[Rh(acetylacetonato)(κ2-o-Ph2PC6H4CH=N-2,6-(i-Pr)2C6H3)] | 900145-22-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Rh(acetylacetonato)(κ2-o-Ph2PC6H4CH=N-2,6-(i-Pr)2C6H3)]
• CAS: 900145-22-4
• 化学式: C₃₆H₃₉NO₂PRh
• 分子量: 651.59
• InChiKey: VAOYMBLAQFMGNR-DYAYVFJASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Rh(acetylacetonato)(κ2-o-Ph2PC6H4CH=N-2,6-(i-Pr)2C6H3)] 、 O-亚苯基硼酸盐 以 乙醚 为溶剂， 以35%的产率得到[Rh(B(1,2-O2C6H4)2)(κ2-o-Ph2PC6H4CH=N-2,6-(i-Pr)2C6H3)]
  参考文献：
  名称：

  Novel rhodium complexes containing a bulky iminophosphine ligand and their use as catalysts for the hydroboration of vinylarenes

  摘要：

  Addition of o-Ph2PC6H4CH=N-2,6-(Pr2C6H3)-Pr-i (1) to [RhCl(coe)(2)](2) (coe = cis-cycloctene) gave several new iminophosphino rhodium(I) complexes including [Rh(kappa(2)-o-Ph2PC6H4CH=N-2,6-(Pr2C6H3)-Pr-i)(mu-Cl)](2) (2). Addition of 1 to Rh(acac)(coe)(2) (acac = acetylacetonato) gave [Rh(acac)(kappa(2)-o-Ph2PC6H4CH=N-2,6-(Pr2C6H3)-Pr-i)] (3) in yields of up to 75%. Complex 3 has been examined for its ability to catalyze the hydroboration of a series of vinyl arenes. Reactions using catecholborane and pinacolborane seem to proceed largely through a dehydrogenative borylation mechanism to give a number of boronated products. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.10.043
• 作为产物：
  描述：

  cyclooctane,(Z)-4-hydroxypent-3-en-2-one,rhodium 、 N-[2,6-bis(propan-2-yl)phenyl]-1-[2-(diphenylphosphanyl)phenyl]methanimine 以 甲苯 为溶剂， 以75%的产率得到[Rh(acetylacetonato)(κ2-o-Ph2PC6H4CH=N-2,6-(i-Pr)2C6H3)]
  参考文献：
  名称：

  Novel rhodium complexes containing a bulky iminophosphine ligand and their use as catalysts for the hydroboration of vinylarenes

  摘要：

  Addition of o-Ph2PC6H4CH=N-2,6-(Pr2C6H3)-Pr-i (1) to [RhCl(coe)(2)](2) (coe = cis-cycloctene) gave several new iminophosphino rhodium(I) complexes including [Rh(kappa(2)-o-Ph2PC6H4CH=N-2,6-(Pr2C6H3)-Pr-i)(mu-Cl)](2) (2). Addition of 1 to Rh(acac)(coe)(2) (acac = acetylacetonato) gave [Rh(acac)(kappa(2)-o-Ph2PC6H4CH=N-2,6-(Pr2C6H3)-Pr-i)] (3) in yields of up to 75%. Complex 3 has been examined for its ability to catalyze the hydroboration of a series of vinyl arenes. Reactions using catecholborane and pinacolborane seem to proceed largely through a dehydrogenative borylation mechanism to give a number of boronated products. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.10.043