2-(ethyl(p-tolyl)amino)ethan-1-ol | 13386-60-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(ethyl(p-tolyl)amino)ethan-1-ol
• 英文别名: 2-(N-Ethyl-p-toluidino)ethanol；2-(N-ethyl-4-methylanilino)ethanol
• CAS: 13386-60-2
• 化学式: C₁₁H₁₇NO
• 分子量: 179.262
• InChiKey: WULPPMCTKHSRAO-UHFFFAOYSA-N

物化性质

• 沸点：
  312.9±25.0 °C(Predicted)
• 密度：
  1.028±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  23.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  在 双氧水 、 sodium hydroxide 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 、 水 为溶剂， 以24.0 mg的产率得到2-(ethyl(p-tolyl)amino)ethan-1-ol
  参考文献：
  名称：

  通过迭代硼同系化进行可编程胺合成

  摘要：

  可编程胺合成是通过将氮和碳原子顺序插入硼酸CB键来实现的。这一策略是通过一种新的氮烯类试剂实现的，该试剂允许通过N-插入从芳基或烷基硼酸酯直接形成氨基硼烷。

  DOI：

  10.1002/anie.202307118

文献信息

• Non-linear optically active molecules, their synthesis, and use
  申请人：McGinniss D. Vincent

  公开号：US20080004415A1

  公开（公告）日：2008-01-03

  In one aspect, the present invention provides a hyperpolarizable organic chromophore. The chromophore is a nonlinear optically active compound that includes a π-donor conjugated to a π-acceptor through a π-electron conjugated bridge. In other aspects of the invention, donor structures and acceptor structures are provided. In another aspect of the invention, a chromophore-containing polymer is provided. In one embodiment, the chromophore is physically incorporated into the polymer to provide a composite. In another embodiment, the chromophore is covalently bonded to the polymer, either as a side chain polymer or through crosslinking into the polymer. In other aspects, the present invention also provides a method for making the chromophore, a method for making the chromophore-containing polymer, and methods for using the chromophore and chromophore-containing polymer.

  在一个方面，本发明提供了一种高极化有机色团。该色团是一种非线性光学活性化合物，包括一个π-给体通过一个π-电子共轭桥连接到一个π-受体上。在本发明的其他方面，提供了给体结构和受体结构。在发明的另一个方面，提供了含有色团的聚合物。在一种实施例中，色团被物理地并入聚合物中以提供复合材料。在另一种实施例中，色团通过侧链聚合物或交联到聚合物中与聚合物共价键合。在其他方面，本发明还提供了制备色团的方法、制备含有色团的聚合物的方法以及使用色团和含有色团的聚合物的方法。
• Stabilized unsaturated polymer resin compositions and methods of using the same
  申请人：First Chemical Corporation

  公开号：US20030083443A1

  公开（公告）日：2003-05-01

  Stabilized pre-promoted unsaturated polymer resin systems that include a tertiary aromatic amine cure promoter. The stabilized curable resins systems can include a vinyl ester resin.

  稳定的预促进不饱和聚合物树脂体系，包括一种三级芳香胺硬化促进剂。稳定的可固化树脂体系可以包括乙烯基酯树脂。
• Methods of curing unsaturated polymers using tertiary aromatic amine cure promoters
  申请人：First Chemical Corporation

  公开号：US06258894B1

  公开（公告）日：2001-07-10

  Methods of promoting the cure of unsaturated polymer resins with a peroxide initiator by including as a promotor N-alkyl-N-(2-hydroxyalkyl)-p-toluidines. The use of the tertiary aromatic amines as a promotor provides a fast cure at a wide range of temperatures. Polymerizable compositions and methods of applying the same to a surface are also described.

  本发明提供了一种促进过氧化物引发剂下不饱和聚合物树脂固化的方法，其中包括将N-烷基-N-(2-羟基烷基)-对甲苯胺作为促进剂。使用三级芳香胺作为促进剂可在广泛的温度范围内快速固化。本发明还描述了可聚合组合物及其在表面上应用的方法。
• Methods of curing unsaturated polymers using tertiary aromatic amine
  申请人：First Chemical Corporation

  公开号：US06114470A1

  公开（公告）日：2000-09-05

  Methods of promoting the cure of unsaturated polymer resins with a peroxide initiator by including as a promotor N-alkyl-N-(2-hydroxyalkyl)-p-toluidines. The use of the tertiary aromatic amines as a promotor provides a fast cure at a wide range of temperatures. Polymerizable compositions and methods of applying the same to a surface are also described.

  本发明涉及一种促进过氧化物引发剂下不饱和聚合物树脂固化的方法，其中包括将N-烷基-N-（2-羟基烷基）-对甲苯胺作为促进剂。使用三级芳香胺作为促进剂可以在广泛的温度范围内快速固化。本发明还描述了可聚合组合物和将其应用于表面的方法。
• Precoating type adhesive composition
  申请人：THREE BOND CO., LTD.

  公开号：EP0952198A1

  公开（公告）日：1999-10-27

  An adhesive composition for use in precoating a screw member or the like, which comprises: (A) a suspension solution comprising a mixture of: (A1) one or more polymerization accelerator; (A2) one or more compound having at least one polymerizable double bond at a terminal thereof or in a side chain thereof; (A3) one or more acidic substance which becomes acidic after dissolved in water; and (A4) an aqueous binder which has an emulsifying capability and which is water-insolubilized by the acidic substance (A3); and (B) microcapsules containing one or more polymerization initiator. Also disclosed is a preparation process of the adhesive composition.

  一种用于预涂螺杆构件或类似构件的粘合剂组合物，它包括： (A) 一种悬浮溶液，其中包含以下物质的混合物(A1) 一种或多种聚合促进剂；(A2) 一种或多种在其末端或侧链上具有至少一个可聚合双键的化合物；(A3) 一种或多种溶于水后变为酸性的酸性物质；以及 (A4) 一种具有乳化能力并被酸性物质 (A3) 水不溶解的水性粘合剂；以及 (B) 含有一种或多种聚合引发剂的微胶囊。还公开了粘合剂组合物的制备工艺。