(N,N-diethyl,N'-ethylene(salicylideniminato))(salicylato)copper(II) | 180851-45-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (N,N-diethyl,N'-ethylene(salicylideniminato))(salicylato)copper(II)
• CAS: 180851-45-0
• 化学式: C₇H₅O₃*C₁₃H₁₉N₂O*Cu
• 分子量: 419.968
• InChiKey: NEJUEWHMTWAJQO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.27
• 重原子数：
  27.0
• 可旋转键数：
  7.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  99.02
• 氢给体数：
  1.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  (N,N-diethyl,N'-ethylene(salicylideniminato))(salicylato)copper(II) 、 方酸 在 H₂O 作用下， 以 甲醇 为溶剂， 以75%的产率得到(μ-1,2-squarato)bis{(N,N-diethyl,N'-ethylene(salicylideniminato))aquacopper(II)}hydrate
  参考文献：
  名称：

  Synthesis, x-ray structural study and magnetism of a novel binuclear copper(II) complex showing an unusual coordination mode for a squarato ligand

  摘要：

  Reaction of the [N,N-diethyl,N'-ethylene(salicylideniminato)](salicylato) copper(II) complex [Cu(SalNEt2)(Sal)] with squaric acid in CH3OH affords [Cu2(SalNEt2)2(H2O)(C4O4)] . H2O, whose X-ray structure shows the first example of a binuclear copper(II) complex with an unusual mu-1,2-coordination mode for the bridging squarato (C4O42-) ligand. This type of linking leads to the shortest bimetallic distance, as well as to the largest antiferromagnetic interaction observed so far for squarato bridged copper(II) complexes.

  DOI：

  10.1016/s0277-5387(00)83645-1