(oxydibenzene-4,1-diyl)-dimethanethiol | 7344-22-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (oxydibenzene-4,1-diyl)-dimethanethiol
• 英文别名: (Oxydibenzene-4,1-diyl)dimethanethiol；[4-[4-(sulfanylmethyl)phenoxy]phenyl]methanethiol
• CAS: 7344-22-1
• 化学式: C₁₄H₁₄OS₂
• 分子量: 262.397
• InChiKey: MSILJOYZYPRFDK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  11.2
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-甲基-2-氯-喹啉 、 (oxydibenzene-4,1-diyl)-dimethanethiol 以 乙醇 为溶剂， 以91%的产率得到2,2'-[oxybis(benzene-4,1-diylmethylenesulfanediyl)]bis(4-methylquinoline)
  参考文献：
  名称：

  2-氯-4-甲基喹啉与硫亲核试剂的反应和4-甲基喹啉-2（1H）-硫酮与取代的苄基氯的反应

  摘要：

  DOI：

  10.1134/s1070428014030257

文献信息

• [EN] LATENT ACIDS AND THEIR USE<br/>[FR] ACIDES LATENTS ET LEUR UTILISATION
  申请人：BASF SE

  公开号：WO2016124493A1

  公开（公告）日：2016-08-11

  Compounds of the formula (I) and (IA) wherein X is -O(CO)-; R1 is C1-C12haloalkyl or C6-C10haloaryl; R2 is located in position 7 of the coumarinyl ring and is OR8; R2a, R2b and R2C independently of each other are hydrogen; R3 is C1-C8haloalkyl or C1-C8haloalkyl; R4 is hydrogen; and R8 is C1-C6alkyI; are suitable as photosensitive acid donors in the preparation of photoresist compositions such as used for example in the preparation of spacers, insulating layers, interlayer dielectric films, insulation layers, planarization layers, protecting layers, overcoat layers, banks for electroluminescence displays and liquid crystal displays (LCD).

  化合物的化学式（I）和（IA），其中X为-O(CO)-；R1为C1-C12卤代烷基或C6-C10卤代芳基；R2位于香豆素环的第7位，为OR8；R2a、R2b和R2C彼此独立地为氢；R3为C1-C8卤代烷基或C1-C8卤代烷基；R4为氢；R8为C1-C6烷基，适用于作为感光酸给体，用于制备光刻胶组合物，例如用于制备间隔层、绝缘层、层间介质膜、绝缘层、平坦化层、保护层、覆盖层、电致发光显示器和液晶显示器（LCD）的制备。
• High purity monoalkyltin compounds and uses thereof
  申请人：ARKEMA FRANCE

  公开号：EP2123659A1

  公开（公告）日：2009-11-25

  The present invention relates to high purity monoalkyltin compounds, more specifically to alkyltin compound compositions containing monoalkyltin as major compound, and minor quantities of di- and/or trialkyltin compounds. The present invention also relates to the preparation processes of such high purity monoalkyltin compounds, as well as to the uses of said monoalkyltin compounds as chlorine-containing polymer-stabilisers, glass coating chemicals and catalysts, as well as articles comprising at least one polymer matrix and a high purity monoalkyltin compound.

  本发明涉及高纯度的单烷基锡化合物，更具体地是含有单烷基锡作为主要化合物的烷基锡化合物组合物，以及少量的二烷基锡和/或三烷基锡化合物。本发明还涉及制备这种高纯度单烷基锡化合物的过程，以及将所述单烷基锡化合物用作含氯聚合物稳定剂、玻璃涂层化学品和催化剂的用途，以及包含至少一个聚合物基质和高纯度单烷基锡化合物的制品。
• [EN] SULFONIUM DERIVATIVES AND THE USE THEROF AS LATENT ACIDS<br/>[FR] DÉRIVÉS DE SULFONIUM ET LEUR UTILISATION EN TANT QU'ACIDES LATENTS
  申请人：BASF SE

  公开号：WO2010046240A1

  公开（公告）日：2010-04-29

  Compounds of the formula (I), wherein Ar1 is for example phenylene or biphenylene both unsubstituted or substituted; Ar2 and Ar3 are for example independently of each other phenyl, naphthyl, biphenylylyl or heteroaryl, all optionally substituted; or Ar1 and Ar2 for example together with a direct bond, O, S or (CO), form a fused ring system; R is for example hydrogen, C3-C30cycloalkyl or C1-C18alkyl; and R1, R2 and R3 independently of each other are for example C1-C10haloalkyl; are effective photoacid generators (PAG).

  化合物的公式（I），其中Ar1例如是未取代或取代的苯基或联苯基; Ar2和Ar3例如是独立的苯基，萘基，联苯基或杂环基，均可选取代; 或者例如Ar1和Ar2与直接键，O，S或（CO）一起形成融合的环系统; R例如是氢，C3-C30环烷基或C1-C18烷基; R1，R2和R3独立地例如是C1-C10卤代烷基; 是有效的光酸发生剂（PAG）。
• NOVEL CYCLIC COMPOUND AND OPTICAL MATERIAL COMPOSITION INCLUDING SAME
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20170334876A1

  公开（公告）日：2017-11-23

  One embodiment of the present invention can provide an optical material composition that includes a cyclic compound that is represented by formula (1) and an episulfide that is represented by formula (2). Another embodiment of the present invention can provide an optical material production method that includes a step wherein, with respect to the total amount of the optical material composition, 0.0001-10 mass % of a polymerization catalyst is added to the optical material composition and the optical material composition is polymerization cured. (In formula (2), m is an integer from 0 to 4, and n is an integer from 0 to 2.)

  本发明的一个实施例可以提供一种光学材料组合物，其中包括由式（1）表示的环状化合物和由式（2）表示的环氧硫化物。本发明的另一个实施例可以提供一种光学材料生产方法，其中包括一步，其中，在光学材料组合物的总量中，添加0.0001-10质量％的聚合催化剂到光学材料组合物中，并对光学材料组合物进行聚合固化。（在式（2）中，m是0到4的整数，n是0到2的整数。）
• NOVEL EPISULFIDE COMPOUND AND OPTICAL MATERIAL COMPOSITION CONTAINING SAME
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20170247351A1

  公开（公告）日：2017-08-31

  According to the present invention, it is possible to provide an optical material composition that contains an episulfide compound represented by formula (1) and an episulfide compound represented by formula (2). According to this optical material composition, it is possible to suppress a reduction in the yield rate caused by molding defects, and possible to obtain an optical material having excellent dyeability. (In formula (1), m and p are each an integer between 0 and 4, and n and q are each an integer between 0 and 2.) (In formula (2), m is an integer between 0 and 4 and n is an integer between 0 and 2.)

  根据本发明，可以提供一种含有由式（1）表示的环硫醚化合物和由式（2）表示的环硫醚化合物的光学材料组合物。根据这种光学材料组合物，可以抑制由成型缺陷引起的产率降低，并且可以获得具有优异染色性能的光学材料。（在式（1）中，m和p分别是介于0和4之间的整数，n和q分别是介于0和2之间的整数。）（在式（2）中，m是介于0和4之间的整数，n是介于0和2之间的整数。）