1,3,5-tris((4,5-diazafluoren-9-yliminoxy)methyl)-2,4,6-trimethylbenzene | 1133857-36-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1,3,5-tris((4,5-diazafluoren-9-yliminoxy)methyl)-2,4,6-trimethylbenzene
• 英文别名: N-[[3,5-bis[(3,13-diazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaen-8-ylideneamino)oxymethyl]-2,4,6-trimethylphenyl]methoxy]-3,13-diazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaen-8-imine
• CAS: 1133857-36-9
• 化学式: C₄₅H₃₃N₉O₃
• 分子量: 747.816
• InChiKey: GIKKQGUVOSDMGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  57
• 可旋转键数：
  9
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  142
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 顺-双(2,2'-二吡啶基)二氯化钌(II)二水合物 、 1,3,5-tris((4,5-diazafluoren-9-yliminoxy)methyl)-2,4,6-trimethylbenzene 以 乙二醇甲醚 为溶剂， 生成 (1,3,5-tris((4,5-diazafluoren-9-yliminoxy)methyl)-2,4,6-trimethylbenzene)tris(bis(2,2'-bipyridine)ruthenium(II)) fexafluorophosphate
  参考文献：
  名称：

  Synthesis, photophysical, and electrochemical properties of two novel trinuclear Ru(II) polypyridyl complexes

  摘要：

  Two polypyridyl ligands 2,2',2"-tris((4,5-diazafluoren-9-yliminoxy)ethyl)amine (L-1) and 1,3,5-tris((4,5-diazafluoren-9-yliminoxy)methyl))-2,4,6-trimethylbenzene (L-2), and corresponding trinuclear Ru(II) complexes [(bpy)(6)L1-2(Ru-II)(3)](PF6)(6) (Ru-L-1, Ru-L-2) have been synthesized. Cyclic voltammetry of the complexes are consistent with one Ru(II)-centered oxidation at 1.32 V and four ligand-centered reductions. Photophysical behaviors are investigated by UV-Vis absorption and fluorescence spectrometry. The two complexes show metal-to-ligand charge transfer absorption at 440 nm and emission at around 580 nm. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.12.005