8-Methyl-4-azafluoren | 64292-00-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 8-Methyl-4-azafluoren
• 英文别名: 8-Methyl-4-azafluorene；6-methyl-5H-indeno[1,2-b]pyridine
• CAS: 64292-00-8
• 化学式: C₁₃H₁₁N
• 分子量: 181.237
• InChiKey: FWSZAJLJLOCOCA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  8-Methyl-4-azafluoren 、 potassium permanganate 以45%的产率得到
  参考文献：
  名称：

  PROSTAKOV N. S.; PLESHAKOV V. G.; SEJTEMBETOV T. S.; FESENKO D. A.; ONASA+, ZH. ORGAN. XIMII, 1977, 13, 7, 1484-

  摘要：

  DOI：
• 作为产物：
  描述：

  3-methyl-2-(3-methylphenyl)pyridine 以3%的产率得到
  参考文献：
  名称：

  PROSTAKOV N. S.; PLESHAKOV V. G.; SEJTEMBETOV T. S.; FESENKO D. A.; ONASA+, ZH. ORGAN. XIMII, 1977, 13, 7, 1484-

  摘要：

  DOI：

文献信息

• Scope of regioselective Suzuki reactions in the synthesis of arylpyridines and benzylpyridines and subsequent intramolecular cyclizations to azafluorenes and azafluorenones
  作者：Joydev K. Laha、Ketul V. Patel、Saima Saima、Surabhi Pandey、Ganesh Solanke、Vanya Vashisht

  DOI：10.1039/c8nj02734j

  日期：——

  current investigation on regioselective Suzuki reactions of 2,3-dihalopyridines and 2-halo-3-halomethylpyridines yielded the unexplored synthesis of arylpyridines and benzylpyridines bearing synthetic handles for further functionalization. Indeed, the scope of intramolecular cyclizations of arylpyridines and benzylpyridines prepared in this study for the synthesis of azafluorenes and azafluorenones has been

  目前对2，3-二卤代吡啶和2-卤代-3-卤代甲基吡啶的区域选择性Suzuki反应的研究产生了未经探索的芳基吡啶和苄基吡啶的合成，其带有用于进一步官能化的合成手柄。实际上，已经研究了在这项研究中制备的用于合成氮杂芴和氮杂芴酮的芳基吡啶和苄基吡啶的分子内环化的范围。
• ORGANIC LIGHT-EMITTING DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：US20160351817A1

  公开（公告）日：2016-12-01

  An organic light-emitting device including a first electrode, a second electrode, and an organic layer between the first electrode and the second electrode and including an emission layer. The organic layer may include a first compound represented by Formula 1 and a second compound represented by Formula 2: When the first compound represented by Formula 1 and the second compound represented by Formula 2 are included in the emission layer, the organic light-emitting device may have improved (e.g. increased) efficiency and lifespan characteristics.
• PROSTAKOV N. S.; PLESHAKOV V. G.; SEJTEMBETOV T. S.; FESENKO D. A.; ONASA+, ZH. ORGAN. XIMII, 1977, 13, 7, 1484-
  作者：PROSTAKOV N. S.、 PLESHAKOV V. G.、 SEJTEMBETOV T. S.、 FESENKO D. A.、 ONASA+

  DOI：——

  日期：——