3,3'-[氧基二(亚甲基)]二(7-氧杂双环[4.1.0]庚烷) | 103946-55-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 中文名称: 3,3'-[氧基二(亚甲基)]二(7-氧杂双环[4.1.0]庚烷)
• 中文别名: 2H-吡喃-4-醇,四氢-4-(1H-吲唑-6-基)-
• 英文名称: bis(3,4-epoxycyclohexylmethyl) ether
• 英文别名: 4,4'-(Oxybis(methylene))bis(7-oxabicyclo(4.1.0)heptane)；3-(7-oxabicyclo[4.1.0]heptan-3-ylmethoxymethyl)-7-oxabicyclo[4.1.0]heptane
• CAS: 103946-55-0
• 化学式: C₁₄H₂₂O₃
• 分子量: 238.327
• InChiKey: RRXFVFZYPPCDAW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  34.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-环己烯-1-甲醇 在 溶剂黄146 、 sodium hydroxide 作用下， 以 乙酸乙酯 、 甲苯 为溶剂， 反应 8.0h， 生成 3,3'-[氧基二(亚甲基)]二(7-氧杂双环[4.1.0]庚烷)
  参考文献：
  名称：

  경화성 에폭시 수지 조성물 및 그의 경화물, 디올레핀 화합물 및 그의 제조 방법, 및 디에폭시 화합물의 제조 방법

  摘要：

  本发明的目的是提供一种能够通过硬化形成具有高玻璃化转变温度，特别是具有优异的耐热性和透明性平衡的硬化物的硬化环氧树脂组合物。该发明涉及一种硬化环氧树脂组合物，其特征在于包括表示为式（1）的环氧化合物（A）和硬化剂（B），或者涉及一种硬化环氧树脂组合物，其特征在于包括表示为式（1）的环氧化合物（A）和固化催化剂（C）。[在式（1）中，R至R可以相同或不同，表示氢原子，甲基基或乙基基，m和n可以相同或不同，表示1至4的整数]

  公开号：

  KR20160006198A

文献信息

• AROMATIC AMINE COMPOUND, CURING AGENT FOR EPOXY COMPOUND, CURABLE COMPOSITION, CURED PRODUCT, METHOD FOR PRODUCING CURED PRODUCT, AND METHOD FOR PRODUCING AROMATIC AMINE COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20210130284A1

  公开（公告）日：2021-05-06

  An aromatic amine compound capable of satisfactorily forming a cured product having exceptional alkali resistance by reaction with an epoxy compound; a curing agent for an epoxy compound, the curing agent including the aromatic amine compound; a curable composition including the curing agent for an epoxy compound; a cured product of the curable composition; a method for producing the cured product; and a method for producing the abovementioned aromatic amine compound. The aromatic amine compound has a structure such that a specific position in a central skeleton comprising a fused ring such as a fluorene ring is substituted with a side-chain group including two aromatic groups linked by a flexible bond such as an amide bond, at least one amino group is bonded to the end of the side-chain group, and the structure has no hydroxyl groups.

  一种芳香胺化合物，通过与环氧化合物反应能够满意地形成具有异常碱性抗性的固化产品；一种环氧化合物的固化剂，该固化剂包括芳香胺化合物；一种包括环氧化合物的固化剂的可固化组合物；可固化组合物的固化产品；生产所述固化产品的方法；以及生产上述芳香胺化合物的方法。该芳香胺化合物具有这样的结构，即中心骨架中的特定位置包括类似于芴环的融合环，该位置被取代为包括通过柔性键（如酰胺键）连接的两个芳香基的侧链基团，至少一个氨基固定在侧链基团的末端，并且该结构不含羟基。
• [EN] AMINE CO-INITIATOR MIXTURE<br/>[FR] MÉLANGE CO-INITIATEUR À BASE D'AMINE
  申请人：LAMBSON LTD

  公开号：WO2021074363A1

  公开（公告）日：2021-04-22

  The invention relates to a co-initiator comprising the aminobenzoate derivative according to Formula (I) and at least one ancillary amine, wherein the reactivity and solubility of said co-imitator in UV-curable resins is sufficiently high that the co-initiator can be used in UV radiation curing processes. Formula (I) wherein R1 and R2 independently represent methyl or ethyl groups; and j, k, l and m are independently 0 to 20.

