2,2-bis-[3-(1-propenyl)-4-hydroxyphenyl]-propane | 71449-72-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-bis-[3-(1-propenyl)-4-hydroxyphenyl]-propane
• 英文别名: 2,2-Bis(3-(1-propenyl)-4-hydroxyphenyl)propane；4-[2-(4-hydroxy-3-prop-1-enylphenyl)propan-2-yl]-2-prop-1-enylphenol
• CAS: 71449-72-4
• 化学式: C₂₁H₂₄O₂
• 分子量: 308.42
• InChiKey: VHQITFPYPJKSGM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,2’-二烯丙基双酚 A 以 甲醇 为溶剂， 生成 2,2-bis-[3-(1-propenyl)-4-hydroxyphenyl]-propane
  参考文献：
  名称：

  Propenyl-substituted phenolglycidyl ethers, processes for producing

  摘要：

  含有至少一个1-丙烯基团在邻位或对位与环氧基团相对的分子中的单价和多价苯酚缩水甘油醚，或是在邻位或对位与环氧基团相对的丙烯基取代的单价或多价苯酚缩水甘油醚的异构混合物，以及在邻位或对位与环氧基团相对的烯丙基取代的单价或多价苯酚缩水甘油醚，异构混合物中丙烯基的比例必须至少为5当量-%，相对于丙烯基和烯丙基的当量总和。这些新化合物可以通过丙烯酸树脂的固化剂和自由基聚合的方法转化为具有有价值的机械性能的聚合物。该过程中，使用环氧氯丙烷对丙烯基取代的苯酚，或丙烯基和烯丙基取代的苯酚的异构混合物进行缩水甘油化。

  公开号：

  US04384129A1

文献信息

• Curable mixtures based on maleimides and propenyl-substituted phenols,
  申请人：Ciba-Geigy Corporation

  公开号：US04371719A1

  公开（公告）日：1983-02-01

  Curable mixtures of (a) maleimides of the general formula I ##STR1## wherein R is an n-valent aliphatic or aromatic radical, and n is the number 1, 2 or 3; and (b) mono- or polyvalent phenols which contain in the molecule at least one 1-propenyl group in the ortho- or para-position with respect to the hydroxyl group, or isomeric mixtures of mono- or polyvalent phenols which are propenyl-substituted in the ortho- or para-position and mono- or polyvalent phenols which are allyl-substituted in the ortho- or para-position, the proportion of propenyl groups in the isomeric mixture having to be at least 5 equivalent-%, relative to the sum of the equivalents of propenyl and allyl groups. The novel mixtures cure at elevated temperatures relatively rapidly, and produce molded materials having valuable mechanical properties.

  通用公式I的马来酰胺（a）可治疗混合物 ##STR1## 其中R是n-价的脂肪族或芳香族基团，n是数字1、2或3；和（b）分子中至少在羟基团相对于1-丙烯基团的邻位或对位含有单价或多价酚，或者在邻位或对位含有丙烯基取代物和在对位或邻位含有烯丙基取代物的单价或多价酚的异构混合物，异构混合物中丙烯基基团的比例至少为5当量％，相对于丙烯基和烯丙基基团当量总和。这种新型混合物在较高温度下相对迅速固化，并产生具有有价值机械性能的成型材料。
• Epoxide-containing compositions and their polymerization
  申请人：Ciba-Geigy Corporation

  公开号：US04220513A1

  公开（公告）日：1980-09-02

  Polymerizable compositions comprise (a) a compound containing in the same molecule both at least one 1,2-epoxide group and at least two groups chosen from allyl, methallyl, and 1-propenyl groups, e.g., 2,2-bis(3-allyl-4-(glycidyloxy)phenyl)propane or bis(3-(1-propenyl)-4-(glycidyloxy)phenyl)methane, and (b) a compound containing at least two mercaptan groups per molecule, e.g., pentaerythritol tetrathioglycollate. The compositions are caused to polymerize by the action of irradiation or free-radical catalysts. They may, if desired, also contain a heat-curing crosslinking agent for epoxide resins; the epoxide-containing polymers so obtained can be subsequently crosslinked in situ. The compositions are useful in various two-stage operations, such as the production of multilayer printed circuits.

