(Z)-2-(p-fluorophenyl)-3-(thiophen-2-yl)acrylonitrile | 347-19-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (Z)-2-(p-fluorophenyl)-3-(thiophen-2-yl)acrylonitrile
• 英文别名: 2-(4-fluoro-phenyl)-3c-[2]thienyl-acrylonitrile；2-(4-Fluor-phenyl)-3c-[2]thienyl-acrylonitril；(Z)-2-(4-Fluorophenyl)-3-(2-thienyl)acrylonitrile；(Z)-2-(4-fluorophenyl)-3-thiophen-2-ylprop-2-enenitrile
• CAS: 347-19-3
• 化学式: C₁₃H₈FNS
• 分子量: 229.278
• InChiKey: UXFYHMDTHQLJKQ-DHZHZOJOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (Z)-2-(p-fluorophenyl)-3-(thiophen-2-yl)acrylonitrile 在 碘 作用下， 以 甲苯 为溶剂， 反应 3.0h， 以65%的产率得到6-fluoronaphto[2,1-b]thiophene-9-carbonitrile
  参考文献：
  名称：

  Synthesis and photophysical properties of new reactive fluorophenanthrenes

  摘要：

  A series of six new suitably functionalized fluorophenanthrene derivatives were synthesized through a simple procedure, making use of inexpensive starting materials under mild conditions. The target phenanthrenes were characterized by H-1 and C-13 NMR and FT-IR spectroscopies. UV-Vis absorption and photoluminescence of these phenanthrenes were evaluated in solutions. A notable behavior and a strong fluorescence in the blue region of the visible spectrum were observed, making them potential candidates for organic light-emitting diode technology or advanced materials. Their electrochemical behavior was also experimentally examined in solution, demonstrating an important charge transfer interaction owing to their pi-conjugated electronic system.

  DOI：

  10.5802/crchim.29
• 作为产物：
  描述：

  2-噻吩甲醛 、 对氟苯乙腈 在 氢氧化钾 、 乙醇 作用下， 生成 (Z)-2-(p-fluorophenyl)-3-(thiophen-2-yl)acrylonitrile
  参考文献：
  名称：

  Buu-Hoi et al., Journal of the Chemical Society, 1952, p. 4590,4593

  摘要：

  DOI：

文献信息

• Buu-Hoi et al., Journal of the Chemical Society, 1952, p. 4590,4593
  作者：Buu-Hoi et al.

  DOI：——

  日期：——
• Amato, M. E.; Fisichella, S.; Occhipinti, S., Phosphorus and Sulfur and the Related Elements, 1987, vol. 29, p. 35 - 40
  作者：Amato, M. E.、Fisichella, S.、Occhipinti, S.、Scarlata, G.

  DOI：——

  日期：——
• Alberghina, Gaetano; Amato, Maria Emanuela; Corsaro, Antonio, Journal of the Chemical Society. Perkin transactions II, 1985, p. 353 - 356
  作者：Alberghina, Gaetano、Amato, Maria Emanuela、Corsaro, Antonio、Fisichella, Salvatore、Scarlata, Giuseppe

  DOI：——

  日期：——
• Synthesis and photophysical properties of new reactive fluorophenanthrenes
  作者：Amira K. Hajri、Marzough A. Albalawi、Nadia H. Elsayed、Faouzi Aloui

  DOI：10.5802/crchim.29

  日期：——

  A series of six new suitably functionalized fluorophenanthrene derivatives were synthesized through a simple procedure, making use of inexpensive starting materials under mild conditions. The target phenanthrenes were characterized by H-1 and C-13 NMR and FT-IR spectroscopies. UV-Vis absorption and photoluminescence of these phenanthrenes were evaluated in solutions. A notable behavior and a strong fluorescence in the blue region of the visible spectrum were observed, making them potential candidates for organic light-emitting diode technology or advanced materials. Their electrochemical behavior was also experimentally examined in solution, demonstrating an important charge transfer interaction owing to their pi-conjugated electronic system.