9-[4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl]-N,N-diphenylcarbazol-3-amine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 9-[4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl]-N,N-diphenylcarbazol-3-amine
• 化学式: C₄₅H₃₁N₅
• 分子量: 641.775
• InChiKey: JNZDKQMSQUUXOG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.3
• 重原子数：
  50
• 可旋转键数：
  7
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  46.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  9-（4-（4,6-二苯基-1,3,5-三嗪-2-基）苯基）-9H-咔唑 在 N-碘代丁二酰亚胺 、 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 14.0h， 生成 9-[4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl]-N,N-diphenylcarbazol-3-amine
  参考文献：
  名称：

  一种三嗪类组合物及其制备方法和应用

  摘要：

  本发明提供一种三嗪类组合物及其制备方法和应用。所述制备方法包括如下步骤：(1)式M0所示化合物发生碘代反应，得到式M所示中间体化合物；(2)式M所示中间体化合物与硼酸类化合物或二芳胺类化合物反应，得到三嗪类组合物。本发明中通过对三嗪类组合物的制备方法进行设计，制备得到的三嗪类组合物中三嗪类化合物的纯度较高，适用作制备有机电致发光器件的有机薄膜层材料。

  公开号：

  CN115073428A

文献信息

• Organic electroluminescent element
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US10297761B2

  公开（公告）日：2019-05-21

  An organic electroluminescence device includes: an anode; a cathode; and a single- or multi-layer organic layer interposed between the anode and the cathode. The organic layer includes at least one emitting layer containing a dopant material represented by a formula below. In the formula, X1 to X5 each independently represent CR1 or a nitrogen atom, at least one of X1 to X5 is a nitrogen atom, L1 represents a divalent aromatic hydrocarbon group or a divalent heterocyclic group, A and B each independently represents a cyclic structure, at least one of the cyclic structure A and the cyclic structure B has a substituent, and R1 represents an aryl group, alkyl group or the like.

  一种有机电致发光器件包括：阳极；阴极；以及置于阳极和阴极之间的单层或多层有机层。有机层包括至少一个发射层，其中含有下式表示的掺杂材料。式中，X1 至 X5 各自独立地代表 CR1 或氮原子，X1 至 X5 中至少有一个是氮原子，L1 代表二价芳烃基团或二价杂环基团，A 和 B 各自独立地代表环状结构，环状结构 A 和环状结构 B 中至少有一个具有取代基，R1 代表芳基、烷基或类似基团。
• Organic electroluminescent materials and devices
  申请人：Universal Display Corporation

  公开号：US10381569B2

  公开（公告）日：2019-08-13

  A composition formed of a mixture of two compounds having similar thermal evaporation properties that are pre-mixed into an evaporation source that can be used to co-evaporate the two compounds into an emission layer in OLEDs via vacuum thermal evaporation process is disclosed. The first and second compounds can have an evaporation temperature T1 and T2, respectively, of 150 to 350° C., and the absolute value of T1−T2 can be less than 20° C. The first compound can have a concentration C1 in the mixture and a concentration C2 in a film formed by evaporating the mixture in a vacuum deposition tool at a constant pressure between 1×10−6 Torr to 1×10−9 Torr, at a 2 Å/sec deposition rate on a surface positioned at a predefined distance away from the mixture being evaporated, where the absolute value of (C1−C2)/C1 is less than 5%.

  本发明公开了一种由两种具有相似热蒸发特性的化合物的混合物组成的组合物，这两种化合物预先混合到蒸发源中，可用于通过真空热蒸发工艺将这两种化合物共同蒸发到 OLED 的发射层中。第一种和第二种化合物的蒸发温度 T1 和 T2 可分别为 150 至 350 摄氏度、第一种化合物在混合物中的浓度为 C1，而在真空沉积工具中以 1×10-6 托至 1×10-9 托的恒定压力、2 Å/秒的沉积速率、在距离被蒸发混合物预定距离的表面上蒸发混合物而形成的薄膜中的浓度为 C2，其中 (C1-C2)/C1 的绝对值小于 5%。
• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20160060251A1

  公开（公告）日：2016-03-03

  Novel carbazole-containing compounds are provided. The novel compounds also contain electron donor groups, aryl linkers, and at least one nitrogen heterocycle. These novel organic compounds are useful in OLED devices and can exhibit delayed fluorescence.
• ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20160197286A1

  公开（公告）日：2016-07-07

  An organic electroluminescence device includes: an anode; a cathode; and a single- or multi-layer organic layer interposed between the anode and the cathode. The organic layer includes at least one emitting layer containing a dopant material represented by a formula below. In the formula, X 1 to X 5 each independently represent CR 1 or a nitrogen atom, at least one of X 1 to X 5 is a nitrogen atom, L 1 represents a divalent aromatic hydrocarbon group or a divalent heterocyclic group, A and B each independently represents a cyclic structure, at least one of the cyclic structure A and the cyclic structure B has a substituent, and R 1 represents an aryl group, alkyl group or the like.
• Compound, Organic Electroluminescent Device Containing Same and Application Thereof
  申请人：BEIJING ETERNAL MATERIAL TECHNOLOGY CO., LTD

  公开号：US20220158095A1

  公开（公告）日：2022-05-19

  A compound, an organic electroluminescent device containing the compound, and an application thereof. The compound has a structure shown in (I).