[Zn(3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin)(triehylenediamine)] | 1072502-97-6

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: [Zn(3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin)(triehylenediamine)]
• 英文别名: Zn(C20H4N4(CH3)4(CH2CH3)4)(DABCO)；Zn(C20H4N4(CH3)4(CH2CH3)4)(1,4-diazabicyclo[2.2.2]octane)
• CAS: 1072502-97-6
• 化学式: C₃₈H₄₈N₆Zn
• 分子量: 654.229
• InChiKey: KVIQQFZEHBIOEW-FVZPTBRNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三乙烯二胺 、 zinc 3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin 以 乙醇 为溶剂， 生成 [Zn(3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin)(triehylenediamine)]
  参考文献：
  名称：

  Synthesis, spectra, and complexing properties of polyoxyethylene-substituted 5,15-diphenylporphyrins

  摘要：

  Porphyrins with two opposite meso-phenyl substituents of the macroring linked via o-positions by polyoxyethylene bridges of various lengths were prepared. Their spectra and complexing properties toward Zn2+ and 1,4-diazabicyclo[2.2.2]octane were examined. The rate constants of formation and stability constants of the corresponding complexes were determined, and the concentration ranges of their formation were evaluated.

  DOI：

  10.1134/s1070363207110217

文献信息

• Complexation of zinc octaalkylporphyrin with mono-, di-, and triethylenediamines in toluene
  作者：G. M. Mamardashvili、N. Zh. Mamardashvili、O. I. Koifman

  DOI：10.1134/s0036023607080104

  日期：2007.8

  The complexation of zinc octaalkylporphyrin with mono-, di-, and triethylenediamines in toluene was studied by spectrophotometry using the molar ratio method and by H-1 NMR. The effect of the structure of the two-center organic base on the formation of 1 : 1 or 2 : 1 metal porphyrin-ligand complex was established. The stability constants of the resulting complexes were calculated and the concentration ranges of their existence were determined.