6-hydroxy-13-methyl-6,7,12b,13-tetrahydro-5bH-[1,3]dioxolo[4,5-i][1,3]dioxolo[4',5':4,5]benzo[1,2-c]phenanthridin-14-one | 548-10-7

分子结构分类

有机化合物 - 生物碱及其衍生物 - 苯并菲啶生物碱

中文名称

——

中文别名

——

英文名称

6-hydroxy-13-methyl-6,7,12b,13-tetrahydro-5bH-[1,3]dioxolo[4,5-i][1,3]dioxolo[4',5':4,5]benzo[1,2-c]phenanthridin-14-one

英文别名

6-Hydroxy-13-methyl-6,7,12b,13-tetrahydro-5bH-[1,3]dioxolo[4,5-i][1,3]dioxolo[4',5':4,5]benzo[1,2-c]phenanthridin-14-on；6-oxochelidonine；oxychelidonine；12-hydroxy-24-methyl-5,7,18,20-tetraoxa-24-azahexacyclo[11.11.0.02,10.04,8.014,22.017,21]tetracosa-2,4(8),9,14(22),15,17(21)-hexaen-23-one

6-hydroxy-13-methyl-6,7,12b,13-tetrahydro-5b<i>H</i>-[1,3]dioxolo[4,5-<i>i</i>][1,3]dioxolo[4',5':4,5]benzo[1,2-<i>c</i>]phenanthridin-14-one化学式

CAS

548-10-7

化学式

C₂₀H₁₇NO₆

mdl

——

分子量

367.358

InChiKey

UPVAYLMWVRMHNE-UHFFFAOYSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

1.8
重原子数：

27
可旋转键数：

0
环数：

6.0
sp3杂化的碳原子比例：

0.35
拓扑面积：

77.5
氢给体数：

1
氢受体数：

6

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
白屈菜碱	(+/-)-chelidonine	20267-87-2	C₂₀H₁₉NO₅	353.375

反应信息

作为产物：

描述：

白屈菜碱在 mercury(II) diacetate 作用下，生成 6-hydroxy-13-methyl-6,7,12b,13-tetrahydro-5bH-[1,3]dioxolo[4,5-i][1,3]dioxolo[4',5':4,5]benzo[1,2-c]phenanthridin-14-one

参考文献：

名称：

Gadamer; Theissen, Archiv der Pharmazie, 1924, p. 580,588

摘要：

DOI：

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文献信息

Gadamer; Theissen, Archiv der Pharmazie, 1924, p. 580,588

作者：Gadamer、Theissen

DOI：——

日期：——

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