1,6-bis(2,4-dinitrophenoxy)-2,4-hexadiyne | 70557-69-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,6-bis(2,4-dinitrophenoxy)-2,4-hexadiyne
• 英文别名: 1,6-Bis (2,4-dinitrophenoxy)-2,4-hexadiyne；1-[6-(2,4-dinitrophenoxy)hexa-2,4-diynoxy]-2,4-dinitrobenzene
• CAS: 70557-69-6
• 化学式: C₁₈H₁₀N₄O₁₀
• 分子量: 442.298
• InChiKey: CACJAZTZMFUFGB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  32
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  202
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  1,6-bis(2,4-dinitrophenoxy)-2,4-hexadiyne 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Albouy; Patillon; Pouget, Molecular Crystals and Liquid Crystals (1969-1991), 1982, vol. 93, # 1-4, p. 239 - 246

  摘要：

  DOI：
• 作为产物：
  描述：

  2,4-dinitro-1-prop-2- ynyloxybenzene 、 在 吡啶 、 tetrakis(actonitrile)copper(I) hexafluorophosphate 作用下， 以 甲苯 为溶剂， 反应 48.0h， 以39%的产率得到1,6-bis(2,4-dinitrophenoxy)-2,4-hexadiyne
  参考文献：
  名称：

  Nanohoop Rotaxane Design to Enhance the Selectivity of Reaction-Based Probes: A Proof-of-Principle Study

  摘要：

  DOI：

  10.1021/acs.orglett.1c01348

文献信息

• Novel nonlinear optical materials and processes employing diacetylenes
  申请人：UNIVERSITY PATENTS, INC.

  公开号：EP0021695A2

  公开（公告）日：1981-01-07

  Novel non-linear optical, piezoelectric, pyroelectric, waveguide, and other materials are presented together with processes for their employment and articles formed thereby. Such materials, processes and articles comprise diacetylenes and polymers formed from diacetylenic species, which polymers are amenable to close geometric, steric, structural, and-electronic control. Accordingly, it is now possible to design, formulate and employ new diacetylenic species and polymers formed therefrom to provide non-linear optic, waveguide, piezoelectric, and pyroelectric materials and devices having surprising efficiencies and degrees of effect. According to a preferred embodiment of the invention, diacetylenes which are crystallizable into crystals. having a non-centrosymmetric unit cell may form single crystals or may be elaborated into a thin film upon a substrate by the Langmuir-Blodgett technique. Such films may, optionally, be polymerized either thermally or by irradiation for use in non- linear optical and other systems. According to other prefered embodiments, diacetylenes are covalently bonded to substrates through the employment of silane species and subsequently polymerized to yield non-linear optic and other devices having high structural integrity in addition to high efficiencies and effects.

  本文介绍了新型非线性光学、压电、热释电、波导和其他材料，以及使用这些材料的工艺和由此形成的物品。这些材料、工艺和物品包括二乙炔和由二乙炔类物质形成的聚合物，这些聚合物可进行严密的几何、立体、结构和电子控制。因此，现在可以设计、配制和使用新的二乙炔类物质和由其形成的聚合物，以提供非线性光学、波导、压电和热释电材料和装置，其效率和效果令人惊讶。根据本发明的一个优选实施方案，可结晶成具有非中心对称单胞的晶体的二乙炔可形成单晶体，也可通过朗缪尔-布洛杰特技术在基底上形成薄膜。这种薄膜可以选择热聚合或辐照聚合，用于非线性光学系统和其他系统。根据其他优选的实施方案，二乙炔通过硅烷共价键合到基底上，然后进行聚合，以产生非线性光学器件和其他器件，这些器件除了具有高效率和高效果外，还具有很高的结构完整性。
• Photographic articles comprising a compound having acetylenic bonds and methods for producing the articles
  申请人：UNIVERSITY PATENTS, INC.

  公开号：EP0077577A2

  公开（公告）日：1983-04-27

  This invention provide a novel photoresistive article having significantly improved properties of resultion when used as a photoresist. The article comprising a substrate and a layer carried by said substrate of a photopolymerizable composition which layer comprises at least one material having at least two acetylenic bonds, at least two of said bonds being in conjugation with one another and having a plurality of discrete domains. In one embodiment of the invention, within the discrete domain, a majority of the molecules of the material are oriented in an irregular array. The domains may have an average dimension of less than 10,000 angstom units and provides enhanced resolution of micro-structural lines in an image projected thereon.

  本发明提供了一种新型光致抗蚀剂制品，该制品在用作光致抗蚀剂时，其结果性能得到明显改善。 该制品包括基底和由所述基底承载的一层可光聚合的组合物，该层包括至少一种具有至少两个乙炔键的材料，其中至少两个键彼此共轭，并具有多个离散畴。 在本发明的一个实施例中，在离散畴内，材料的大部分分子以不规则阵列的方式定向。 这些畴的平均尺寸可小于 10,000 个角单位，并可提高投射到其上的图像中的微观结构线的分辨率。
• Optical waveguides employing diacetylenes
  申请人：UNIVERSITY PATENTS, INC.

  公开号：EP0081477A2

  公开（公告）日：1983-06-15

  Novel waveguides employing diacetylenes are present together with processes for their production. Such articles comprise diacetylenes and polymers formed from diacetylenic species, which polymers are amendable to close geometric, steric, structural, and electronic control. Accordingly, it is now possible to design formulate and employ new diacetylenic waveguideing polymers to provice non-linear optic, devices having surprising efficiencies. According to a preferred embodiment of the invention, diacetylenes which are crystallizable into crystals having a non-centro-symmetric unit cell may form single crystals or may be elaborated into a thin film upon a substrate by the Langmuir-Blodgett technique. Such films may, optionally, be polymerized either thermally or by irradiation for use. According to other preferred embodiments, diacetylenes are covalently bonded to substrates through the employment of silane species and subsequently polymerized to yield non- linear optic devices having high structural integrity in addition to high efficiencies and effects.

  本文介绍了使用二乙炔的新型波导及其生产工艺。这些产品包括二乙炔和由二乙炔类物质形成的聚合物，这些聚合物可进行严密的几何、立体、结构和电子控制。因此，现在可以设计、配制和使用新型二乙炔基波导聚合物，以提供具有惊人效率的非线性光学器件。 根据本发明的一个优选实施方案，可结晶成具有非中心对称单胞的晶体的二乙炔可形成单晶体，也可通过朗缪尔-布洛杰特技术在基底上制成薄膜。这种薄膜可以选择热聚合或辐照聚合来使用。根据其他优选的实施方案，二乙炔通过硅烷共价键合到基底上，然后进行聚合，以产生非线性光学器件，这种器件除了具有高效率和高效果外，还具有很高的结构完整性。
• Photographic or photolithographic article and method of forming a photoresist
  申请人：UNIVERSITY PATENTS, INC.

  公开号：EP0022618B1

  公开（公告）日：1985-12-04
• US4431263A
  申请人：——

  公开号：US4431263A

  公开（公告）日：1984-02-14