2-(6-(4-vinylbenzyloxy)hexyl)isoindoline-1,3-dione | 1357291-82-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: 2-(6-(4-vinylbenzyloxy)hexyl)isoindoline-1,3-dione
• 英文别名: 2-[6-[(4-Ethenylphenyl)methoxy]hexyl]isoindole-1,3-dione；2-[6-[(4-ethenylphenyl)methoxy]hexyl]isoindole-1,3-dione
• CAS: 1357291-82-7
• 化学式: C₂₃H₂₅NO₃
• 分子量: 363.456
• InChiKey: GSXYYUPHBDMOAC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  27
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  46.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-(6-溴己基)邻苯二甲酰亚胺 、 (4-乙烯基苯基)甲醇 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 、 mineral oil 为溶剂， 反应 26.0h， 以21%的产率得到2-(6-(4-vinylbenzyloxy)hexyl)isoindoline-1,3-dione
  参考文献：
  名称：

  Nitroxide-mediated controlled radical polymerizations of styrene derivatives

  摘要：

  AbstractSeveral (protected) amine and alcohol functionalized styrene monomers were synthesized via readily accessible synthetic routes. The controlled radical copolymerization of these functionalized styrene monomers with styrene was performed using two alkoxyamines, namely N‐(2‐methylpropyl)‐N‐(1‐diethylphosphono‐2,2‐dimethylpropyl)‐O‐(2‐carboxylprop‐2‐yl) hydroxylamine (MAMA‐SG1) and N‐tert‐butyl‐N‐(2‐methyl‐1‐phenylpropyl)‐O‐(1‐phenylethyl)hydroxylamine. The copolymers obtained showed low polydispersities, controlled molecular weights, and a random topology. The thermal properties of the polymers were determined with differential scanning calorimetry. All polymers were amorphous and showed glass transition temperatures between 40 and 111 °C. Deprotection of the copolymers afforded amine or alcohol pendant polystyrenes which were readily functionalized with isocyanates. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012

  DOI：

  10.1002/pola.25833

文献信息

• Nitroxide-mediated controlled radical polymerizations of styrene derivatives
  作者：Patrick J. M. Stals、Trang N. T. Phan、Didier Gigmes、Tim F. E. Paffen、E. W. Meijer、Anja R. A. Palmans

  DOI：10.1002/pola.25833

  日期：2012.2.15

  AbstractSeveral (protected) amine and alcohol functionalized styrene monomers were synthesized via readily accessible synthetic routes. The controlled radical copolymerization of these functionalized styrene monomers with styrene was performed using two alkoxyamines, namely N‐(2‐methylpropyl)‐N‐(1‐diethylphosphono‐2,2‐dimethylpropyl)‐O‐(2‐carboxylprop‐2‐yl) hydroxylamine (MAMA‐SG1) and N‐tert‐butyl‐N‐(2‐methyl‐1‐phenylpropyl)‐O‐(1‐phenylethyl)hydroxylamine. The copolymers obtained showed low polydispersities, controlled molecular weights, and a random topology. The thermal properties of the polymers were determined with differential scanning calorimetry. All polymers were amorphous and showed glass transition temperatures between 40 and 111 °C. Deprotection of the copolymers afforded amine or alcohol pendant polystyrenes which were readily functionalized with isocyanates. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012