycerol carbonate, polyglycerol carbonate and mixtures thereof, with an amine of the general formula (I): HNR 1 R 2 (I) wherein R 1 represents a hydrogen atom or a hydrocarbon group selected from the group consisting of alkyl groups and alkenyl groups having from 1 to 22 carbon atoms and R 2 represents a hydrocarbon group selected from the group consisting of alkyl groups and alkenyl groups having from 4 to 22 carbon atoms, and cyclic alkyl groups having 5 or 6 carbon atoms, are described along with methods for their use as pearlizing agents in surface-active preparations.

  通过将选自由甘油碳酸酯、二甘油碳酸酯、多甘油碳酸酯和其混合物的碳酸酯与通式（I）的胺反应制备烷基和/或烯基甘油氨基甲酸酯，其中R1表示氢原子或由1到22个碳原子的烷基和烯基基团组成的羟基碳基，R2表示由4到22个碳原子的烷基和烯基基团以及具有5或6个碳原子的环烷基组成的羟基碳基。同时还描述了它们作为表面活性制剂中珠光剂的使用方法。
• Ethylenically unsaturated monomers for thickener compositions
  申请人：Bobsein Barrett Richard

  公开号：US20100286434A1

  公开（公告）日：2010-11-11

  New ethylenically unsaturated monomers are provided that can be (co)polymerized to provide a composition and method whereby the same group that is attached to or within the backbone of an associative thickener is reversibly switched between being hydrophilic and hydrophobic in nature. When the group that is attached to or within the backbone is rendered hydrophilic, the aqueous thickener is pourable and readily incorporated into aqueous polymer compositions. When this group is rendered hydrophobic, the thickener performs its thickening function efficiently. Switching is readily accomplished by adjusting the pH of the associative thickener composition and the aqueous polymer composition being thickened. The thickeners are prepared from the novel monomers by an aqueous solution polymerization.

  提供了新的具有乙烯基不饱和性的单体，可以进行(共)聚合以提供一种组合物和方法，其中连接到或在联合增稠剂骨架内的相同基团在亲水性和疏水性之间可逆地切换。当连接到或在骨架内的基团变为亲水性时，水性增稠剂是可倾倒的，并且容易与水性聚合物组成物混合。当这个基团变为疏水性时，增稠剂有效地执行其增稠功能。通过调整联合增稠剂组合物和被增稠的水性聚合物组成物的pH值，可以轻松实现切换。这些增稠剂通过水溶液聚合从新单体制备而成。
• AMINOMETHYL- SUBSTITUTED IMIDAZOLE COMPOUNDS FOR USE AS FRICTION MODIFIERS IN LUBRICATING OIL COMPOSITIONS
  申请人：Suen Yat Fan

  公开号：US20110136710A1

  公开（公告）日：2011-06-09

  Disclosed are aminomethyl-substituted imidazole compounds and their use as friction modifiers in lubricating oils. Also disclosed is a process for preparing the aminomethyl-substituted imidazole compounds. A further aspect is directed to a lubricating oil composition and a lubricating oil additive concentrate having the aminomethyl-substituted imidazole compounds of the present invention.

  本发明公开了氨甲基取代咪唑化合物及其在润滑油中作为摩擦改性剂的用途。还公开了制备氨甲基取代咪唑化合物的方法。另一个方面涉及到一种润滑油组合物和润滑油添加剂浓缩物，其具有本发明中的氨甲基取代咪唑化合物。
• Thickener composition and method for thickening aqueous systems
  申请人：Bobsein Barrett Richard

  公开号：US20100261813A1

  公开（公告）日：2010-10-14

  A composition and method whereby the same group that is attached to or within the backbone of an associative thickener is reversibly switched between being hydrophilic and hydrophobic in nature. The group comprises a tertiary amine, or tertiary phosphine and has a hydrocarbon radical bonded to the amine nitrogen atom or phosphine phosphorus atom, which hydrocarbon radical is pendant to the backbone and contains fewer than 10 carbon atoms. When the group that is attached to or within the backbone is rendered hydrophilic, the aqueous thickener is pourable and readily incorporated into aqueous polymer compositions. When this group is rendered hydrophobic, the thickener performs its thickening function efficiently. Switching is readily accomplished by adjusting the pH of the associative thickener composition and the aqueous polymer composition being thickened.

  一种构成和方法，其中与关联增稠剂的主干相连或内部的相同基团可在亲水性和疏水性之间可逆地切换。该基团包括三级胺或三级膦，并且具有与胺氮原子或膦磷原子结合的碳氢基团，该碳氢基团悬挂于主干上并且含有少于10个碳原子。当与主干相连的基团变为亲水性时，水性增稠剂是可倾倒的并且容易混合在水性聚合物组合物中。当这个基团变为疏水性时，增稠剂有效地完成其增稠功能。通过调整关联增稠剂组合物和被增稠的水性聚合物组合物的pH值，可轻松实现切换。
• Verfahren zur Herstellung von Diaminen
  申请人：Ruhrchemie Aktiengesellschaft

  公开号：EP0005856A2

  公开（公告）日：1979-12-12

  Die Erfindung betrifft die Herstellung von aliphatischen und cycloaliphatischen Diaminen durch einen 2-Stufen-Prozeß. Hierbei werden in der 1. Stufe Dialdehyde mit Monoaminen zu den entsprechenden Diazomethinen umgesetzt. In der 2. Stufe werden diese Diazomethine mit Ammoniak und Wasserstoff in Gegenwart eines Hydrierkatalysators zur Umsetzung gebracht.

  本发明涉及采用两步法生产脂肪族和环脂族二胺。在第一阶段，二醛与一胺反应生成相应的重氮甲胺。在第二阶段，这些重氮甲胺在氢化催化剂的作用下与氨和氢发生反应。