acrylic acid 5-ethyl-2-oxo-[1,3]dioxan-5-ylmethyl ester | 3536-74-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶烷
• 英文名称: acrylic acid 5-ethyl-2-oxo-[1,3]dioxan-5-ylmethyl ester
• 英文别名: 5-ethyl-5-acryloyloxymethyl-2-oxo-1,3-dioxane；(5-ethyl-2-oxo-1,3-dioxan-5-yl)methyl prop-2-enoate
• CAS: 3536-74-1
• 化学式: C₁₀H₁₄O₅
• 分子量: 214.218
• InChiKey: UNOQBIRFMZVHIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  acrylic acid 5-ethyl-2-oxo-[1,3]dioxan-5-ylmethyl ester 在 对甲苯磺酸 作用下， 以 甲醇 为溶剂， 生成 2-Ethyl-2-acryloyloxymethyl-3-methoxycarbonyloxypropanol
  参考文献：
  名称：

  Vinyl monomer having linear carbonate and hydroxyl groups

  摘要：

  用作生产含羟基乙烯聚合物的单体，提供了一种具有以下结构的化合物：##STR1## 其中R.sup.1为丙烯酰基、甲基丙烯酰基或4-乙烯基苄基；R.sup.2为烷基；R.sup.3为烷基、烷氧基烷基、烯烃基、炔烃基、芳基烷基或芳基。

  公开号：

  US05534647A1
• 作为产物：
  描述：

  三羟甲基丙烷 、 丙烯酰氯 、 碳酸二乙酯 在 氢氧化钾 、 tin 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 250.0 ℃ 、800.0 Pa 条件下， 以10 g的产率得到acrylic acid 5-ethyl-2-oxo-[1,3]dioxan-5-ylmethyl ester
  参考文献：
  名称：

  快速单体：影响光引发丙烯酸酯聚合中丙烯酸酯单体固有反应性的因素

  摘要：

  对分子结构对丙烯酸酯光引发聚合反应的影响进行了系统的研究。最初，研究的重点是氢键的作用，发现通过氢键进行的预组织可提高最大聚合速率（R p）。这种氢键促进的预组织也影响了所得聚合物的立构规整度。接下来，研究了由给定单体的计算偶极矩（μcalc）表示的极性影响。观察到R p与计算的玻尔兹曼平均偶极矩（μcalc）之间存在直接的线性关系。的[R p -μ计算值相关性适用于纯单体，单体混合物，甚至单体与惰性溶剂的混合物。这种相关性使得能够合理设计具有所需反应性的单体。另外，这些研究表明，聚合的传播步骤受氢键的影响，而偶极矩则影响终止速率常数。可以将这两种机理解释视为影响丙烯酸酯聚合速度的互补因素。

  DOI：

  10.1021/ma021785r

文献信息

• Vinyl monomer having linear carbonate and hydroxyl groups
  申请人：Nippon Paint Co., Ltd.

  公开号：US05534647A1

  公开（公告）日：1996-07-09

  For use as a monomer for producing hydroxyl group-containing vinyl polymers, there is provided a compound of the formula: ##STR1## wherein R.sup.1 is acryloyl, methacryloyl or 4-vinylbenzyl; R.sup.2 is an alkyl; and R.sup.3 is an alkyl, alkoxyalkyl, alkenyl, alkynyl, aralkyl or aryl.

  用作生产含羟基乙烯聚合物的单体，提供了一种具有以下结构的化合物：##STR1## 其中R.sup.1为丙烯酰基、甲基丙烯酰基或4-乙烯基苄基；R.sup.2为烷基；R.sup.3为烷基、烷氧基烷基、烯烃基、炔烃基、芳基烷基或芳基。
• CURABLE COMPOSITION, COLOR FILTER USING THE SAME AND MANUFACTUIRNG METHOD THEREFOR, AND SOLID IMAGE PICKUP ELEMENT
  申请人：NAKASHIMA Taeko

  公开号：US20080171272A1

  公开（公告）日：2008-07-17

  The present invention provides a curable composition containing a resin, a compound containing an ethylenically unsaturated double bond and a photopolymerization initiator, wherein the resin is manufactured by polymerizing at least a monomer having a dipole moment of 2.0 or more as a copolymerization component, a color filter using the same and a manufacturing method therefor, and a solid image pickup element.
• INTERFACE BINDER, RESIST COMPOSITION CONTAINING THE SAME, LAMINATE FOR FORMING MAGNETIC RECORDING MEDIUM HAVING LAYER CONTAINING THE SAME, MANUFACTURING METHOD OF MAGNETIC RECORDING MEDIUM USING THE SAME, AND MAGNETIC RECORDING MEDIUM PRODUCED BY THE MANUFACTURING METHOD
  申请人：Omatsu Tadashi

  公开号：US20090011367A1

  公开（公告）日：2009-01-08

  To provide an interface binder for binding a resist layer and a laminate for forming magnetic recording medium having a substrate and a magnetic layer, the interface binder containing a first functional group crosslinkable with a surface of the laminate, and a second functional group crosslinkable with the resist layer.
• MICROPARTICLE COMPRISING CROSS-LINKED POLYMER
  申请人：Dias Aylvin Jorge Angelo Athanasius

  公开号：US20100291116A1

  公开（公告）日：2010-11-18

  Microparticle comprising a cross-linked polymer comprising (a) a cross-linker comprising two or more radically polymerizable groups, preferably selected from the group consisting of alkenes, sulfhydryl (SH), thioic, unsaturated esters, unsaturated urethanes, unsaturated ethers, and unsaturated amides; (b) a monofunctional reactive diluent comprising maximum one unsaturated C—C bond represented by the formula R 0 —C(R 1 )═CHR 2 Formula (I) wherein —R 0 is chosen depending on the structure of a selected active agent (c) to be loaded into the microparticle and is chosen to have a structure that when combined with the other components of the microparticle provides a higher affinity of the selected active agent (c) for the microparticle; —each R 1 is chosen from hydrogen and substituted and unsubstituted, aliphatic, cycloaliphatic and aromatic hydrocarbon groups which groups optionally contain one or more moieties selected from the group of ester moieties, ether moieties, thioester moieties, thioether moieties, carbamate moieties, thiocarbamate moieties, amide moieties and other moieties comprising one or more heteroatoms, in particular one or more heteroatoms selected from S, O, P and N, each R 5 in particular independently being chosen from the group of hydrogen and substituted and unsubstituted alkyl groups, which alkyl groups optionally contain one or more heteroatoms, in particular one or more heteroatoms selected from P, S, O and N; —each R 2 is chosen from hydrogen, —COOCH 3 , —COOC 2 H 5 , —COOC 3 H 7 , and —COOC 4 H 9 .
• US5534647A
  申请人：——

  公开号：US5534647A

  公开（公告）日：1996-07-09