CoCl2(6-amino-5-formyl-1,3-dimethyluracilbenzoylhydrazone) | 244036-41-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: CoCl2(6-amino-5-formyl-1,3-dimethyluracilbenzoylhydrazone)
• 英文别名: N-[(E)-(4-amino-1,3-dimethyl-2,6-dioxopyrimidin-5-yl)methylideneamino]benzamide;dichlorocobalt
• CAS: 244036-41-7
• 化学式: C₁₄H₁₅Cl₂CoN₅O₃
• 分子量: 431.204
• InChiKey: DXQROKFYJOTZHH-QPJJLOBJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  6-amino-5-formyl-1,3-dimethyluracilbenzoylhydrazone 、 cobalt(II) chloride 以 乙醇 为溶剂， 生成 CoCl2(6-amino-5-formyl-1,3-dimethyluracilbenzoylhydrazone)
  参考文献：
  名称：

  Synthesis and spectral studies on metal complexes with the neutral O,N,O-tridentate Schiff base 6-amino-5-formyl-1,3-dimethyluracil-benzoylhydrazone

  摘要：

  From the reaction between different Co(II), Cu(II), Zn(II) and Pd(II) salts and the Schiff base 6-amino-5-formyl-1,3-dimethyluracilbenzoylhydrazone (H(2)BEZDO), in ethanol and acetone media, five complexes with M/L stoichiometry 1/1, containing the neutral organic ligand, have been obtained. These compounds have been studied by IR, C-13 and H-1-NMR, UV-VIS-NIR and EPR spectroscopies and magnetic measurements. A single crystal X-ray diffraction study has been carried out on the compound [Cu(ClO4)(H(2)BEZDO)(H2O)]ClO4. The structure consists of mononuclear cations [Cu(ClO4)(H(2)BEZDO)(H2O)](+) and uncoordinated perchlorate anions, The coordination environment around the Cu(II) may be described as a square-based pyramid in which the Schiff base acts as tridentate ligand through the O(4), N(51) and O(52) atoms, making two five- and six-membered chelate rings. The coordination sphere is completed with the oxygen atom of the water molecule and an oxygen atom of a weakly coordinated perchlorate group occupying the apical position of the polyhedron. Both complex units and uncoordinated perchlorate anions are extensively hydrogen-bonded, forming bidimensional sheets. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00108-4