5,5,19,19,33,33-Hexamethylnonacyclo[18.15.0.02,18.04,16.06,15.09,14.022,34.023,32.024,29]pentatriaconta-1(35),2,4(16),6(15),7,9,11,13,17,20,22(34),23(32),24,26,28,30-hexadecaene-8,30-dicarbonitrile

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 5,5,19,19,33,33-Hexamethylnonacyclo[18.15.0.02,18.04,16.06,15.09,14.022,34.023,32.024,29]pentatriaconta-1(35),2,4(16),6(15),7,9,11,13,17,20,22(34),23(32),24,26,28,30-hexadecaene-8,30-dicarbonitrile
• 英文别名: 5,5,19,19,33,33-hexamethylnonacyclo[18.15.0.02,18.04,16.06,15.09,14.022,34.023,32.024,29]pentatriaconta-1(35),2,4(16),6(15),7,9,11,13,17,20,22(34),23(32),24,26,28,30-hexadecaene-8,30-dicarbonitrile
• 化学式: C₄₃H₃₂N₂
• 分子量: 576.74
• InChiKey: YJTYKEJQMAHMOA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.4
• 重原子数：
  45
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  potassiumhexacyanoferrate(II) trihydrate 、 8,30-Dibromo-5,5,19,19,33,33-hexamethylnonacyclo[18.15.0.02,18.04,16.06,15.09,14.022,34.023,32.024,29]pentatriaconta-1(35),2,4(16),6(15),7,9,11,13,17,20,22(34),23(32),24,26,28,30-hexadecaene 在 2-双环己基膦-2',6'-二甲氧基联苯 、 palladium diacetate 、 sodium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以17.5%的产率得到5,5,19,19,33,33-Hexamethylnonacyclo[18.15.0.02,18.04,16.06,15.09,14.022,34.023,32.024,29]pentatriaconta-1(35),2,4(16),6(15),7,9,11,13,17,20,22(34),23(32),24,26,28,30-hexadecaene-8,30-dicarbonitrile
  参考文献：
  名称：

  用于电子器件的材料

  摘要：

  本发明涉及具有苯并茚并芴基体的化合物和涉及其在电子器件中、特别是在有机电致发光器件中的用途。

  公开号：

  CN105636944B

文献信息

• Materials for electronic devices
  申请人：Merck Patent GmbH

  公开号：US10559756B2

  公开（公告）日：2020-02-11

  The invention relates to compounds with benzindenofluorene base bodies having a structure of formula (I): and to the use thereof in electronic devices, in particular in organic electroluminescent devices.

  本发明涉及具有式 (I) 结构的苯并茚满芴基体化合物： 并将其用于电子设备，特别是有机电致发光设备。
• Materials for Electronic Devices
  申请人：MERCK PATENT GMBH

  公开号：US20160254456A1

  公开（公告）日：2016-09-01

  The invention relates to compounds with benzindenofluorene base bodies and to the use thereof in electronic devices, in particular in organic electroluminescent devices.
• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20190319194A1

  公开（公告）日：2019-10-17

  A composition formed of a mixture of two compounds having similar thermal evaporation properties that are pre-mixed into an evaporation source that can be used to co-evaporate the two compounds into an emission layer in OLEDs via vacuum thermal evaporation process is disclosed. The first and second compounds can have an evaporation temperature T 1 and T 2 , respectively, of 150 to 350° C., and the absolute value of T 1 -T 2 can be less than 20° C. The first compound can have a concentration C 1 in the mixture and a concentration C 2 in a film formed by evaporating the mixture in a vacuum deposition tool at a constant pressure between 1×10 −6 Torr to 1×10 −9 Torr, at a 2 Å/sec deposition rate on a surface positioned at a predefined distance away from the mixture being evaporated, where the absolute value of (C 1 −C 2 )/C 1 is less than 5%.
• [DE] MATERIALIEN FÜR ELEKTRONISCHE VORRICHTUNGEN<br/>[EN] MATERIALS FOR ELECTRONIC DEVICES<br/>[FR] MATÉRIAUX POUR DISPOSITIFS ÉLECTRONIQUES
  申请人：MERCK PATENT GMBH

  公开号：WO2014111269A2

  公开（公告）日：2014-07-24

  Die vorliegende Anmeldung betrifft Verbindungen mit Benzindenofluoren- Grundkörper und ihre Verwendung in elektronischen Vorrichtungen, insbesondere in organischen Elektrolumineszenzvorrichtungen.