(3-Iodo-2,4,6-trimethyl-phenyl)-bis-(2,4,6-trimethyl-phenyl)-phosphane | 197144-69-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-Iodo-2,4,6-trimethyl-phenyl)-bis-(2,4,6-trimethyl-phenyl)-phosphane
• 英文别名: (3-Iodo-2,4,6-trimethylphenyl)bis(2,4,6-trimethylphenyl)phosphane；(3-iodo-2,4,6-trimethylphenyl)-bis(2,4,6-trimethylphenyl)phosphane
• CAS: 197144-69-7
• 化学式: C₂₇H₃₂IP
• 分子量: 514.429
• InChiKey: XGKQASCSFKZZJO-UHFFFAOYSA-N

物化性质

• 熔点：
  161.5-163.0 °C
• 沸点：
  539.3±50.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  29
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (3-Iodo-2,4,6-trimethyl-phenyl)-bis-(2,4,6-trimethyl-phenyl)-phosphane 在 18-冠醚-6 、 铜 、 potassium carbonate 作用下， 以 various solvent(s) 为溶剂， 反应 120.0h， 生成 {3-[Bis-(2,4,6-trimethyl-phenyl)-phosphinoyl]-2,4,6-trimethyl-phenyl}-bis-(4-tert-butyl-phenyl)-amine
  参考文献：
  名称：

  Synthesis and redox properties of sterically hindered meta- and para- aminophosphinobenzenes

  摘要：

  Meta- and para-aminophosphinobenzenes composed of para substituted triarylamine and all ortho methylated triarylphosphine moieties were synthesized and their redox properties were investigated by cyclic voltammetry. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)01711-5
• 作为产物：
  描述：

  (3-Bromo-2,4,6-trimethyl-phenyl)-bis-(2,4,6-trimethyl-phenyl)-phosphane 在 正丁基锂 、 碘 作用下， 生成 (3-Iodo-2,4,6-trimethyl-phenyl)-bis-(2,4,6-trimethyl-phenyl)-phosphane
  参考文献：
  名称：

  Synthesis and redox properties of sterically hindered meta- and para- aminophosphinobenzenes

  摘要：

  Meta- and para-aminophosphinobenzenes composed of para substituted triarylamine and all ortho methylated triarylphosphine moieties were synthesized and their redox properties were investigated by cyclic voltammetry. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)01711-5