[(C6H3-2,6-(C6H3-2,6-iPr2)2)Al]2 | 609344-53-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(C6H3-2,6-(C6H3-2,6-iPr2)2)Al]2
• 英文别名: (aluminum)(C6H3-2,6-(C6H3-2,6-iPr2)2)2
• CAS: 609344-53-8
• 化学式: C₆₀H₇₄Al₂
• 分子量: 849.211
• InChiKey: KWGZPXKBAMJIHA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.87
• 重原子数：
  62
• 可旋转键数：
  12
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  AlI2(2,6-(2,6-(isopropyl)2C6H3)2C6H3) 在 KC₈ 作用下， 以 乙醚 为溶剂， 生成 [(C6H3-2,6-(C6H3-2,6-iPr2)2)Al]2
  参考文献：
  名称：

  The [2 + 4] Diels−Alder Cycloadditon Product of a Probable Dialuminene, Ar‘AlAlAr‘ (Ar‘ = C₆H₃- 2,6-Dipp₂; Dipp = C₆H₃-2,6-Prⁱ₂), with Toluene

  摘要：

  Reduction of Ar'AlI2 (Ar' = Ar'= C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2) with KC8 in diethyl ether most probably affords the first "dialuminene", Ar'AlAlAr'; it was characterized by its reaction with toluene which yielded a [2 + 4] cycloaddition product incorporating the Ar'AlAlAr' unit.

  DOI：

  10.1021/ja034478p

文献信息

• The [2 + 4] Diels−Alder Cycloadditon Product of a Probable Dialuminene, Ar‘AlAlAr‘ (Ar‘ = C₆H₃- 2,6-Dipp₂; Dipp = C₆H₃-2,6-Prⁱ₂), with Toluene
  作者：Robert J. Wright、Andrew D. Phillips、Philip P. Power

  DOI：10.1021/ja034478p

  日期：2003.9.1

  Reduction of Ar'AlI2 (Ar' = Ar'= C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2) with KC8 in diethyl ether most probably affords the first "dialuminene", Ar'AlAlAr'; it was characterized by its reaction with toluene which yielded a [2 + 4] cycloaddition product incorporating the Ar'AlAlAr' unit.