((C6H3-2,6-(C6H3-2,6-i-Pr2)2)Ge)2(μ-O) | 1311159-30-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ((C6H3-2,6-(C6H3-2,6-i-Pr2)2)Ge)2(μ-O)
• CAS: 1311159-30-4
• 化学式: C₆₀H₇₄Ge₂O
• 分子量: 956.427
• InChiKey: WNZFNYVZSALJQG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.55
• 重原子数：
  63.0
• 可旋转键数：
  16.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  吡啶-N-氧化物 、 (Ge(C₆H₃)-2,6-(C₆H₃-2,6-ⁱPr)₂)₂ 以 甲苯 为溶剂， 以42%的产率得到((C6H3-2,6-(C6H3-2,6-i-Pr2)2)Ge)2(μ-O)
  参考文献：
  名称：

  Tethered Heavy Dicarbene Analogues: Synthesis and Structure of Ditetryldiyl Ethers (Ar′E)₂(μ-O) (E = Ge, Sn; Ar′ = C₆H₃-2,6-(C₆H₃-2,6-ⁱPr₂)₂)

  摘要：

  Ditetryldiyl ethers (Ar'E)(2)(mu-O) (E = Ge, Sn; = C6H3-2,6-(C6H3-2,6-Pr-i(2))(2)) which contain a pair of two-coordinate Sn or Ge atoms were successfully prepared by the reaction of the corresponding dimetallylene (Ar'E)(2) with 1 equiv of pyridine N-oxide. The tin oxide was found to cocrystallize with a hydroxide impurity: {Ar'Sn(mu-OH)}(2). Structural determination revealed a slightly bent oxide E-O-E core (E = Ge, 154.8(1)degrees; E = Sn, 154.7(3)degrees) and a trans orientation of the Ar' groups in each complex. The compounds were also characterized by NMR and electronic spectroscopy.

  DOI：

  10.1021/om2004018