4-Pentadecyloxy-benzoyl chloride | 918626-12-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-Pentadecyloxy-benzoyl chloride
• 英文别名: 4-(Pentadecyloxy)benzoyl chloride；4-pentadecoxybenzoyl chloride
• CAS: 918626-12-7
• 化学式: C₂₂H₃₅ClO₂
• 分子量: 366.972
• InChiKey: AGKDFUDNSLQHSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  25
• 可旋转键数：
  16
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-Pentadecyloxy-benzoyl chloride 在 4-二甲氨基吡啶 、 三乙胺 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 生成 [3-[4-(4-Pentadecoxybenzoyl)sulfanylbenzoyl]oxyphenyl] 4-(4-pentadecoxybenzoyl)sulfanylbenzoate
  参考文献：
  名称：

  摘要：

  A new series of achiral banana-shaped compounds ("S-n'') has been synthesised and studied by the classical techniques (optical microscopy, differential scanning calorimetry, X-ray diffraction and electro-optic investigations). The short homologues (S-6,S-7) present an intercalated smectic B6 and a two-dimensional B1 phase. The intermediate S-8-S-10 compounds only form a B1 phase while the mesophase of long homologues (S-11-S-16) is identified as a switchable smectic B2 mesophase.

  DOI：

  10.1039/b103143k
• 作为产物：
  描述：

  4-tetradecyloxybezoic acid 在 草酰氯 作用下， 以 二氯甲烷 为溶剂， 生成 4-Pentadecyloxy-benzoyl chloride
  参考文献：
  名称：

  摘要：

  A new series of achiral banana-shaped compounds ("S-n'') has been synthesised and studied by the classical techniques (optical microscopy, differential scanning calorimetry, X-ray diffraction and electro-optic investigations). The short homologues (S-6,S-7) present an intercalated smectic B6 and a two-dimensional B1 phase. The intermediate S-8-S-10 compounds only form a B1 phase while the mesophase of long homologues (S-11-S-16) is identified as a switchable smectic B2 mesophase.

  DOI：

  10.1039/b103143k

文献信息

• Preparation and Ferroelectric Properties of New Chiral Liquid Crystalline Organic Radical Compounds
  作者：Rui Tamura、Naohiko Ikuma、Katsuaki Suzuki、Yoshiaki Uchida、Yoshio Aoki、Hiroyuki Nohira

  DOI：10.3987/com-09-s(s)64

  日期：——

  synthesized new chiral liquid crystalline (LC) organic radical compounds 2 and 3, which are the derivatives of the previously reported compounds 1 containing a chiral cyclic nitroxide unit and an ester group in the mesogen core, and their ferroelectric properties have been studied. The enantiomerically enriched (2S,5S)-2 and (2S,5S)-3 showed an SmC * phase for which their ferroelectric properties such as spontaneous

  我们合成了新的手性液晶（LC）有机自由基化合物 2 和 3，它们是先前报道的化合物 1 的衍生物，它们在介晶核中含有一个手性环状硝基氧单元和一个酯基，并对其铁电性能进行了研究。对映体富集的 (2S,5S)-2 和 (2S,5S)-3 显示出 SmC * 相，将它们的铁电特性如自发极化 (Ps) 和倾斜角 (θ) 与 (2S,5S) 进行了比较)-1。
• The Synthesis, Mesomorphic Behaviour and the Uniaxial Nature of 1,2,4,5-Tetra-(4-Alkoxybenzoyloxy) Benzenes
  作者：W. D. J. Amilaprasadh Norbert、John W. Goodby、Michael Hird、Kenneth J. Toyne、J. Cliff Jones、Jay S. Patel

  DOI：10.1080/10587259508038707

  日期：1995.2

  A homologous series of 1,2,4,5-tetra-(4-alkoxybenzoyloxy)benzenes (2, R = C4H9, C6H13 to C16H33 and C18H37) has been synthesised. Optical microscopy revealed that the compounds with R = C4H9, C6H13 to C10H21 have a nematic phase, compounds with R = C11H23 to C14H29 have nematic and smectic C phases and compounds with R = C15H31, C16H33 and C18H37 have only a smectic C phase. The T-N-I values show an 'odd-even' alternation which is typical of calamitic systems. The refractive indices for aligned samples of compound 2h (R = C10H21) demonstrate that the nematic phase is uniaxial.
• Preparation and Properties of<i>C</i>₂-Symmetric Organic Radical Compounds Showing Ferroelectric Liquid Crystal Properties
  作者：Naohiko Ikuma、Yoshiaki Uchida、Rui Tamura、Katsuaki Suzuki、Jun Yamauchi、Yoshio Aoki、Hiroyuki Nohira

  DOI：10.1080/15421400903065325

  日期：2009.9.3

  We have synthesized a new class of liquid crystalline (LC) organic radical compounds 2, which are the C-2-symmetric derivatives of the previously reported compounds 1 containing a chiral nitroxide unit and an ester group in the mesogen core, and their LC properties have been fully characterized. The enantiomerically enriched 2 showed N* and SmC* phases. Their LC phase transition behavior is similar to that of 1, whereas the ferroelectric properties of the SmC* phase of (2S,5S)-2 differed from those of (2S,5S)-1. We discuss the origin of this difference in terms of their molecular structures optimized by molecular orbital calculations.
• ——
  作者：J. C. Rouillon、J. P. Marcerou、M. Laguerre、H. T. Nguyen、M. F. Achard

  DOI：10.1039/b103143k

  日期：2001.11.23

  A new series of achiral banana-shaped compounds ("S-n'') has been synthesised and studied by the classical techniques (optical microscopy, differential scanning calorimetry, X-ray diffraction and electro-optic investigations). The short homologues (S-6,S-7) present an intercalated smectic B6 and a two-dimensional B1 phase. The intermediate S-8-S-10 compounds only form a B1 phase while the mesophase of long homologues (S-11-S-16) is identified as a switchable smectic B2 mesophase.