Na(O3SC6H4CH2C(CH2PPh2)3) | 172221-19-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Na(O3SC6H4CH2C(CH2PPh2)3)
• CAS: 172221-19-1
• 化学式: C₄₇H₄₂O₃P₃S*Na
• 分子量: 802.826
• InChiKey: GXQGZAIXLAVZOK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.52
• 重原子数：
  55.0
• 可旋转键数：
  15.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  57.2
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 、 Na(O3SC6H4CH2C(CH2PPh2)3) 生成 Rh(I)(O3S(C6H4)CH2C(CH2P(C6H5)2)3)(cycloocta-1,5-diene)
  参考文献：
  名称：

  Zwitterionic Metal Complexes of the New Triphosphine NaO3S(C6H4)CH2C(CH2PPh2)3 in Liquid Biphasic Catalysis: An Alternative to Teflon "Ponytails" for Facile Catalyst Separation without Water

  摘要：

  The new Ligand NaO3S(C6H4)CH2C(CH(2)PPh(2))(3) (sulphos) has been synthesized. The application of the zwitterionic Rh(I) complexes (sulphos)Rh(cod) and (sulphos)Rh(CO)(2) in liquid biphasic catalysts has been demonstrated for the hydrogenation of styrene and the hydroformylation of 1-hexene, respectively. The Latter reaction gives C-7 alcohols in an alcohol/hydrocarbon system and C-7 aldehydes in an alcohol-water/hydrocarbon system. All rhodium a's recovered in the polar phase at the end of the catalytic reactions.

  DOI：

  10.1021/om00012a002

文献信息

• Synthesis, characterization and aqueous-biphase catalysis of the ruthenium dimer Na[{O3S(C6H4)CH2C(CH2PPh2)3Ru}2(μ-Cl)3]
  作者：Iraima Rojas、Francisco Lopez Linares、Norma Valencia、Claudio Bianchini

  DOI：10.1016/s1381-1169(98)00311-2

  日期：1999.7

  the reaction of the tripodal ligand NaO3S(C6H4)CH2C(CH2PPh2)3 with the ruthenium complex [RuCl2(DMSO)4]. The dimeric complex is an effective catalyst precursor for the liquid-biphase hydrogenation of the double bond in various alkenes (1-hexene, 1-decene, allylbenzene, styrene) as well as the heteroaromatic ring in benzo[b]thiophene and quinoline. All the metal remains in the polar phase at the end of

  该二聚体的Na [ø 3 -S（O 6 ħ 4）CH 2 C（CH 2 PPH 2）3钌} 2（μ-Cl）的3 ]·3H 2 O具有被的反应中合成的三足配体的NaO 3具有钌配合物[RuCl 2（DMSO）4的S（C 6 H 4）CH 2 C（CH 2 PPh 2）3]。二聚配合物是在各种烯烃（1-己烯，1-癸烯，烯丙基苯，苯乙烯）以及苯并[ b ]噻吩和喹啉中的杂芳环上进行双键液相双相加氢的有效催化剂前体。在催化反应结束时，所有金属都保留在极性相中。