carbonodithioic acid O-isopropyl S-(3-pentane-2,4-dione) ester | 1795-45-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代缩醛
• 英文名称: carbonodithioic acid O-isopropyl S-(3-pentane-2,4-dione) ester
• 英文别名: Dithiokohlensaeure-O-isopropylester-S-diacetylmethylester；O-propan-2-yl 2,4-dioxopentan-3-ylsulfanylmethanethioate
• CAS: 1795-45-5
• 化学式: C₉H₁₄O₃S₂
• 分子量: 234.34
• InChiKey: ZOGJXRDCEHZMPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  sodium isopropylxanthate 、 3-氯-2,4-戊二酮 以 乙醇 为溶剂， 生成 carbonodithioic acid O-isopropyl S-(3-pentane-2,4-dione) ester
  参考文献：
  名称：

  杀真菌剂的研究。七。某些吡唑衍生物的合成及其抗真菌活性。

  摘要：

  合成了 4-烷氧基硫代羰基硫代和 4-（N，N-二取代硫代氨基甲酰硫代）吡唑以及两种硫氰基吡唑。测试了这些化合物以及前一篇论文中所述化合物的抗真菌活性。总之，4-硫氰基吡唑具有很高的抗真菌活性，其中 1-（间硝基苯基）-4-硫氰基-3, 5-二甲基吡唑的抗真菌活性最高。

  DOI：

  10.1248/cpb.12.182

文献信息

• KETONE-CONTAINING CONTROLLED RADICAL INITIATORS FOR POLYMERIZATION REACTIONS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20200369820A1

  公开（公告）日：2020-11-26

  Controlled radical initiators that are ketone-containing dithiocarbamate or ketone-containing dithiocarbonate compounds are used to form polymeric materials that have a single polymeric block or multiple polymeric blocks. Reaction mixtures containing controlled radical initiators and various ethylenically unsaturated monomers, polymeric materials formed from the reaction mixtures, crosslinkable compositions containing the polymeric materials, crosslinked compositions formed from the crosslinkable compositions, and articles containing the polymeric materials, the crosslinkable compositions, or the crosslinked compositions are provided.

  含酮的二硫代氨基甲酸盐或含酮的二硫代碳酸盐控制自由基引发剂用于形成具有单一聚合物块或多重聚合物块的聚合物材料。本发明提供了含有控制自由基引发剂和多种乙烯基不饱和单体的反应混合物、由反应混合物形成的聚合物材料、含有聚合物材料的可交联组合物、由可交联组合物形成的交联组合物，以及包含聚合物材料、可交联组合物或交联组合物的物品。
• Ketone-containing controlled radical initiators for polymerization reactions
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10941234B2

  公开（公告）日：2021-03-09

  Controlled radical initiators that are ketone-containing dithiocarbamate or ketone-containing dithiocarbonate compounds are used to form polymeric materials that have a single polymeric block or multiple polymeric blocks. Reaction mixtures containing controlled radical initiators and various ethylenically unsaturated monomers, polymeric materials formed from the reaction mixtures, crosslinkable compositions containing the polymeric materials, crosslinked compositions formed from the crosslinkable compositions, and articles containing the polymeric materials, the crosslinkable compositions, or the crosslinked compositions are provided.

  含酮二硫代氨基甲酸酯或含酮二硫代碳酸酯化合物的受控自由基引发剂可用于形成具有单个或多个聚合物嵌段的聚合物材料。提供了含有受控自由基引发剂和各种乙烯基不饱和单体的反应混合物、由反应混合物形成的聚合材料、含有聚合材料的可交联组合物、由可交联组合物形成的交联组合物以及含有聚合材料、可交联组合物或交联组合物的物品。
• POLYMERIC MATERIALS FORMED USING INITIATORS WITH TWO THIOCARBONYLTHIO-CONTAINING GROUPS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20210095097A1

  公开（公告）日：2021-04-01

  Controlled radical initiators, reaction mixtures containing the controlled radical initiators and various ethylenically unsaturated monomers, polymeric materials formed from the reaction mixtures, crosslinkable compositions containing the polymeric materials, crosslinked compositions formed from the crosslinkable compositions, and articles containing the polymeric materials, the crosslinkable compositions, or the crosslinked compositions are provided. The controlled radical initiators are bis-dithiocarbamate or bis-dithiocarbonate compounds having a single carbon between the two dithiocarbamate or dithiocarbonate groups. Also attached to that single carbon is a ketone group.
• [EN] KETONE-CONTAINING CONTROLLED RADICAL INITIATORS FOR POLYMERIZATION REACTIONS<br/>[FR] INITIATEURS DE RADICAUX CONTRÔLÉS CONTENANT DES CÉTONES POUR DES RÉACTIONS DE POLYMÉRISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2019162805A1

  公开（公告）日：2019-08-29

  Controlled radical initiators that are ketone-containing dithiocarbamate or ketone-containing dithiocarbonate compounds are used to form polymeric materials that have a single polymeric block or multiple polymeric blocks. Reaction mixtures containing controlled radical initiators and various ethylenically unsaturated monomers, polymeric materials formed from the reaction mixtures, crosslinkable compositions containing the polymeric materials, crosslinked compositions formed from the crosslinkable compositions, and articles containing the polymeric materials, the crosslinkable compositions, or the crosslinked compositions are provided.