4,4'-bis(3,5-dimethoxyphenyl)-6,6'-dimethyl-2,2'-bipyridine | 1161442-15-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4,4'-bis(3,5-dimethoxyphenyl)-6,6'-dimethyl-2,2'-bipyridine
• 英文别名: (CH3(C5H2N)(C6H3)(OMe)2)2；4-(3,5-Dimethoxyphenyl)-2-[4-(3,5-dimethoxyphenyl)-6-methylpyridin-2-yl]-6-methylpyridine
• CAS: 1161442-15-4
• 化学式: C₂₈H₂₈N₂O₄
• 分子量: 456.541
• InChiKey: ULEXQRYLPUXVBN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  34
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  62.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  tetrakis(actonitrile)copper(I) hexafluorophosphate 、 4,4'-bis(3,5-dimethoxyphenyl)-6,6'-dimethyl-2,2'-bipyridine 以 乙醇 为溶剂， 以75%的产率得到[Cu((CH3(C5H2N)(C6H3)(OMe)2)2)2][PF6]*0.25HPF6
  参考文献：
  名称：

  Preparation and photophysical studies of copper(I) and ruthenium(II) complexes of 4,4′-bis(3,5-dimethoxyphenyl)-6,6′-dimethyl-2,2′-bipyridine

  摘要：

  We report the synthesis of a new ligand, 4,4'-bis(3,5-dimethoxyphenyl)-6,6'-dimethyl-2,2'-bipyridine, optimised for binding to copper(I) and with pendant functionality that can eventually be developed into metallodendritic structures. The synthesis and photophysical properties of complexes with copper(I) and ruthenium(II) are reported. The solid state structure of the complex [Cu(1)(2)][PF6] center dot MeCN (1 = 4,4'-bis(3,5-dimethoxyphenyl)- 6,6'-dimethyl-2,2'-bipyridine) is also described. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.08.036