[Ru(η6-C6H6)Cl2(PEt3)] | 39732-61-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ru(η6-C6H6)Cl2(PEt3)]
• 英文别名: [Ru(η6-benzene)Cl2PEt3]；benzene;ruthenium(2+);triethylphosphane;dichloride
• CAS: 39732-61-1
• 化学式: C₁₂H₂₁Cl₂PRu
• 分子量: 368.248
• InChiKey: PUTYJIZYTOXITD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  对苯二腈 、 ammonium hexafluorophosphate 、 [Ru(η6-C6H6)Cl2(PEt3)] 以 甲醇 为溶剂， 以68%的产率得到[Ru(η6-C6H6)(P(C2H5)3)Cl((CN)2C6H4)]PF6
  参考文献：
  名称：

  Synthesis and spectroscopic properties of cationic Ru(II) arene complexes [Ru(η6-arene)(P)Cl(L)]+. (P=PPh3, PEt3, MePPri2 and L=4-cyanopyridine or 1,4-dicyanobenzene)

  摘要：

  Reactions of [Ru(eta(6)-arene)(P)Cl-2] (P = PPh3, PEt3 or MePPr'(2)) with organonitriles 4-cyanopyridine or 1,4-dicyanobenzene (referred hereafter as CNPy or DCB) in methanol, in the presence of NH4PF6, gives the cationic arene complexes [Ru(eta(6)-arene)(P)Cl(L)](+) (L = CNPy or DCB). The reaction products have been characterized by physico-chemical methods viz., elemental analyses, IR, H-1- C-13-, P-31-NMR, electronic and FAB mass spectra. The spectral data of the complexes revealed the presence of a pendant nitrile group. These could behave as potential metallo-ligands and could find wide application in the syntheses of homo- or heterobimetallic mixed valence bridged complexes. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00258-8

文献信息

• Synthetic, spectral, electrochemical and structural aspects of some Ru(II) arene complexes with some novel bridging ligands
  作者：P Valerga、M.C Puerta、D.S Pandey

  DOI：10.1016/s0022-328x(01)01446-2

  日期：2002.4

  Reactions of chloro-bridged dimeric Ru(II) complexes [Ru(η6-arene)Cl2}2] with bridging ligands 1,4-dicyanamidobenzene, N,N′-dicyano 4-4′-diaminobiphenyl, 2,5-dichloro-1,4-dicyanamidobenzene and 2,5-dimethyl-1,4-dicyanamidobenzene (referred hereafter as dcdH2, bpH2, ddcl and dmcd) in dicloromethane at room temperature gave binuclear complexes with the general formulation [Ru(η6-arene)Cl2}2(μ-L)].

  的反应氯桥二聚的Ru（II）配合物[茹（η 6 -arene）氯2 } 2 ]与桥连配体的1,4- dicyanamidobenzene，Ñ，Ñ '-dicyano 4-4'-二氨基联苯，2,5-二氯-1,4- dicyanamidobenzene和2,5-二甲基-1,4- dicyanamidobenzene（以下简称dcdH 2，BPH 2在室温下在dicloromethane，DDCL和DMCD），得到双核络合物与一般的制剂[茹（ η 6 -arene）氯2 } 2（μ-L）]。然而，随着这些配合物的配体桥接的反应的[Ru（η 6 -arene）（P）氯2 ]（η 6 -arene =苯或p -cymene; P = PPH 3， PET 3或MePPr我2）在甲醇，在NH存在4 PF 6，得到阳离子芳烃络合物[茹（η 6 -arene）（P）氯} 2（L）] 2+（L = dcdH
• Synthesis of ruthenium amide complexes by nucleophilic attack on ortho-metalated imine ligands
  作者：Gaines C. Martin、James M. Boncella、E. J. Wucherer

  DOI：10.1021/om00054a051

  日期：1991.8

  The cationic ortho-metalated imine complexes, (eta-6-C6R6) activated Ru(R')N = C(R'')C6H4(L) (R = Me, H; R' = Ph, Et, Me; R'' = H, Me; L + PMe3, CO), 1, are formed in the reaction of (C6R6)RuCl2(L) with 2 equiv of imine and 2 equiv of AgBF4. These complexes react with powerful nucleophiles [Li(Bu(t)O)3AlH,RLi] via attack at the imine carbon atom, giving the neutral ortho-metalated amide complexes C6R6 activated Ru(R')-NC(R'')(Nu)C6H4(L). The nucleophilic attack occurs with high (> 98%) diastereoselectivity when the nucleophile differs from the substituent on the imine carbon. The molecular structures of [(eta-6-C6Me6) activated Ru(Ph)N = (CH)C6H4(PMe3)][BF4], 1a, and (eta-6-C6Me6) activated Ru(Ph)NC(H)(Me)C6H4(PMe3), 2a, were determined by X-ray diffraction. Complex 1a crystallizes in space group P2(1)/c (No. 14) with cell parameters a = 10.893 (2) angstrom, b = 14.507 (1) angstrom, c = 17.568 (3) angstrom, beta = 100.40 (1)-degrees, Z = 4, R = 0.025, and R(W) = 0.028. Compound 2a crystallizes in space group P2(1)/c (No. 14) with cell parameters a = 16.803 (3) angstrom, b = 9.306 (2) angstrom, c = 18.077 (3) angstrom, beta = 109.65 (1)-degrees, Z = 4, R = 0.061, and R(W) = 0.060.