  这项发明涉及一种共同引发剂，其包括按照式（I）中的氨基苯甲酸酯衍生物和至少一种辅助胺，其中所述共同引发剂在UV固化树脂中的反应性和溶解性足够高，以至于该共同引发剂可以用于UV辐射固化工艺中。式（I）中，R1和R2分别代表甲基或乙基基团；j、k、l和m独立地为0至20。
• Sulfonium salt, curable composition, ink composition, inkjet recording method, printed material, process for producing lithographic printing plate, and lithographic printing plate
  申请人：Tsuchimura Tomotaka

  公开号：US20070197677A1

  公开（公告）日：2007-08-23

  A sulfonium salt is provided that has a cation represented by Formula (II) (R 1′ to R 13′ in Formula (II) independently denote a hydrogen atom or a substituent, and may be bonded to each other to form a ring, provided that at least one of R 1′ to R 8′ denotes a halogen atom or a haloalkyl group). There are also provided a curable composition that includes the sulfonium salt, and an ink composition that includes the curabie composition. Furthermore, there are also provided an inkjet recording method employing the ink composition, and a process for producing a lithographic printing plate, the process including discharging the ink composition onto a hydrophilic support. A printed material and a lithographic printing plate thus obtained are also included in the present invention.

  提供一种具有由化学式（II）表示的阳离子的硫铵盐（其中，化学式（II）中的R1'到R13'独立地表示氢原子或取代基，并且它们可以结合在一起形成环，前提是R1'到R8'中至少有一个表示卤素原子或卤代烷基）。还提供了包括该硫铵盐的可固化组合物，以及包括该可固化组合物的油墨组合物。此外，还提供了一种采用该油墨组合物的喷墨记录方法，以及生产平版印刷版的工艺，其中该工艺包括将油墨组合物排放到亲水性支撑体上。本发明还包括由此获得的印刷材料和平版印刷版。
• PHOTOCURABLE COMPOSITION, CURED PRODUCT AND OPTICAL COMPONENT USING SAME
  申请人：DAICEL CORPORATION

  公开号：US20180134838A1

  公开（公告）日：2018-05-17

  Provided is a photocurable composition which less causes resin-induced swelling of molds, allows the molds to endure more satisfactorily, and has excellent economic efficiency. This photocurable composition includes components (A), (B), (C), and (D). The component (A) is present in a content of 10 to 50 weight percent of the totality of photocurable compounds contained in the photocurable composition. The component (A) is a cycloaliphatic epoxy compound represented by Formula (a). The component (B) is an oxetane compound having a solubility parameter of 9.5 (cal/cm 3 ) 1/2 or more as determined by the Fedors' method. The component (C) is a glycidyl ether epoxy compound having a molecular weight of 250 or more. The component (D) is a photoinitiator: wherein R 1 to R 18 are each, identically or differently, selected from hydrogen, halogen, a hydrocarbon group optionally containing oxygen or halogen, and optionally substituted alkoxy; and X is selected from a single bond and a linkage group.

  提供的是一种光固化组合物，其引起模具树脂引起的膨胀较少，使模具更能承受，并具有优秀的经济效益。该光固化组合物包括组分（A），（B），（C）和（D）。组分（A）在光固化组合物中所含光固化化合物的总量的10至50重量％。组分（A）是由式（a）表示的环状脂肪族环氧化合物。组分（B）是具有由Fedors方法确定的溶解度参数为9.5（cal/cm3）1/2或更高的氧杂环丙烷化合物。组分（C）是具有分子量为250或更高的缩水甘油醚环氧化合物。组分（D）是光引发剂：其中R1到R18分别相同或不同地选择自氢，卤素，含氧或卤素的碳氢基团和可选择的取代烷氧基; X选择自单键和连接基团。
• Resist ink composition
  申请人：——

  公开号：US20030022958A1

  公开（公告）日：2003-01-30

  The present invention provides a resist ink composition comprising a compound (a) having at least one oxetanyl group and at least one epoxy group within the same molecule and a compound (b) capable of initiating cationic polymerization under irradiation by an active energy ray and/or under heat. This resist ink composition has high photosensitivity and enables the final curing by a brief heating and the cured film exhibits good physical properties.

  本发明提供了一种抗蚀墨水组合物，包括一个化合物（a），其分子内至少具有一个环氧乙烷基团和至少一个环氧基团，以及一种化合物（b），能够在活性能量射线辐射和/或热下启动阳离子聚合。该抗蚀墨水组合物具有高感光性，可以通过短暂加热最终固化，固化薄膜具有良好的物理性能。