(1R,2S,6R,7S)-2-methyl-4-phenyl-4-azatricyclo[5.2.1.0^2,9]dec-8-ene-3,5-dione | 67094-30-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: (1R,2S,6R,7S)-2-methyl-4-phenyl-4-azatricyclo[5.2.1.0^2,9]dec-8-ene-3,5-dione
• 英文别名: 3a-methyl-2-phenyl-3a,4,7,7a-tetrahydro-4,7-methano-isoindole-1,3-dione；3a-methyl-2-phenyl-3a,4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione；2-methyl-4-phenyl-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
• CAS: 67094-30-8
• 化学式: C₁₆H₁₅NO₂
• 分子量: 253.301
• InChiKey: RYMOMTMZHJAEQI-UHFFFAOYSA-N

物化性质

• 熔点：
  109 °C(Solv: benzene (71-43-2))
• 沸点：
  457.2±45.0 °C(Predicted)
• 密度：
  1.294±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  19
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-甲基-N-苯基马来酰亚胺 以78%的产率得到
  参考文献：
  名称：

  HEBENBROCK K.-F., J. LIEBIGS ANN. CHEM., 1978, NO 2, 320-336

  摘要：

  DOI：

文献信息

• Highly enantioselective synthesis of chiral imides and derived products via chiral base desymmetrisation
  作者：David J Adams、Alexander J Blake、Paul A Cooke、Christopher D Gill、Nigel S Simpkins

  DOI：10.1016/s0040-4020(02)00367-8

  日期：2002.6

  The enantioselective deprotonation of several ring-fused imides with a chiral base, followed by electrophilic quenching, gives a range of chiral products in good yield and in ≥91% ee. The absolute stereochemistry of two of the products was determined by X-ray crystallography. A number of the imide products were subjected to further, highly regioselective, transformations, including enolate substitution

  几种具有手性碱的环稠合酰亚胺的对映选择性去质子化，然后进行亲电猝灭，可得到一系列手性产物，收率良好，ee≥91％。通过X射线晶体学测定了两种产物的绝对立体化学。使许多酰亚胺产物进行进一步的高度区域选择性的转化，包括烯醇酸酯取代，还原和硫磺化。
• Cyanate resin blends and radomes including them
  申请人：Saint-Gobain Performance Plastics Corporation

  公开号：US10329383B2

  公开（公告）日：2019-06-25

  Certain embodiments are directed to cyanate resin blends comprising, for example, a mixture of a cyanate monomer and a cyanate oligomer. The resin blends are effective to provide a dielectric constant of less than 2.7, a glass transition temperature of at least 150° C. and a moisture absorption of less than 1.5%. Radomes using the resin are also described.

  某些实施方案涉及氰酸酯树脂混合物，例如由氰酸酯单体和氰酸酯低聚物混合物组成。这种树脂混合物能有效提供小于 2.7 的介电常数、至少 150 摄氏度的玻璃化转变温度和小于 1.5% 的吸湿性。此外，还介绍了使用该树脂的 Radomes。
• Novel catalyst for hydrogenation of polymer and process for hydrogenating polymer with the catalyst
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0339986B1

  公开（公告）日：1992-12-02
• Hydrogenation catalyst composition and process for hydrogenating olefinically unsaturated polymer using the same
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0434469B1

  公开（公告）日：1995-02-22
• Catalyst composition for hydrogenating olefinically unsaturated polymers
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0544304B1

  公开（公告）日：1998-02-04