1,1'-[(1E,11E)-5,8-Dioxa-2,11-diazoniadodeca-1,11-diene-\ 1,12-diyl]dinaphthalen-2-olate | 906748-29-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,1'-[(1E,11E)-5,8-Dioxa-2,11-diazoniadodeca-1,11-diene-\ 1,12-diyl]dinaphthalen-2-olate
• 英文别名: 1-[2-[2-[2-[(2-hydroxynaphthalen-1-yl)methylideneamino]ethoxy]ethoxy]ethyliminomethyl]naphthalen-2-ol
• CAS: 906748-29-6
• 化学式: C₂₈H₂₈N₂O₄
• 分子量: 456.541
• InChiKey: FUWZKWBTNMPLTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  34
• 可旋转键数：
  11
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  83.6
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1,8-二氨基-3,6-二氧杂辛烷 、 2-羟基-1-萘甲醛 以 甲醇 为溶剂， 反应 3.0h， 生成 1,1'-[(1E,11E)-5,8-Dioxa-2,11-diazoniadodeca-1,11-diene-\ 1,12-diyl]dinaphthalen-2-olate
  参考文献：
  名称：

  Sonochemical and hydrothermal synthesis of PbTe nanostructures with the aid of a novel capping agent

  摘要：

  In this work, a new Schiff-base compound derived from 1,8-diamino-3,6-dioxaoctane and 2-hydroxy-1-naphthaldehyde marked as (2-HyNa)-(DaDo) was synthesized, characterized, and then used as capping agent for the preparation of PbTe nanostructures. To fabricate PbTe nanostructures, two different synthesis methods; hydrothermal and sonochemical routes, were applied. To further investigate, the effect of preparation parameters like reaction time and temperature in hydrothermal synthesis and sonication time in the presence of ultrasound irradiation on the morphology and purity of the final products was tested. The products were analyzed with the aid of SEM, TEM, XRD, FT-IR, and EDS. Based on the obtained results, it was found that pure cubic phased PbTe nanostructures have been obtained by hydrothermal and sonochemical approaches. Besides, SEM images showed that cubic-like and rod-like PbTe nanostructures have been formed by hydrothermal and sonochemical methods, respectively. Sonochemical synthesis of PbTe nanostructures was favorable, because the synthesis time of sonochemical method was shorter than that of hydrothermal method. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.materresbull.2013.07.010
• 作为试剂：
  描述：

  碲化氢 、 lead(II) nitrate 在 1,1'-[(1E,11E)-5,8-Dioxa-2,11-diazoniadodeca-1,11-diene-\ 1,12-diyl]dinaphthalen-2-olate 、 一水合肼 、 sodium hydroxide 作用下， 以 乙二醇 为溶剂， 反应 6.0h， 生成
  参考文献：
  名称：

  Sonochemical and hydrothermal synthesis of PbTe nanostructures with the aid of a novel capping agent

  摘要：

  In this work, a new Schiff-base compound derived from 1,8-diamino-3,6-dioxaoctane and 2-hydroxy-1-naphthaldehyde marked as (2-HyNa)-(DaDo) was synthesized, characterized, and then used as capping agent for the preparation of PbTe nanostructures. To fabricate PbTe nanostructures, two different synthesis methods; hydrothermal and sonochemical routes, were applied. To further investigate, the effect of preparation parameters like reaction time and temperature in hydrothermal synthesis and sonication time in the presence of ultrasound irradiation on the morphology and purity of the final products was tested. The products were analyzed with the aid of SEM, TEM, XRD, FT-IR, and EDS. Based on the obtained results, it was found that pure cubic phased PbTe nanostructures have been obtained by hydrothermal and sonochemical approaches. Besides, SEM images showed that cubic-like and rod-like PbTe nanostructures have been formed by hydrothermal and sonochemical methods, respectively. Sonochemical synthesis of PbTe nanostructures was favorable, because the synthesis time of sonochemical method was shorter than that of hydrothermal method. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.materresbull.2013.07.010