  聚合物组合物包括（a）一种化合物，其分子中同时含有至少一个1,2-环氧基团和至少两个选自烯丙基，甲基烯丙基和1-丙烯基基团的基团，例如2,2-双（3-烯丙基-4-（环氧基氧基）苯基）丙烷或双（3-（1-丙烯基）-4-（环氧基氧基）苯基）甲烷，和（b）一种每个分子中含有至少两个巯基基团的化合物，例如对硫代乙二醇四羧酸四酯。通过辐射或自由基催化剂的作用，使组合物聚合。如果需要，它们还可以含有环氧树脂的热固性交联剂；因此获得的含环氧基的聚合物可以随后原位交联。该组合物在各种两阶段操作中有用，例如多层印刷电路板的生产。
• Curable mixtures based on maleimides and 1-propenyl-substituted phenols
  申请人：Ciba-Geigy Corporation

  公开号：US04288583A1

  公开（公告）日：1981-09-08

  Curable mixtures of (a) maleimides of the general formula I ##STR1## wherein R is an n-valent aliphatic or aromatic radical, and n is the number 1,2 or 3; and (b) mono- or polyvalent phenols which contain in the molecule at least one 1-propenyl group in the ortho- or para-position with respect to the hydroxyl group, or isomeric mixtures of mono- or polyvalent phenols which are propenyl-substituted in the ortho- or para-position and mono- or polyvalent phenols which are allyl-substituted in the ortho- or para-position, the proportion of propenyl groups in the isomeric mixture having to be at least 5 equivalent-%, relative to the sum of the equivalents of propenyl and allyl groups. The novel mixtures cure at elevated temperatures relatively rapidly, and produce moulded materials having valuable mechanical properties.

  可治愈的混合物包括（a）通式I的马来酰亚胺：##STR1## 其中R是n价的脂肪族或芳香族基团，n是1、2或3；以及（b）分子中至少在与羟基团相对的邻-或对位含有一个1-丙烯基基团的单价或多价酚，或者是在邻-或对位上丙烯基取代的同分异构体混合物和在邻-或对位上烯丙基取代的单价或多价酚，同分异构体混合物中丙烯基的比例必须至少为5当量-%，相对于丙烯基和烯丙基当量总和。这种新型混合物在升高温度下相对快速地固化，并产生具有有价值的机械性能的模塑材料。
• Hydroxyl-containing compositions and their polymerization
  申请人：Ciba-Geigy Corporation

  公开号：US04308367A1

  公开（公告）日：1981-12-29

  Polymerizable compositions comprise (a) a compound containing in the same molecule both at least one phenolic hydroxyl group and at least two groups chosen from allyl, methallyl, and 1-propenyl groups, e.g., 2,2-bis(3-allyl-4-hydroxyphenyl)propane or bis(3-(1-propenyl)-4-hydroxyphenyl)methane, (b) a compound containing at least two mercaptan groups per molecule, e.g., pentaerythritol tetrathioglycollate, and (c) a heat-activated crosslinking agent for phenol-aldehyde novolac resins. The compositions are caused to polymerize by the action of irradiation of free-radical catalysts. The polymers so obtained, containing more than one phenolic hydroxyl group, can be subsequently crosslinked in situ by heating. The compositions are useful in various two-stage operations, such as the production of multilayer printed circuits. Polymerizable compositions may also comprise (d) a compound as (a) but containing at least two phenolic hydroxyl groups, (e) a compound containing more than two mercaptan groups per molecule. On irradiation or on heating in the presence of a catalyst, preferably a free-radical catalyst, these compositions crosslink, they are useful as adhesives in forming coatings on polar substrates.

  可聚合组合物包括（a）一种化合物，该化合物在同一分子中含有至少一个酚羟基和至少两个选择自烯丙基，甲烯丙基和1-丙烯基的基团，例如2,2-双（3-烯丙基-4-羟基苯基）丙烷或双（3-（1-丙烯基）-4-羟基苯基）甲烷，（b）一种化合物，每个分子中含有至少两个巯基基团，例如对甲苯磺酸四硫醇酯，以及（c）一种热活性交联剂用于酚醛诺伍拉克树脂。通过自由基催化剂的辐射作用引起组合物聚合。由此获得的聚合物含有多个酚羟基，可以通过加热在原位交联。该组合物在各种两阶段操作中有用，例如多层印刷电路的生产。可聚合组合物还可以包括（d）一种化合物，与（a）相同但含有至少两个酚羟基，（e）一种每个分子中含有多于两个巯基基团的化合物。在辐射或催化剂存在下加热时，这些组合物交联，它们在形成极性基底上的涂层粘合剂中有用。